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Tailored Conversion Coatings for Enhanced Adhesion to Metal

2012-03-21
The use of silane chemistries tailored to promote the adhesion of performance and appearance coatings to metal substrates are requiring new methodologies for measuring, approving, and implementing on commercial aircraft. Engineering performance, lean manufacturing, environmental and employee safety considerations are driving the commercial aerospace industry to replace long standing conversion coating materials and processes. Tailored silane chemistries such as Boegel are being considered for many of these applications. Silanes work by reacting with metal oxides providing a strong covalent bond, cross linking to form a tough barrier and have an organic functional group tailored to react with the specific resin system in the subsequent coating. Traditionally conversion coatings such as anodize and chromate conversion coating performance is validated based on meeting standalone requirements.
Technical Paper

Comparison of Waste Systems

2004-07-19
2004-01-2581
A summary of waste processes and waste process data is presented in the context of mission equivalent system mass. Storage, size reduction, drying, aerobic and anaerobic biodegradation, chemical oxidation, pyrolysis, and post processing are evaluated in the context of probable long-duration missions beyond LEO, and the probable quantities and types of wastes and of the other on-board systems. An assessment of the waste systems described in the ALS Reference Missions Document is presented, and rationale for some changes to these systems is provided.
Technical Paper

Corrosion Testing of Brazed Space Station IATCS Materials

2004-07-19
2004-01-2471
Increased nickel concentrations in the IATCS coolant prompted a study of the corrosion rates of nickel-brazed heat exchangers in the system. The testing has shown that corrosion is occurring in a silicon-rich intermetallic phase in the braze filler of coldplates and heat exchangers as the result of a decrease in the coolant pH brought about by cabin carbon dioxide permeation through polymeric flexhoses. Similar corrosion is occurring in the EMU de-ionized water loop. Certain heat exchangers and coldplates have more silicon-rich phase because of their manufacturing method, and those units produce more nickel corrosion product. Silver biocide additions did not induce pitting corrosion at silver precipitate sites.
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