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Technical Paper

Automobile Exhaust Emmision Control- A review

2019-11-21
2019-28-2382
Since the 20th century increase in the number of cars in the major cities is been a point of concern because of the toxic gasses being emitted from the engine of an automobile. These gasses are polluting the atmosphere and degrading the air to breathe. The main gasses responsible for the degradation of air quality are carbon monoxide, hydrocarbon and oxides of nitrogen. There is a necessity to find ways to reduce the pollution emitted into the atmosphere from the automobile. The source of emission is either evaporation from fuel tank or carburetor which is easy to be dealt with or harmful gasses due to improper combustion which is a concern for the environment. The two ways to reduce these emissions are, modification in the engine to minimize the production of harmful gases and to treat the harmful gasses emitted from the engine before blowing it into the atmosphere from the exhaust. Catalysts help to break harmful gasses into smaller compounds that are environment-friendly.
Technical Paper

Experimental and Numerical Prediction of the Pressure Drop Reduction of Catalytic Converter under Various Mass Flow Rate of Exhaust Gas for a Naturally Aspirated Diesel Engine

2019-10-11
2019-28-0030
Nowadays, Diesel emission control strategies are stricter across the globe which caused the rise in need of diesel after treat treatment devices that are more reliable and efficient. The optimized design of the catalytic converter aids in the durability of the product as well as the improvement in efficient operation of the Indian driving cycle. By changing the convergent and divergent cone angles of the catalytic converter, the consequential decrease in pressure drop leads to efficient flow of exhaust gases. The purpose of this study is to design, test, and analyse the catalytic converter in order to reduce the pressure drop in the exhaust system of a naturally aspirated diesel engine using both experimental and CFD techniques. In this study, a Diesel Oxidation Catalyst Catalytic Converter is investigated. For numerical analysis, ANSYS Fluent is used.
Technical Paper

Effects of Prechamber on Efficiency Improvement and Emissions Reduction of a SI Engine Fuelled with Gasoline and CNG

2019-10-07
2019-24-0236
The permanent aim of the automotive industry is the further improvement of the engine efficiency and the simultaneous pollutant emissions reduction. The aim of the study was the optimization of the gasoline and compressed natural gas (CNG) combustion by means of a passive prechamber. This analysis allowed the improvement of the engine efficiency in lean-burn operation condition too. The investigation was carried out in an real small Spark Ignition (SI) engine fueled with Gasoline and CNG and equipped with a proper designed passive prechamber. In particular, Gasoline and CNG were used to analyze the effects of the prechamber on engine performance and associated pollutant emissions. Indicated Mean Effective Pressure, Heat Release Rate and Mass Burned Fraction were used to evaluate the effects on engine performance. Gaseous emissions were measured as well. Particulate Mass, Number and Size Distributions were analyzed.
Technical Paper

Exhaust Purification Performance Enhancement by Early Activation of Three Way Catalysts for Gasoline Engines Used in Hybrid Electric Vehicles

2019-09-09
2019-24-0148
Three-way catalyst (TWC) converters are used to purify the toxic substances such as carbon monoxide (CO), nitrogen oxides (NOx), and hydrocarbons (HC) emitted from gasoline engines. However, a large amount of emissions could be emitted before the TWC reaching its light-off temperature during cold start. For hybrid electric vehicles (HEVs) powered by gasoline engines, the emission purification performance by TWC unfortunately become worse caused by mode switching from engine to battery and vice versa, which is possible to generate cold start conditions over and over for TWC In this study, targeting at reducing the emissions from series HEVs by early activation of TWC, numerical simulations with experiments are carried out. A HEV is tested on a chassis dynamometer under Worldwide Light-duty Test Cycle (WLTC) mode; the upstream and downstream gas conditions of the close-coupled catalyst converter are measured.
Technical Paper

Heat Transfer Characterization of Catalytic Converter Substrates During Warm-Up

2019-09-09
2019-24-0163
The transient heat transfer behavior of a real size automotive catalytic reactor has been simulated with OpenFOAM in 1D. The model takes into consideration the gas-solid convective heat transfer, axial wall conduction and heat capacity effects in the solid phase, but also the chemical reactions of CO and C3H6 oxidations, based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters have been chosen based on the tuning of experimental data. The impact of different initial catalytic converter temperatures, inlet flow temperatures and inlet flow rates have been quantified, even in terms of overall cumulative emissions. . A dimensional analysis is proposed and dimensionless temperature difference and space-time coordinate are defined. Using this suitably modified coordinates, for the case of negligible axial solid conduction, computed solid temperature at the reactor outlet lay on the typical S-curve.
Technical Paper

Analysis of TWC Operation Characteristics in a Euro6 Gasoline Light Duty Vehicle

2019-09-09
2019-24-0162
A Euro6 gasoline light duty vehicle has been tested at the engine dynamometer and the emissions have been analyzed upstream and downstream the Three-Way-Catalyst (TWC) during the WLTP cycle. Catalyst simulations have been used for assessing the processes inside the catalytic converter using a reaction scheme based on 19 brutto reactions (Direct oxidation and reduction, selective catalytic re-ductions with CO, C3H6 and H2, steam reforming, water-gas shift and bulk Ceria as well as surface Ce-ria reactions). The reactions have been parametrized in order to best approximate the measurements. Based on the reactions taken into account, the real vehicle emissions can be predicted with good accu-racy. The simulations show that the cycle emissions are comprising mainly by the cold start contribution as well as discrete emission break-through events during transients.
Technical Paper

Experimental and Numerical Analysis of Latest Generation Diesel Aftertreatment Systems

2019-09-09
2019-24-0142
A comprehensive experimental and numerical analysis of two state-of-the-art diesel AfterTreatment Systems (ATS) for automotive applications is presented in this work. Both systems, designed to fulfill Euro 6 emissions regulations standards, consist of a closed-coupled Diesel Oxidation Catalyst (DOC) followed by a Selective Catalytic Reduction (SCR) catalyst coated on a Diesel Particulate Filter (DPF), also known as SCR on Filter (SCRoF). While the two systems feature the same Urea Water Solution (UWS) injector, major differences could be observed in the UWS mixing device, which is placed upstream of the SCRoF, whose design represents a crucial challenge due to the severe flow uniformity and compact packaging requirements.
Technical Paper

A Novel 1D Co-Simulation Framework for the Prediction of Tailpipe Emissions Under Different IC Engine Operating Conditions

2019-09-09
2019-24-0147
The prediction of the pollutants emitted by internal combustion engines during driving cycles has been a challenge since the introduction of the emission regulation legislation. During the last decade, along with the more tightening limits and increased public concern about the matter of air quality, the possibility of simulating various driving tests with cost effective computing facilities has become a key feature for modern simulation codes. Many 1D simulation tools are available on the market, offering real time models capable of achieving the simulation of any driving cycle in limited time frames. These approaches are based on the extreme simplification of the engine geometry and on the adoption of engine maps, which, for any engine operating condition, give the engine output in terms of power, or torque, and of exhaust gas composition.
Technical Paper

Analysis of the Emission Conversion Performance of Gasoline Particulate Filters Over Lifetime

2019-09-09
2019-24-0156
Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Due to their rapid market introduction, extensive field experience with GPFs is not yet available. Especially for four-way catalytic converters, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. In the first part of the paper, experimental GPF ash loading results are presented. Since most of the ash accumulated in the filter results from the combustion of lubricating oil additives, a burner test bench with a purpose-designed oil injection system was chosen for the investigations. The analysis of the backpressure results show that, contrary to high soot loadings, the ash load has a relatively low impact on engine performance and fuel consumption.
Technical Paper

Analysis and Modeling of NOx Reduction Based on the Reactivity of Cu Active Sites and Brønsted Acid Sites in a Cu-Chabazite SCR Catalyst

2019-09-09
2019-24-0150
In this study, the NOx purification reactivity of a Cu-chabazite SCR catalyst was analyzed over a wide temperature range based on the NH3-SCR mechanism considering Cu redox reactions and reactions on a Brønsted acid site. It was revealed that the De-NOx reactions on the active site of Cu proceeded in different paths at lower and higher temperatures. This means that the rate-limiting step of SCR reactions was changed as each temperature. The reaction rate of NOx purification on a Cu site less than 200 °C was determined by the reaction rate of oxidation of Cu sites. On the other hand, the NH3 adsorption on Cu sites played a dominant role in NOx purification at temperature range higher than 300°C. Moreover, it was also observed that the Cu reaction site took different states at low and high temperatures during the NOx purification and was estimated that the valence state of a Cu site was changed as the temperature increased.
Technical Paper

Development of Three Way Catalyst Aging Model: Application to Real Driving Emission Condition

2019-09-09
2019-24-0047
Further reduction of vehicles pollutant and CO2 emissions is required to prevent global warming and to improve air quality. The exhaust system is designed to ensure low emission during all life of the vehicle. As catalyst aging is affecting the catalyst performance, such impact needs to be consider upfront during the design of the fresh catalyst. Until now, the exhaust system design are evaluated based on real tests for each vehicle, using exhaust lines aged on engine test benches or burner benches. This induces major investigation limitations such as: late evaluation in development cycle, high testing and prototyping cost. The usage of Model Based Development approach can be a powerful way to improve this process by allowing system evaluation under several aging conditions at early development stage. The present study focuses on modelling of the Three Way Catalyst (TWC) aging to predict the mileage impact on tailpipe emissions.
Technical Paper

A New Take on Porous Medium Approach for Modelling Monoliths and Other Multiple Channel Devices

2019-09-09
2019-24-0049
The porous medium approach is widely used to represent high-resistance devices, such as catalysts, filters or heat exchangers. Because of its computational efficiency, it is invaluable when flow losses need to be predicted on a system level. One drawback of using the porous medium approach is the loss of detailed information downstream of the device. Correct evaluation of the turbulence downstream affects the calculation of the related properties, e.g. heat and mass transfer. The novel approach proposed in the current study is based on a modified distribution of the resistance across the porous medium, which allows to account for the single jets developing in the small channels, showing an improved prediction of the turbulence at the exit of the device, while keeping the low computational demand of the porous medium approach. The benefits and limitations of the current approach are discussed and presented by comparing the results with different numerical approaches and experiments.
Technical Paper

One-Dimensional Modeling of a Thermochemical Recuperation Scheme for Improving Spark-Ignition Range Extender Engine Efficiency

2019-09-09
2019-24-0066
Range extender (REx) engines have promise for providing low-cost energy for future battery electric vehicles. Due to their restricted operation range, REx engines provide an opportunity to implement system-level schemes that are less attractive for engines designed for highly transient operation. This paper explores a thermochemical recuperation (TCR) scheme for a 2-cylinder BMW spark-ignition REx engine using a 1-D model implemented in GT-Power™. The TCR reactor employs a unique catalytic heat exchange configuration that enables efficient transfer of exhaust sensible and chemical enthalpy to steam reform the incoming fuel. The engine model without the TCR reactor was validated using experimental emissions and performance data from a BMW engine operating on a test stand. A custom integrated heat exchanger and catalyst model was created and integrated with the validated engine. A parametric modeling sweep was conducted with iso-octane as fuel over a range of reformed fuel fraction.
Technical Paper

Development of a Dedicated CNG Three-Way Catalyst Model in 1-D Simulation Platforms

2019-09-09
2019-24-0074
A growing interest towards heavy-duty engines powered with NG, dictated by stringent regulations in terms of emissions, has made it essential to study a specific Three-Way Catalyst (TWC). Oxygen storage phenomena characterize the catalytic converter efficiency under real world driving operating conditions and, consequently, during strong dynamics in Air-to-Fuel ratio (AFR). A numerical “quasi-steady” model has been set-up to simulate the chemical process inside the reactor. A dedicated experimental campaign has been performed in order to evaluate the catalyst response to a defined λ variation, thus providing the data necessary for the numerical model validation. In fact, goal of the present research activity was to investigate the effect of very fast composition transitions of the engine exhaust typical of the mentioned driving conditions (including fuel cutoffs etc.) on the catalyst performance and on related emissions.
Standard

Engine Oil Performance and Engine Service Classification (Other than "Energy Conserving")

2019-07-16
WIP
J183
This SAE Standard outlines the engine oil performance categories and classifications developed through the efforts of the Alliance of Automobile Manufacturers (Alliance), American Petroleum Institute (API), the American Society for Testing and Materials (ASTM), the Engine Manufacturers Association (EMA), International Lubricant Specification Advisory Committee (ILSAC), and SAE. The verbal descriptions by API and ASTM, along with prescribed test methods and limits are shown for active categories in Table 1 and obsolete categories in Table A1. Appendix A is a historical documentation of the obsolete categories. For purposes of this document, active categories are defined as those (a) for which the required test equipment and test support materials, including reference engine oils and reference fuels, are readily available, (b) for which ASTM or the test developer monitors precision for all tests, and (c) which are currently available for licensing by API EOLCS.
Journal Article

The Effect of NO2/NOx Ratio on the Performance of a SCR Downstream of a SCR Catalyst on a DPF

2019-06-14
Abstract Different aftertreatment systems consisting of a combination of selective catalytic reduction (SCR) and SCR catalyst on a diesel particulate filter (DPF) (SCR-F) are being developed to meet future oxides of nitrogen (NOx) emissions standards being set by the Environmental Protection Agency (EPA) and the California Air Resources Board (CARB). One such system consisting of a SCRF® with a downstream SCR was used in this research to determine the system NOx reduction performance using experimental data from a 2013 Cummins 6.7L ISB diesel engine and model data. The contribution of the three SCR reactions on NOx reduction performance in the SCR-F and the SCR was determined based on the modeling work. The performance of a SCR was simulated with a one-dimensional (1D) SCR model. A NO2/NOx ratio of 0.5 was found to be optimum for maximizing the NOx reduction and minimizing NH3 slip for the SCR for a given value of ammonia-to-NOx ratio (ANR).
Technical Paper

Event-Driven Simulation of Particle-Particle and Particle-Surface Collisions in Ice Crystal Icing

2019-06-10
2019-01-2014
This paper describes an event-driven simulation tool for predicting particle-particle and particle-surface interactions in ice crystal icing (ICI). A new accretion model which is much less empirical than existing models for predicting ICI accretion is also described. Unlike previous models, the new “gouge/bounce model” (GBM) differentiates between (erosion) losses resulting from particle bounce and those resulting from particle gouging. A bounce threshold based on the tangential Stokes number is used to calculate most of the bounce loss. The GBM also predicts ejecta velocities and directions, at least approximately, which is important because most of the mixed-phase mass flux impacting a surface actually bounces off or erodes existing material in ICI, thereby increasing the mass flux downstream.
Technical Paper

Analysis and Automated Detection of Ice Crystal Icing Conditions Using Geostationary Satellite Datasets and In Situ Ice Water Content Measurements

2019-06-10
2019-01-1953
Recent studies have found that high mass concentrations of ice particles in regions of deep convective storms can adversely impact aircraft engine and air probe (e.g. pitot tube and air temperature) performance. Radar reflectivity in these regions suggests that they are safe for aircraft penetration, yet high ice water content (HIWC) is still encountered. The aviation weather community seeks additional remote sensing methods for delineating where ice particle (or crystal) icing conditions are likely to occur, including products derived from geostationary (GEO) satellite imagery that is now available in near-real time at increasingly high spatio-temporal detail from the global GEO satellite constellation.
Technical Paper

Low-Temperature NH3 Storage, Isothermal Desorption, Reactive Consumption, and Thermal Release from Cu-SSZ-13 and V2O5-WO3/TiO2 Selective Catalytic Reduction Catalysts

2019-04-02
2019-01-0735
Worldwide, regulations continue to drive reductions in brake-specific emissions of nitric oxide (NO) and nitrogen dioxide (NO2) from on-highway and nonroad diesel engines. NOx, formed as a byproduct of the combustion of fossil fuels (e.g., natural gas, gasoline, diesel, etc.), can be converted to dinitrogen (N2) through ammonia (NH3) selective catalytic reduction (SCR). In this study, we closely examine the low-temperature storage, isothermal desorption, reactive consumption, and thermal release of NH3 on commercial Cu-SSZ-13 and V2O5-WO3/TiO2 SCR catalysts. Catalyst core-reactor, N2 adsorption (BET) surface area, and in-situ diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS) experiments are utilized to investigate the fundamental chemical processes relevant to low-temperature (T < 250°C) NH3 SCR.
Technical Paper

Effects of Zeolite Structure, Cu Content, Feed Gas Space Velocity, NH3/NOx Ratio, and Sulfur Poisoning on the Performance of Zeolite-Based SCR Catalyst

2019-04-02
2019-01-0736
To meet the increasingly stringent nitrogen oxides (NOx) emission regulations of diesel engines, the selective catalytic reduction (SCR) of NOx with ammonia (NH3) has become the current mainstream technical route. Experiments in the present study included the performance of Cu-Beta catalyst and Cu-CHA catalyst before and after hydrothermal aging, and the effects of Cu content, feed gas space velocity (GHSV), NH3/NOx ratio, and sulfur poisoning on the performance of Cu-CHA catalyst. In the low temperature range (T≤250 °C), the T50 and T90 of Cu-Beta catalyst are 139 °C and 165 °C, respectively, while those of Cu-CHA catalyst are 150 °C and 183 °C, respectively. In the high temperature range (T>400 °C), the NOx conversion of Cu-CHA catalyst is generally higher than that of Cu-Beta catalyst. The temperature window of Cu-Beta catalyst is 154 to 514 °C, while that of Cu-CHA catalyst is 168 to 522 °C. Cu-CHA catalyst exhibits better catalytic activity at medium and high temperatures.
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