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It is generally known that NOx reacts with unburned gasoline, olefins in particular, to form sludge precursors. In this study, the authors investigated the process by which NOx and unburned gasoline mix into the engine oil and analyzed the mechanism whereby stop and go driving accelerates sludge formation. It has been found that NOx detected in the engine oil as nitrite ions mixes into the oil in the crankcase. The NOx concentration in the engine oil increases rapidly when the crankcase gas temperature is nearly equal to the dew point of the water vapor in the crankcase. Unburned gasoline is mainly absorbed into the oil through the oil film on the cylinder walls and the oil in the ring grooves. During low-temperature engine operation in stop-go driving (i.e., when the vehicle is stopped), NOx and unburned gasoline are absorbed into the engine oil and, in high-temperature engine operation (i.e., when the vehicle is moving), NOx and unburned gasoline are released from the oil.

In order to clarify the effect of each gasoline component on engine performance during warm-up, changes in the air-fuel ratio and quantity of wall flow (liquid gasoline on the induction port) were measured using ordinary gasolines and model gasolines consisting of a blend of several hydrocarbons and MTBE (methyl-tertiary-butyl-ether). The unburned air-fuel mixture in a combustion chamber was sampled via a solenoid valve and analyzed by gas chromatography to investigate the vaporization rate of each component. The results show that MTBE has an important effect on driveability because it contains oxygen and easily vaporizes, resulting in a lean mixture in the transient state. The popular driveability index, T50 (50% distillation temperature), does not provide an adequate means of evaluating MTBE-blended gasoline.

An analysis was made of wear factors by investigating the effect of engine operating conditions on valve train wear. It was found that cam nose wear increased as larger amounts of combustion products, including nitrogen oxides and unburned gasoline, became intermixed with the engine oil. Based on these results, a valve train wear test procedure has been developed for evaluating cam nose and rocker arm wear under engine firing conditions. It has been confirmed that this test procedure correlates will with ASTM Sequence VE test and CCMC TU-3 test.