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The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

Changing of emission levels leads to an increasing demand for a satisfying solution to measure mass emissions of motor vehicles on both, engine and chassis dynamometers. Partial flow systems may fit to the demands. These systems require an exact determination of exhaust volume flow and time aligned concentration measurement. This paper will address these issues and problems related with partial flow sampling. Several exhaust flow measurement systems have been studied and integrated mass results have been checked against the full flow CVS. As the investigations indicate, modal mass calculation from sampling direct exhaust at the end of tailpipe is feasible but not a satisfying solution in equivalency and repeatability in comparison to CVS-results. This is especially the case on emission levels near or below ULEV.

Flame Ionization Detectors (FID) can be used to detect organic hydrocarbons that occur in plastics, lacquers, adhesives, solvents and gasoline. These substances are ionized in the hydrogen flame of the FID. The ionization current that is produced depends on the amount of hydrocarbon in the sample. With the lowering of emissions limits, measuring instruments, including the FID, have to be able to detect very low values. For SULEV (Super-Ultra Low Emissions Vehicle) measurements the accuracy and also the general applicability of the CVS (Constant Volume Sampling) measuring technique are now questioned. Basic understanding is necessary to ask the right questions. One important issue is the science behind the measurement principle of the FID. And in this case especially the influence of contamination of the operating gases, cross sensitivity and data processing on the Limit of Detection (LOD).

Fast and exact measurement of engine oil consumption is a very difficult task. Our aim is to achieve this measurement at a common test bed without engine modifications. We resolved this problem with a new technique using Laser Mass Spectrometry to detect appropriate tracers in the raw engine exhaust. The tracers are added to the engine oil. to the engine oil. For detection of these tracers we use a Laser Mass Spectrometer (LAMS). This is a combination of resonant laser ionization (with an all-solid-state laser) and Time-of-Flight Mass Spectrometry. Currently this is the only way to detect oil originated molecules (like our tracers) in the raw exhaust very fast (50 Hz) and sensitive (ppb-region). Thus, engine mapping of oil consumption over load and speed can be performed in 1-2 days with about 90 measurements. Even measurement during dynamic engine operation is possible, but not quantitative (due to the lack of information about dynamic exhaust gas mass flow).