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A multi-functional membrane filter was developed through deposition of agglomerated Three-Way Catalyst particles with a size of 1 ~ 2 microns on the conventional bare particulate filter. The filtration efficiency reaches almost 100 % from the beginning of soot trapping with a low pressure drop and both reductions of NO and CO emission were achieved.

Nowadays, most manufacturers are looking for the improvement of lightweight parts and other components in the automobile field. Carbon fiber and glass fiber are the most effective materials for their requirement to reduce the weight in vehicles due to their light weight and high tensile strength. The diameter of carbon fiber is 6 μm while glass fiber diameter is 17 μm. The mechanical tensile force of carbon fiber and glass fiber are 430 N and 290 N respectively on fiber alone without matrix. Carbon fibers are gradually smaller in each filament due to tensile force. Approximately 5 mm are elongated for both carbon fiber and glass fiber in tensile test report. In current research, characteristic and tensile force of carbon fiber and glass fiber were investigated by using electron microscopy, Raman spectroscopy and XRD.

The exhaust emissions from diesel combustion are the sources of particulate matter emitted to the atmosphere, which are components of air pollution that implicated in human health such as lung cancer. At present the diesel particulate filter can remove PM from the exhaust gas before emitted to the atmosphere. This research is investigating morphology and structure of acicular mullite to develop the fabrication process filter in order to study particulate matters trapping and oxidation mechanisms. This paper used two main substances to study the structure of diesel particulate filter (DPFs); Aluminum oxide (Al2O3) and Silicon dioxide (SiO2). These are mainly in the conventional DPFs. The variable substances are Titanium dioxide (TiO2) and Vanadium oxide (V2O5), which added to investigate and produce the acicular mullite DPFs structure. The mullite samples were sintered at 1300 oC with holding time of 1 h.

The soot contamination in used engine oils of diesel engine vehicles was about 1% by weight. The soot and metal wear particle sizes might be in the range of 0-1 µm and 1-25 µm, respectively. The characteristics of soot affecting on metal wear was investigated. Soot particle contamination in diesel engine oil was simulated using carbon black. Micro-nanostructure of soot particles were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and laser diffraction spectroscopy (LDS). The metal wear behavior was studied by means of a Four-Ball tribology test with wear measured. Wear roughness in micro-scale was investigated by high resolution optical microscopy (OM) , 3D rendering optical technique and SEM image processing method. It was found that the ball wear scar diameter increased proportionally to the soot primary particle size. The effect of biodiesel contamination were also increasing in wear scar diameter.

Diesel engines are high thermal efficiency because of high compression ratio but produce high concentration of particulate matter (PM) because of direct injection fuel diffusion combustion. PM must be removed from the exhaust gas to protect human health. This research describes biodiesel engine performance, efficiency and combustion behavior using combustion pressure analyzer. It was clearly observed that PM emitted from CI engines can be reduced by using renewable bio-oxygenated fuels. The morphology and nanostructure of fossil fuel and biofuel PMs were investigated by using a Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The morphology of biodiesel and diesel doesn’t have much different in the viewpoint of particulate matter trapping using DPF micro surface pores. The agglomerated ultrafine particles and primary nanoparticles sizes of diesel and biodiesel engine’s PM are approximately 50-500 nm and 20-50 nm, respectively.

The diesel particulate membrane filter (DPMF) is a good solution to the problem of high pressure drop that exists across diesel particulate filters (DPFs) as a result of the soot trapping process. Moreover, DPMFs that have a membrane layer composed of SiC nanoparticles can reduce the oxidation temperature of soot and the apparent activation energy. The SiC nanoparticles have an oxide layer on their surface, with a thickness less than 10 nm. From the visualization of soot oxidation on the surface of SiC nanoparticles by an environmental transmission electron microscope (ETEM), soot oxidation is seen to occur at the interface between the soot and oxide layers. The soot oxidation temperature dependency of the contact area between soot and SiC nanoparticles was evaluated using a temperature programmed reactor (TPR). The contact area between soot and SiC nanoparticles was varied by changing the ratio of SiC nanoparticles and carbon black (CB), which was used as an alternative to soot.

A direct numerical simulation of turbulent premixed flames in a constant volume vessel is conducted to understand flame-wall interactions and heat loss characteristics under the pressure rising condition. The contribution of the burnt region to the total heat flux is more significant compared to the reaction region. The velocity profiles indicate inward and outward motions. The profile of the turbulent kinetic energy is damped by the wall, and no distinct turbulence production is observed. Since the turbulence is weakened in the burnt region, the effect of near wall turbulence to the total wall heat flux is considered to be limited.

Surface pores that are open to the inlet channel below the surface play a particularly important role in the filtration of particulate matter (i.e., soot) inside the walls of a diesel particulate filter (DPF); they are closely related to the pressure drop and filtration efficiency through the DPF as well as the performance of the regeneration process. In this study, a scanning electron microscope (SEM) was used to dynamically visualize the soot deposition process at the particle scale as “time-lapse” images corresponding to the different increases in the pressure drop at each time step. The soot was first trapped at the deepest areas of the surface pores because the porous channels in this area were constricted by silicon carbide grains; soot dendrite structures were observed to grow and finally cause obstructions here.

A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

Hydraulically damped rubber mount (HDM) can effectively attenuate vibrations transmitting between automotive powertrain and body/chassis, and reduce interior noise of car compartment. This paper involves an analytical qualitative analysis approach of dynamics characteristics of HDM. Analysis of experimental results verifies the effectiveness of the qualitative analysis approach. Frequency- and amplitude-dependent dynamic characteristic of HDM are investigated to clarify working mechanism of HDM. The presented qualitative analysis approach provides a convenient performance adjustment guideline of HDM to meet vibration isolation requirements of powertrain mount system.

The major aim of this study is to investigate the tribofilm formation and friction-speed characteristics of ZnDTP in the presence of other lubricant additives. Simultaneous measurement of friction and electrical conductivity were employed using ZnDTP and several kinds of functionally different additives. Several analyses of friction surfaces were also carried out in order to measure the reaction film thickness and investigate the chemical composition of this film. It was demonstrated that the presence of each additive with ZnDTP prevented the formation of a ZnDTP tribofilm and thereby could provide lower friction than ZnDTP alone.

Trapping of diesel particulates and phenomena of chemical reaction in regeneration were investigated by visualization through the cross-sectional area of a diesel-particulate-filter wall, using a digital-microscope with a high focusing depth. Herein, SiC-DPF walls were polished up to make a uniform height and to create a mirror-like surface on each SiC-particle-grain. At the beginning of the trapping process, it was observed that large particulates were trapped once in the small pores inside the wall, and then, since the flow-pattern was changed drastically, the trapped particulates were pushed out and blown off again, and finally, trapped in a region further downstream. As time passed, image analysis disclosed that since fine particulates were deposited around the SiC-particle-grain surface, the flow-channels became increasingly narrow.

In order to investigate early soot formation process in diesel combustion, spectral analysis and optical thermometry of early soot formation region in a transient spray flame under diesel-like conditions (Pg2.8 MPa, Tg620-820K) was attempted via laser-induced fluorescence (LIF) from pyrene (C16H10) doped in the fuel. Pyrene is known to exhibit a temperature\-dependent variation of LIF spectrum; the ratio of S2/S1 fluorescence yields, from the lowest excited singlet state S1 and the second excited singlet state S2, depends on temperature. In the present study, pyrene was doped (1%wt) in a model diesel fuel (0-solvent) and the variation of LIF spectra from the pyrene in the spray flame in a rapid compression machine were examined at different ambient temperatures, ambient oxygen concentrations, measurement positions and timings after start of fuel injection.

The influence of the head shape on intracranial responses under impact was investigated by using Finite Element Method. Head shape models of 52 young adult male Japanese were analyzed by Multi Dimensional Scaling (MDS), and a 2 dimensional distribution map of head shapes was obtained. Five finite element models of the Japanese head were constructed by a transformed finite element model of an average European adult male (H-Head model) using Free Form Deformation (FFD) technique. The constructed models represent the 5th and 95th percentile of the first 2 scales obtained by MDS. The same acceleration pulse was applied to the H-Head model and the five finite element models. The cause of the difference was considered to be differences in pressure distribution in the brain caused by the differences in the head shape. Variation in the head shape should be taken into account in simulating the effects of impact using a finite element model.

The purpose of this study is to investigate the turbulent mixing in a diesel spray by large eddy simulation (LES). As the first step for the numerical simulation of diesel spray by LES, the LES of transient circular gas jets and particle laden jets were conducted. The simulation of transient circular jets in cylindrical coordinates has numerical instability near the central axis. To reduce the instability of calculation, azimuthal velocity around the central axis is calculated by the linear interpolation and filter width around the axis is modified to the radial or axial grid scale level. A transient circular gas jet was calculated by the modified code and the computational results were compared with experimental results with a Reynolds number of about 13000. The computational results of mean velocity and turbulent intensity agreed with experimental results for z/D>10. Predicted tip penetration of the jet also agreed to experimental data.

Measurements of Excitation-Emission Matrix (EEM) of shock-heated vapors of polycyclic aromatic hydrocarbons (PAHs) at high temperature (750-1500K) and high pressure (0.3-1.3MPa) conditions were conducted using a multi-wavelength excitation laser in order to demonstrate the potential of the single-measurement EEM fluorometry for investigation of soot precursors. Argon-diluted vapors of naphthalene and pyrene, as PAH model compounds, were heated in an optically accessible shock tube. The PAH vapors were excited by a coherent multi-wavelength “rainbow” laser light generated by converting the 4th harmonic (266nm) of a pulsed Nd:YAG laser using a Raman cell frequency converter filled with high-pressure (2MPa) methane-hydrogen mixture.

Hydraulically damped rubber engine mounts (HDM) are an effective means of providing sufficient isolation from engine vibration while also providing significant damping to control the rigid body motions of the engine during normal driving conditions. This results in a system which exhibits a high degree of non-linearity in terms of both frequency and amplitude. The numerical simulation of vibration isolation characteristics of HDM is difficult due to the fluid-structure interaction between the main supporting rubber and fluid in chambers, the nonlinear material properties, the large deformation of rubber parts, structure contact problems among the inner parts, and the turbulent flow in the inertia track. In this paper an integrated numerical simulation analysis based on structural FEM and a lumped-parameter model of HDM is carried out.

To investigate the ignition process in a diesel spray, the ignition in a transient fuel spray is analyzed numerically by a discrete droplet spray model (DDM) coupled with the Shell kinetics model at various operating conditions. Predicted results show that the fuel mixture injected at the start of injection, which travels along midway between the spray axis and the spray periphery, contributes heavily to the first ignition in a spray. The equivalence ratio and temperature of the first ignited mixture are kept nearly constant until the start of hot ignition. The temperature of the first ignited mixture is kept at a constant value of higher temperature than the thermodynamic equilibrium temperature of the mixture before the hot ignition starts. The equivalence ratio of the first ignited mixture is around 1.6 at initial gas temperatures between 750 K and 850 K.

Multi-step water splitting with Mn-ferrite(MnFe2O4)/sodium carbonate(Na2CO3) system accompanying endothermic reaction was investigated for converting solar energy into chemical energy. This water splitting is caused by the oxidation-reduction of manganese ion in the Mn-ferrite. Multi-water splitting with MnFe2O4/Na2CO3 system was consisted of three steps. The first step was hydrogen generation at 1073K. The second step was oxygen release at 1273K. The third step was Na2CO3 reproduction at 873K. The mechanism of multi-water splitting has been considered by XRD, chemical analysis of colorimetry and back titration. The temperature range 873 to 1273K is quite lower than those studied on the solar furnace reaction (O2 releasing step) in two-step water splitting (1500-2300K). This lower temperature range would permit further progress in converting the direct solar energy into chemical energy.