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SCR Deactivation Study for OBD Applications

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

Overview of Southwest Research Institute Activities in Engine Technology R&D

The worldwide drive to improved energy efficiency for engine systems is being supported by several engine R&D programs at Southwest Research Institute (SwRI). This research includes large programs in major-market engine categories, such as heavy-duty, non-road, and light-duty; and includes diesel, gasoline, and alternative fuel aspects. This presentation describes several key diesel engine programs being pursued under the SwRI Clean High Efficiency Diesel Engine consortium (CHEDE-VI), whose goal is to demonstrate future diesel technology exceeding 50% brake thermal efficiency. Additionally, SwRI?s High Efficiency Dilute Gasoline Engines consortium (HEDGE-II), is reviewed, where advanced technology for ultra-high efficiency gasoline engines is being demonstrated. The HEDGE-II program is built upon dilute gasoline engine research, where brake thermal efficiencies in excess of 42% are being obtained for engines applicable to the light-duty market. Presenter Charles E.

Evaluation of a NOx Transient Response Method for OBD of SCR Catalysts

OBD requirements for aftertreatment system components require monitoring of the individual system components. One such component can be an NH3-SCR catalyst for NOx reduction. An OBD method that has been suggested is to generate positive or negative spikes in the inlet NH3 concentration, and monitor the outlet NOx transient response. A slow response indicates that the catalyst is maintaining its NH3 storage capacity, and therefore it is probably not degraded. A fast response indicates the catalyst has lost NH3 storage capacity, and may be degraded. The purpose of the work performed at Southwest Research Institute was to assess this approach for feasibility, effectiveness and practicality. The presentation will describe the work performed, results obtained, and implications for applying this method in test laboratory and real-world situations. Presenter Gordon J. Bartley, Southwest Research Institute