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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

A task group within the SAE Automotive Corrosion and Protection (ACAP) Committee continues to pursue the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. The program is a cooperative effort with OEM, supplier, and consultant participation and is supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels, but correlations between laboratory test results and in-service performance have not been established. The primary objective of this project is to identify an accelerated laboratory test method that correlates with in-service performance. In this paper the type, extent, and chemical nature of cosmetic corrosion observed in the on-vehicle exposures are compared with those from some of the commonly used laboratory tests

Over the past several years a task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has conducted extensive on-vehicle field testing and numerous accelerated lab tests with the goal of establishing a standard accelerated test method for cosmetic corrosion evaluations of finished aluminum auto body panels. This project has been a cooperative effort with OEM, supplier, and consultant participation and was also supported in part by DOE through USAMP (AMD 309). The focus of this project has been the identification of a standardized accelerated cosmetic corrosion test that exhibits the same appearance, severity, and type of corrosion products that are exhibited on identical painted aluminum panels exposed to service relevant environments. Multi-year service relevant exposures were conducted by mounting panels on-vehicles in multiple locations in the US and Canada.

Engine oils formulated using molybdenum dialkyldithiocarbamate, Mo(dtc)2, additives can provide substantial friction reduction under mixed to boundary lubrication conditions. It has been previously shown that the effectiveness of Mo(dtc)2 is significantly affected by the presence of other additives and by additive interaction and depletion processes occurring during use. In this study, ligand exchange reactions in an additive system containing Mo(dtc)2 and zinc dialkyldithiophosphate, Zn(dtp)2, have been investigated during oxidation in hexadecane and various base oils at 160°C. Samples of different composition obtained from these studies were used in investigations of the effects of original additives and ligand exchange products on friction reducing capability at 45 and 105°C.

Since 2000, an Aluminum Cosmetic Corrosion task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has existed. The task group has pursued the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. A cooperative program uniting OEM, supplier, and consultants has been created and has been supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Prior to this committee's formation, numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels. However, correlations between these laboratory test results and in-service performance have not been established. Thus, the primary objective of this task group's project was to identify an accelerated laboratory test method that correlates well with in-service performance.

An electrochemical testing protocol for assessing the intrinsic corrosion-resistance of creep-resistant magnesium alloys in aqueous environments, and effects of passivating surface films anticipated to develop in the presence of engine coolants is under development. This work reports progress in assessing the relative corrosion resistance of the base metals (AMC-SC1, MRI-202S, MRI-230D, AM50 and 99.98% Mg) in a common test environment, based on a near-neutral pH buffered saline solution, found to yield particularly stable values for the open-circuit or corrosion potential. This approach was found to provide a platform for the eventual assessment of the durability of certain passivating layers expected to develop during exposure of the magnesium alloys to aqueous coolants.

A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

This paper presents the progress of an ongoing vehicle micro corrosion environment study. The goal of the study is to develop an improved method for estimating vehicle corrosion based on the Total Vehicle Accelerated Corrosion Test at the Arizona Proving Ground (APG). Although the APG test greatly accelerates vehicle corrosion compared to the field, the “acceleration factor” varies considerably from site-to-site around the vehicle. This method accounts for the difference in corrosivity of various local corrosion environments from site-to-site at APG and in the field. Correlations of vehicle microenvironments with the macroenvironment (weather) and the occurrence of various environmental conditions at microenvironments are essential to the study. A comparison of results from APG versus field measurements generated using a cold rolled steel based corrosion sensor is presented.

A simulated diesel exhaust is treated with a nonthermal plasma discharge under steady state conditions. The plasma effluent is then passed through a sodium zeolite-Y (NaY) catalyst followed by a platinum oxidation catalyst. Detailed FTIR measurements of gas composition are taken before, between, and after the treatment stages. The plasma discharge causes oxidation of NO primarily to NO2, with methyl nitrate and nitric acid byproducts. At the same time, HC is partially oxidized, creating species such as formaldehyde, acetaldehyde, CO and other partial oxidation products. When this mixture passes over the NaY catalyst, part of the NOx is reduced to N2, with the remainder primarily in the form of NO. Methyl nitrate decomposes to form methanol and NOx, and nitric acid is consumed. There is little HC conversion on this catalyst. Small quantities of HCN and N2O are formed. When the mixture then passes over the platinum catalyst, further NOx conversion occurs.

Meeting upcoming stringent emission standards will require that exhaust gas catalyst systems become active very quickly, function at very high efficiencies and maintain those capabilities at high mileages. This means that contamination of the catalysts by engine oil derived poisons must be minimized. Phosphorus compounds, derived from the zinc dialkyldithio-phosphate (ZDTP) additives that provide antiwear and antioxidant activity, are a principal contaminant that can increase catalyst light off times and reduce catalyst efficiency. Therefore, reducing the concentration of, or eliminating, phosphorus in engine oils is desirable. Doing so, however, requires that oils be reformulated to ensure that wear protection will not be compromised and that oxidation stability will be maintained. To address these concerns, laboratory tests for evaluating oil oxidation and wear performance have been developed and used to evaluate developmental low phosphorus oils.

This paper presents the upgrades and improvements needed to bring an old and seldom used reverberation room test suite up to current standards. The upgrades and improvements included eliminating a below-floor pit that was open to the reverberation room, improving the acoustical diffusion within the room, enlarging the opening between the reverberation room and an adjacent anechoic chamber, renovating the anechoic receiving chamber, constructing an innovative sound transmission loss test fixture, and installing of a high power reverberation room sound system.

Proving Ground cyclic testing was used to evaluate vehicles assembled with electrogalvanized and organic composite coated electrogalvanized steel. These same materials, along with several commonly available precoated steels, were also evaluated as hem flange assemblies on towed trailers at the Proving Ground. Testing was terminated as perforation of some of the assemblies occurred. Pitting depth was used to quantitatively evaluate metal loss.

A laboratory wear test is used to evaluate the wear protection properties of new and used engine oils formulated for FFV service. Laboratory-blended mixtures of these oils with methanol and water have also been tested. The test consists of a steel ball rotating against three polished cast iron discs. Oil samples are obtained at periodic intervals from a fleet of 3.0L Taurus vehicles operating under controlled go-stop conditions. To account for the effects of fuel dilution, some oils are tested before and after a stripping procedure to eliminate gasoline, methanol and other volatile components. In addition to TAN and TBN measurements, a capillary electrophoresis technique is used to evaluate the formate content in the oils. The results suggest that wear properties of used FFV lubricants change significantly with their degree of usage.

The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.

The oxidation chemistry of paraffins, aromatics, olefins and MTBE were examined. Detailed chemical kinetics calculations were carried out for oxidation of these compounds in the engine cycle. The oxidation rates are very sensitive to temperature. At temperatures of over 1400 K (depending on the fuel), all the hydrocarbons are essentially oxidized for typical residence time in the engine. Based on the kinetics calculations, a threshold temperature is defined for the conversion of the fuel species to CO, CO2, H2O and partially oxidized products. The difference in the survival fraction between aromatics and non-aromatics is attributed to the higher threshold temperature of the aromatics.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

Since 1985, the Body Division of the Automotive Corrosion and Prevention Committee of SAE (ACAP) has conducted biannual surveys of automotive body corrosion in the Detroit area. The purpose of these surveys is to track industry wide corrosion protection improvements and to make this information available for public consumption. The survey consists of a closed car parking lot survey checking for perforations, blisters, and surface rust. This paper reports the results of the five surveys conducted to date.

The regulated and non-regulated emissions of a current diesel passenger car and two light-duty diesel trucks with catalysts and particulate traps were measured to better understand the effects of aftertreatment devises on the environment. The passenger car, a 1.8 L IDI TC Sierra, was tested both with and without three different diesel oxidation catalysts (DOC) and with two fuel sulfur levels, 0 and 0.05 wt%. One light-duty truck, a 2.5 L DI NA Transit, was tested on one fuel, 0.05 wt% sulfur, with and without three different particulate trap/regeneration systems and with and without a urea lean NOx catalyst (LNC) system. A second similar Transit was tested on the 0.05 wt% sulfur fuel with an electrically regenerated trap system. The results are compared to each other, regulated emission standards, and to emissions from gasoline vehicles.

The presence of a foreign substance on or within a polymer often affects the mechanical, chemical and thermal properties of the material. The change in strength and rigidity of a polymer resulting from the plasticizing action of a sorbed chemical or due to the withdrawal of an added plasticizer by the leaching operation can seriously affect the useful life of the material. In the real engineering world, incompatible chemicals and lubricants get onto various plastic components unexpectedly through design, manufacturing processes, customers services and repairs. This paper presents a number of case-studies which illustrate how undesirable chemicals found on plastic parts can affect product performance and cause damage to the parts.

Erosion damage to automotive car bodies caused by stones and small sand particles and road debris significantly affects the appearance of paint. Painted engineering plastics as well as precoated sheet steel are affected by erosion phenomenon. Erosion of painted plastic substrates results in cosmetic concerns while that on metal substrates results in cosmetic to perforation corrosion. This work describes a laboratory simulation of erosion of painted plastic substrates by small particles on various paint and substrate types. Gloss loss was used to quantitatively evaluate erosion of painted surfaces. Wear behavior of painted plastic substrates to slag sand impact was evaluated as a function of several variables including paint type (one-component melamine crosslinked (1K) vs. two-component isocyanate crosslinked (2K)), thermal history, and coating modulus. The effect of slag sand type (particle size and chemical composition) was studied.