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Technical Paper

The Development of BMW Catalyst Concepts for LEV / ULEV and EU III / IV Legislations 6 Cylinder Engine with Close Coupled Main Catalyst

1998-02-23
980418
To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.
Technical Paper

A New Method for the Investigation of Unburned Oil Emissions in the Raw Exhaust of SI Engines

1998-10-19
982438
The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.
Technical Paper

HC Measurements by Means of Flame Ionization: Background and Limits of Low Emission Measurement

2003-03-03
2003-01-0387
Flame Ionization Detectors (FID) can be used to detect organic hydrocarbons that occur in plastics, lacquers, adhesives, solvents and gasoline. These substances are ionized in the hydrogen flame of the FID. The ionization current that is produced depends on the amount of hydrocarbon in the sample. With the lowering of emissions limits, measuring instruments, including the FID, have to be able to detect very low values. For SULEV (Super-Ultra Low Emissions Vehicle) measurements the accuracy and also the general applicability of the CVS (Constant Volume Sampling) measuring technique are now questioned. Basic understanding is necessary to ask the right questions. One important issue is the science behind the measurement principle of the FID. And in this case especially the influence of contamination of the operating gases, cross sensitivity and data processing on the Limit of Detection (LOD).
Technical Paper

ECU Integrated DSP Based Measurement System for Combustion Analysis

2000-03-06
2000-01-0547
For development of new engines a ‘general purpose ECU’ for spark ignition engines with up to 12 cylinders has been developed. As part of this ECU a DSP (Digital Signal Processor)-based measurement unit for high frequency combustion analysis has been integrated. In this paper, details about this signal processing platform are given. The DSP-unit has 24 analog input channels. 12 channels are used for cylinder pressure measurement; the other 12 channels are general purpose ones. For example, they can be used for ionic current analysis. Additional digital inputs allow measurement of crank speed and crank speed variations. This is an important topic for misfire detection as part of the OBD regulations.
Technical Paper

Research Results on Processes and Catalyst Materials for Lean NOx Conversion

1996-10-01
962041
In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.
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