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The concentrations of soot, NO and the other combustion products were measured by incylinder gas sampling in a DI diesel engine. The effects of injection timing, swirl ratio, and combustion chamber geometry on the formation and emission processes of soot and NO were studied. The following results were obtained: (1) Soot is promptly formed in the flame during the early combustion period where the equivalence ratio in the flame is high over 1.0. Thereafter almost all the formed soot is swiftly burnd up by oxidation during the middle combustion period. This process mainly determines the exhaust soot concentration. (2) NO is formed in the flame during the early and middle combustion period where the flame temperature is high over 2000 K. The highest NO concentration is observed at the flame tip swept by the air swirl. Though the concentration of the formed NO decreases by dilusion it nearly constant during the later combustion period.