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The effect of the shape of the EOI was investigated through a pressure-modulated injection system in order to improve the understanding of the last portion of the traditional diesel diffusion combustion process. Here, the combustion recession at EOI is when the combustion of a mixing controlled diesel jet recedes backwards toward the fuel injector nozzle orifice. Combustion recession was observed using combustion luminosity imaging filtered at 309 nm to capture OH* chemiluminescence and 430 nm to capture CH* chemiluminescence, although soot Natural Luminosity (NL) will also be visible in these measurements. Experimental spray vessel results show that for relatively slow EOI decelerations below 1 ×106 to 2 ×106 m/s2, combustion strongly recesses completely back to the nozzle in both OH* and CH*/NL imaging. 1-D jet mixing calculations add support that this strong recession is indeed fuel rich.

The particulate matter (PM) produced from a diesel engine-simulating combustor was characterized in its morphology, microstructure, and fractal geometry by using a unique thermophoretic sampling and Transmission Electron Microscopy (TEM) system. These results revealed that diesel PM produced from the laboratory-scale burner showed similar morphological characteristics to the particulates produced from diesel engines. The flame air/fuel ratio and the particulate temperature history have significant influences on both particle size and fractal geometry. The primary particle sizes were measured to be 14.7 nm and 14.8 nm under stoichiometric and fuel-rich flame conditions, respectively. These primary particle sizes are smaller than those produced from diesel engines. The radii of gyration for the aggregate particles were 83.8 nm and 47.5 nm under these two flame conditions.

A direct-injection natural gas (DING) engine was modified for optical access to allow the use of laser diagnostic techniques to measure species concentrations and temperatures within the cylinder. The injection and mixing processes were examined using planar laser-induced fluorescence (PLIF) of acetone-seeded natural gas to obtain qualitative maps of the fuel/air ratio. Initial acetone PLIF images were acquired in a quiescent combustion chamber with the piston locked in a position corresponding to 90° BTDC. A series of single shot images acquired in 0.1 ms intervals was used to measure the progression of one of the fuel jets across the cylinder. Cylinder pressures as high as 2 MPa were used to match the in-cylinder density during injection in a firing engine. Subsequent images were acquired in a motoring engine at 600 rpm with injections starting at 30, 20, and 15° BTDC in 0.5 crank angle degree increments.