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SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.

A literature survey was carried out to examine the advances in knowledge regarding spray impingement on surfaces over the last five years. Published experiments indicate that spray impingement is controlled by various spray parameters, surface conditions, and liquid properties. One disadvantage of the published results is that the experiments have mainly been conducted with water droplets or diesel fuel, often at atmospheric conditions. A sensitivity analysis was performed for one common impingement model. The purpose was to investigate how the model described different phenomena when different parameters were changed, including wall temperature, wall roughness and injection velocity of the spray. The model tested showed sensitivity to surface roughness, whereas changes in wall temperature only resulted in increased evaporation from the surface. The increase of injection velocity resulted in a decrease of fuel on the wall by 70%.