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With a view to reducing the environmental impact of fossil fuels, advanced lignin-based biofuels could provide a valuable contribute, since lignin is the most abundant biopolymer on earth after cellulose. However, its thermophysical properties would hamper its use as a pure fuel. In this work we investigated the combustion behavior of sprays of a liquid lignin-methanol blend and evaluated its potential as a low-carbon marine fuel for large two-stroke engines. To this end, an experimental campaign was conducted in an optically accessible combustion chamber whose main dimensions correspond to those of a single cylinder for large two-stroke engines. The chamber is provided with optical accesses for optical diagnostics of the combustion process. The combustion of the mixture was ignited using a diesel pilot jet as the ignition source. Two marine injectors are mounted in the chamber, namely “main” and “pilot” injectors.

Second generation biomass is an attractive renewable feedstock for transport fuels. Its sulfur content is generally negligible and the carbon cycle is reduced from millions to tens of years. One hitherto non-valorized feedstock are so-called humins, a residual product formed in the conversion of sugars to platform chemicals, such as hydroxymethylfurfural and methoxymethylfurfural, intermediates in the production of FDCA, a building block used to produce the polyethylene furanoate (PEF) bottle by Avantium. The focus of this study is to investigate the spray combustion behavior of humins as a renewable alternative for heavy fuel oil (HFO) under large two-stroke engine-like conditions in an optically accessible constant volume chamber.

Recently introduced sulfur caps on marine fuels in so-called sulfur emission control areas (SECAs) are forcing shipping companies to sail on more or less automotive grade diesel in lieu of the considerably less expensive, but sulfur-laden heavy fuel oil (HFO) to which they were accustomed. This development is an opportunity for a bio-based substitute, given that most biomass is sulfur free by default. Moreover, given that biomass is typically solid to start with, cracking it to an HFO grade, which is highly viscous in nature, will involve fewer and/or less harsh process steps than would be the case if an automotive grade fuel were to be targeted. In this study, a renewable low sulfur heavy fuel oil (LSHFO) has been produced by means of subcritical water assisted lignin depolymerization in the presence of a short length surfactant, ethylene glycol monobutyl ether (EGBE).

Owing to environmental and health concerns, tetraethyl lead was gradually phased out from the early 1970's to mid-1990's in most developed countries. Advances in refining, leading to more aromatics (via reformate) and iso-paraffins such as iso-octane, along with the introduction of (bio) oxygenates such as MTBE, ETBE and ethanol, facilitated the removal of lead without sacrificing RON and MON. In recent years, however, legislation has been moving in the direction of curbing aromatic and olefin content in gasoline, owing to similar concerns as was the case for lead. Meanwhile, concerns over global warming and energy security have motivated research into renewable fuels. Amongst which are those derived from biomass. The feedstock of interest in this study is lignin, which, together with hemicellulose and cellulose, is amongst the most abundant organic compounds on the planet.

Lignocellulosic biomass consists of (hemi-) cellulose and lignin. Accordingly, an integrated biorefinery will seek to valorize both streams into higher value fuels and chemicals. To this end, this study evaluated the overall combustion performance of both cellulose- and lignin derivatives, namely the high cetane number (CN) di-n-butyl ether (DnBE) and low CN anisole, respectively. Said compounds were blended both separately and together with EN590 diesel. Experiments were conducted in a single cylinder compression ignition engine, which has been optimized for improved combustion characteristics with respect to low emission levels and at the same time high fuel efficiency. The selected operating conditions have been adopted from previous “Tailor-Made Fuels from Biomass (TMFB)” work.

A Gasoline Compression Ignition combustion strategy was developed and showed its capabilities in the heavy duty single cylinder test-cell, resulting in indicated efficiencies up to 50% and low engine out emissions applying to EU VI and US 10 legislations while the soot remained at a controllable 1.5 FSN. For this concept a single-cylinder CI-engine was used running at a lambda of ∼1.6 and EGR levels of ∼50% and a modified injection strategy. Part of this strategy was also the use of a gasoline blended with an ignition improver, giving the blend a cetane number in the range of regular diesel; ∼50. In this paper a step is taken towards implementation of this combustion concept into a multi-cylinder light duty standalone CI-engine. A standard CI-engine was modified so that its gas-exchange system could deliver the requested amounts of EGR and lambda.

In an earlier study, a novel type of diesel fuel injector was proposed. This prototype injects fuel via porous (sintered) micro pores instead of via the conventional 6-8 holes. The micro pores are typically 10-50 micrometer in diameter, versus 120-200 micrometer in the conventional case. The expected advantages of the so-called Porous Fuel Air Mixing Enhancing Nozzle (PFAMEN) injector are lower soot- and CO2 emissions. However, from previous in-house measurements, it has been concluded that the emissions of the porous injector are still not satisfactory. Roughly, this may have multiple reasons. The first one is that the spray distribution is not good enough, the second one is that the droplet sizing is too big due to the lack of droplet breakup. Furthermore air entrainment into the fuel jets might be insufficient. All reasons lead to fuel rich zones and associated soot formation.

A literature and experimental study was done to create an overview of the behavior of gasoline combusted in a CI-engine. This paper creates a first overview of the work to be done before implementing this Gasoline Compression Ignition concept in a multi-cylinder engine. According to literature the gasoline blend will have advantages over diesel. First the shorter molecular chain of the gasoline makes it less prone to soot. Second the lower density gives the gasoline a higher nozzle exit speed resulting in better mixing capabilities. Third the lower density and higher volatility lets the spray length decrease. This lowers the chance of wall-impingement, but creates worse mixing conditions looking from a spray point of view. The CO and HC emissions tend to increase relative to operation with diesel fuel, NOx emissions largely depend on the choice of combustion strategy and could be influenced by the nitrogen bound to the EHN molecule that is used as an ignition improver.

This paper illustrates the results of an experimental study on the impact of a low cetane number (CN) oxygenated fuel on the combustion process and emissions of a light-duty (LD) single-cylinder research engine. In an earlier study, it was concluded that cyclic oxygenates consistently outperformed their straight and branched counterparts at equal oxygen content and with respect to lowering soot emissions. A clear correlation was reported linking soot and CN, with lower CN fuels leading to more favorable soot levels. It was concluded that a lower CN fuel, when realized by adding low reactive cyclic oxygenates to commercial diesel fuel, manifests in longer ignition delays and thus more premixing. Ultimately, a higher degree of premixing, in turn, was thought to suppress soot formation rates.

It is well known that the addition of gaseous fuels to the intake manifold of diesel engines can have significant benefits in terms of both reducing emissions of hazardous gases and soot and improving fuel economy. Particularly, the addition of LPG has been investigated in numerous studies. Drawbacks, however, of such dual fuel strategies can be found in storage complexity and end-user inconvenience. It is for this reason that on-board refining of a single fuel (for example, diesel) could be an interesting alternative. A second-generation fuel reformer has been engineered and successfully tested. The reformer can work with both gaseous and liquid fuels and by means of partial oxidation of a rich fuel-air mix, converts these into syngas: a mixture of H₂ and CO. The process occurs as partial oxidation takes place in an adiabatic ceramic reaction chamber. High efficiency is ensured by the high temperature inside the chamber due to heat release.

High-voltage nanosecond gas discharge has been shown to be an efficient way to ignite ultra-lean fuel air mixtures in a bulk volume, thanks to its ability to produce both high temperature and radical concentration in a large discharge zone. Recently, a feasibility study has been carried out to study plasma-assisted ignition under high-pressure high-temperature conditions similar to those inside an internal combustion engine. Ignition delay times were measured during the tests, and were shown to be decreasing under high-voltage plasma excitation. The discharge allowed instant control of ignition, and specific electrode geometry designs enabled volumetric ignition even at high-pressure conditions.

The goal of this paper is to acquire insight into the influence of cetane number (CN) and fuel oxygen on overall engine performance in the Premixed Charge Compression Ignition (PCCI) combustion mode. From literature, it is known that low reactive (i.e., low CN) fuels increase the ignition delay (ID) and therefore the degree of mixing prior to auto-ignition. With respect to fuel oxygen, it is known that this has a favorable impact on soot emissions by means of carbon sequestration. This makes the use of low CN oxygen fuels an interesting route to improve the applicability of PCCI combustion in diesel engines. In earlier studies, performed on a heavy-duty engine, cyclic oxygenates were found to consistently outperform their straight and branched counterparts with respect to curbing soot. This was attributed to a considerably lower CN.

In recent years, the study of volumetric ignition using high-speed (nanosecond) pulsed low temperature plasma for gasoline engines was reported by authors [ 1 ]. However, the fundamental analysis of ignition characteristics of the low temperature plasma ignition and the analysis of combustion initiation mechanism of the low temperature plasma ignition was not enough in the previous paper. In this study, a low temperature plasma igniter of a barrier discharge (silent discharge) model was developed for trial purpose. A fundamental analysis of ignition characteristics was carried out when the low temperature plasma ignition was applied as the ignition system for gasoline engine using single-cylinder. The difference between the ignition characteristics of the low temperature plasma and the thermal plasma of a conventional spark plug was investigated by comparing a combustion characteristic of both in various driving conditions.

An HCCI combustion has a low temperature heat release (LTHR) and a high temperature heat release (HTHR). During the LTHR period, fuel chemicals break down into radicals and small hydrocarbons, and they assist an initial reaction of HTHR. This is an important role of LTHR. On the contrary, LTHR has a negative aspect. In general, a heating value of LTHR changes depending on HCCI engine load due to the difference of the injected fuel quantity. The heating value of LTHR is low under low load condition, and the heating value of LTHR is high under high load condition. This leads to the changes of the starting crank angle of HTHR against engine load and it is a nuisance problem for the control of HCCI engine operation. Therefore, a fuel which exhibits the constant LTHR phasing against engine load would be preferable.

It was reported that n-heptane and toluene blended fuels (NTL series fuels) showed the dual phase high temperature heat release (DP-HTHR) combustion in a previous SAE paper [1]. DP-HTHR has the potential to enlarge the engine operational range to high load conditions and lower the engine combustion noise. Further research has been reported in this paper. Initial interests were in the combustion characteristics of a second “bump” in the high temperature heat release (2nd HTHR) in DP-HTHR, since this kind of two-stage combustion appears, when CO oxidation radically occurs over the 1450K temperature range.

To allow the HCCI vehicles to enter the market in the future, it is important to investigate the combustion deviations and operational range differences between the same research octane number fuels. In this paper, eighteen kinds of two hydrocarbon blended fuels, which were composed of n-heptane and another hydrocarbon, such as iso-octane, diisobutylene, 4-methyl-1-pentene, toluene or cyclopentane, were evaluated. Those fuels were blended to have the same research octane numbers of 75, 80, 85 and 90 by changing the blending volume ratio of n-heptane and counterpart hydrocarbon. Intake air was supercharged to 155 kPa abs and its temperature was kept at 58 °C. The HCCI engine was operated at 1000 rpm. Neither hot EGR, nor any other combustion stratification system was utilized in order to investigate the purely hydrocarbon effects on HCCI combustion.

It is well known that ultra-lean combustion can result in higher thermal efficiency, better fuel economy, and greatly reduced NOx emissions. Accomplishing ultra-lean combustion is very difficult with a conventional spark plug, and ignition instability can be cited as one of the factors. Therefore, it is thought that ignition system innovation is important for the achievement of ultra-lean combustion in gasoline engines. This study investigated high-speed plasma ignition as a new ignition system for internal combustion engines. High-speed plasma refers to the transient (non-equilibrated) phase of plasma before formation of an arc discharge; it is obtained by applying high voltage with an ultra-short pulse between coaxial cylindrical electrodes. High-speed plasma can inherently form a multi-channel discharge, with the electrical discharge spreading over a much larger volume than a spark discharge does.

Since the stable operating region of a gasoline-fueled HCCI engine is limited to the part load condition, a mode change between SI and HCCI combustion is required, which poses an issue due to the difference in combustion characteristics. This report focuses on the combustion characteristics in the transitional range. The combustion mode in the transitional range is investigated by varying the internal EGR rate, intake air pressure, and spark advance timing in steady-state experiments. In this parametric study, stable SI-CI combustion is observed. This indicates that the combustion mode transition is possible without misfiring or knocking, regardless of the speed of variable valve mechanism which includes VVA, VVEL, VTEC, VVL and so on, though the response of intake air pressure still remains as a subject to be examined in the actual application.

It is known that the regular gasoline and primary reference fuel (PRF), that have the same research octane number, show the different HCCI engine performance, because of the different phasing and heating value of low temperature heat release. This means that the research octane number is not an “all-round” auto-ignition index, and another index must be developed to evaluate the HCCI combustion characteristics. In this paper, eleven pure hydrocarbon components were blended into twenty three different kinds of model fuels (surrogate fuels), labeled BASE, MC01-MC11 and K01-K11, and the HCCI engine tests were performed under five different intake air temperature conditions to change the auto-ignition characteristic of each hydrocarbon component. As HCCI combustion can be described as a lean and slow gasoline knocking phenomenon, an analysis of HCCI combustion data gives us much more important knowledge of gasoline knocking phenomenon.

This paper presents a new measurement technique for in-cylinder gas temperature and residual gas concentration during the compression stroke of an internal combustion (IC) engine. This technique is based on the infrared absorption of water vapor by a wavelength modulated laser. Wavelength modulation spectroscopy with second harmonic detection (WMS-2f) was adopted to enable the short-path measurements over a wide range of temperatures and pressures corresponding to the late compression stroke in a typical automotive engine. The WMS-2f signal is detected through a bandpass filter at a width of 7.5 kHz, enabling crank angle-resolved measurements. The temperature is determined from the ratio of optical absorption for two overtone transitions of water vapor in the intake gas mixture, and the H2O concentration is determined from this inferred temperature and the absorption for one of the transitions.