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Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

Controlled Auto-Ignition (CAI), also known as Homogeneous charge compression ignition (HCCI), has been the subject of extensive research because of their ability to providing simultaneous reduction in fuel consumption and NOx emissions in a gasoline engine. However, due to its limited operation range, combustion mode switching between CAI and spark ignition (SI) combustion is essential to cover the overall operational range of a gasoline engine for passenger car applications. Previous research has shown that the SI-CAI hybrid combustion has the potential to control the ignition timing and heat release process during both steady state and transient operations. However, it was found that the SI-CAI hybrid combustion process is often characterized with large cycle-to-cycle variations, due to the flame instability at high dilution conditions.

In this paper, an experimental study was performed to investigate characteristics of flame propagation and knocking combustion of hydrous (10% water content) and anhydrous ethanol at different air/fuel ratios in comparison to RON95 gasoline. Experiments were conducted in a full bore overhead optical access single cylinder port-fuel injection spark-ignition engine. High speed images of total chemiluminescence and OH* emission was recorded together with the in-cylinder pressure, from which the heat release data were derived. The results show that under the stoichiometric condition anhydrous ethanol and wet ethanol with 10% water (E90W10) generated higher IMEP with at an ignition timing slightly retarded from MBT than the gasoline fuel for a fixed throttle position. Under rich and stoichiometric conditions, the knock limited spark timing occurred at 35 CA BTDC whereas both ethanol and E90W10 were free from knocking combustion at the same operating condition.

The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).

Having achieved CAI-combustion in a 4-cylinder four-stroke gasoline DI engine the effects of ignition timing on the CAI combustion process were investigated through the introduction of spark. By varying the start of fuel injection, the effects on Indicated Specific values for NOx, HC, CO emissions and fuel consumption were investigated for CAI combustion. The CAI combustion process was then assisted by spark and three different ignition timings were studied. The effect on engine performance and the emission specific values were investigated further. The engine speed was maintained at 1500 rpm and lambda was kept constant at 1.2. It was found that with spark-assisted CAI, IMEP and ISNOx values increased as compared with typical CAI. ISHC values were lower for spark-assisted CAI as compared to typical CAI. Heat release data was studied to better understand this phenomenon.

Controlled auto Ignition (CAI) combustion has great potential for reducing both NOx emissions and fuel consumption in IC engines and the application of direct injection technology to the CAI engine adds another dimension of control to the combustion process. In this work an air-assisted injection system was applied to an engine that used residual gas to initiate and control CAI combustion. Injections were performed at Exhaust valve closure (EVC), intake valve opening (IVO) and BDC of the intake/compression stroke and the effects on combustion phasing (i.e. ignition timing and burn duration), engine output, fuel consumption and exhaust emissions analyzed. Injection at EVC gave the best results in terms of engine output, operating range and combustion stability. Injection at IVO generally resulted in the lowest fuel consumption. It was found that injection timing is an effective means of controlling combustion phasing.

Poppet-valve two-stroke gasoline engines can increase the specific power of their four-stroke counterparts with the same displacement and hence decrease fuel consumption. However, knock may occur at high loads. Therefore, the combustion with stratified lean mixture was proposed to decrease knock tendency and improve combustion stability in a poppet-valve two-stroke direct injection gasoline engine. The effect of intake pressure and split injection on fuel distribution, combustion and knock intensity in lean mixture conditions at high loads was simulated with a three-dimensional computational fluid dynamic software. Simulation results show that with the increase of intake pressure, the average fuel-air equivalent ratio in the cylinder decreases when the second injection ratio was fixed at 70% at a given amount of fuel in a cycle.

The NOx emissions during the crank-start and cold fast-idle phases of a GDI engine are analyzed in detail. The NOx emissions of the first 3 firing cycles are studied under a wide set of parameters including the mass of fuel injected, start of injection, and ignition timing. The results show a strong dependence of the NOx emissions with injection timing; they are significantly reduced as the mixture is stratified. The impact of different valve timings on crank-start NOx emissions was analyzed. Late intake and early exhaust timings show similar potential for NOx reduction; 26-30% lower than the baseline. The combined strategy, resulting in a large symmetric negative valve overlap, shows the greatest reduction; 59% lower than the baseline. The cold fast-idle NOx emissions were studied under different equivalence ratios, injection strategies, combustion phasing, and valve timings. Slightly lean air-fuel mixtures result in a significant reduction of NOx.