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Pure biodiesel fuel (B100) is typically made of fatty acid methyl esters (FAME). FAME has different physical properties as compared to mineral diesel such as higher surface tension, lower volatility and higher specific gravity. These differences lead to a larger droplet size and thus more wall impingement of the fuel during injection in the combustion chamber. This results in higher levels of fuel dilution as the oil is scraped down into the crankcase by the scraper ring. The lower volatility also makes biodiesel more difficult to evaporate once it enters the crankcase. For these reasons, levels of fuel dilution in biodiesel fueled engines are likely to be higher compared to mineral diesel fueled engines. When in-cylinder dosing is applied to raise the exhaust temperature required for the regeneration of Diesel Particulate Filters (DPF's), biodiesel dilution in the engine oil may be elevated to high levels.

A range of tools including analytical, bench, and engine tests have been used to investigate the viscosity increase mechanism and formulation appetite of the Sequence IIIG engine test. As commonly observed with high temperature tests, the Sequence IIIG has a strong appetite for antioxidants. Base oil also has a strong impact. Base oil volatility has a direct physical impact on viscosity due to the evaporation of light base oil components and the resultant increase of non-volatile additive components. Volatility characteristics are dependent on the distribution of volatile fractions. The relative oxidation and volatility contributions to viscosity increase have been compared between the Sequence IIIG and Sequence IIIF. The impact of base oil volatility is greater in the Sequence IIIG than the Sequence IIIF test.

Modern Passenger Car Motor Oils (PCMOs) are formulated to provide superior wear, oxidation, and deposit control under the most demanding driving conditions. In most PCMOs, zinc dialkyldithiophosphate (ZnDTP) has been the dominant antiwear and antioxidant agent for well over 50 years. Unfortunately, the phosphorus in ZnDTP may partially deactivate the exhaust emission catalyst. To ensure that the catalysts function for at least 120,000 miles, engine manufacturers are exploring phosphorus limitations for upcoming PCMO performance categories. This paper explores the antiwear film formation of low phosphorus engine oils using the Electrical Contact Resistance bench test. A prototype ILSAC GF-4 formulation blended with varying amounts and types of ZnDTP was tested at temperatures typical of operating engines. Secondary ZnDTP was found to produce the best films under the broadest temperature range.

The study described in this paper covers the development of the Sequence IVB low-temperature valvetrain wear test as a replacement test platform for the existing ASTM D6891 Sequence IVA for the new engine oil category, ILSAC GF-6. The Sequence IVB Test uses a Toyota engine with dual overhead camshafts, direct-acting mechanical lifter valvetrain system. The original intent for the new test was to be a direct replacement for the Sequence IVA. Due to inherent differences in valvetrain system design between the Sequence IVA and IVB engines, it was necessary to alter existing test conditions to ensure adequate wear was produced on the valvetrain components to allow discrimination among the different lubricant formulations. A variety of test conditions and wear parameters were evaluated in the test development. Radioactive tracer technique (RATT) was used to determine the wear response of the test platform to various test conditions.

The Sequence IIIG is a newly developed 100 hour test used to evaluate the performance of crankcase engine oils in the areas of high temperature viscosity increase, wear, deposits, pumpability, and ring sticking for the North American GF-4 standard. Data from the ASTM Precision Matrix, completed in the spring of 2003, along with early reference data from the Lubricant Test Monitoring System (LTMS) showed unexpected test results for selected oils and indicated that percent viscosity increase and pumpability were highly correlated with oil consumption. This correlation led to an intensive study of the factors that influence oil consumption and an attempt to compensate for non-oil related oil consumption through a model based adjustment of the results. The study and scrutiny of the IIIG data has led to more uniform oil consumption in the test and improved test precision, and has eliminated the need for a correction equation based on non-oil related oil consumption.

Of all the performance tests in the current International Lubricant Standardization and Approval Committee (ILSAC) GF-3 and GF-4 categories, the Sequence IIIF and Sequence IIIG are among the most difficult for the formulator. The Sequence III engine dynamometer tests place a premium on oxidation, high-temperature deposits, and valve train wear control. Besides appearing in the North American Passenger Car Motor Oil (PCMO) specifications, the Sequence III is required for European gasoline engine oils, for American Petroleum Institute (API) diesel engine oil categories, and for base oil interchanges (BOI) among licensed engine oils. The ability to screen antioxidants for the Sequence III is of special interest for developers of engine oil technology. Antioxidants are the single most expensive component and the search for cost-effective oxidation control is among the top technical hurdles for the North American PCMO categories.

With the impending development of GF-6, the newest generation of engine oil, a new standardized oil oxidation and piston deposit test was developed using Chrysler 3.6 L Pentastar engine. The performance requirements and approval for passenger car light duty gasoline engine oil categories are set by the International Lubricants Standardization and Approval committee (ILSAC) and the American Petroleum Institute (API) using standardized testing protocols developed under the guidance of ASTM, the American Society for Testing and Materials. This paper describes the development of a new ASTM Chrysler oxidation and deposit test that will be used to evaluate lubricants performance for oil thickening and viscosity increase, and piston deposits.

Many modern engine platforms use turbochargers to meet higher fuel economy performance, which is often combined with downsizing the engine displacement. Operating downsized, turbocharged, direct injection engines at low speeds and high loads has led to an abnormal combustion phenomenon known as Low Speed Pre-Ignition (LSPI), wherein the fuel-air mixture ignites before the spark occurs. LSPI can lead to extremely high pressures in the combustion chamber, which can damage hardware such as pistons, piston rings, and spark plugs. Lubricants, fuels, and engine operating conditions have been shown to impact LSPI. Any of these can be modified to improve LSPI performance. One solution which has been used widely in the industry is reformulating the lubricant additive package. In particular, calcium-based detergents have been shown to promote LSPI, while magnesium detergents appear neutral to LSPI.

Engine oils and their additives are formulated to meet required performance areas such as lubrication, detergency, dispersancy, anti-wear, and so on. Understanding degradation of engine oil additives is important to formulate oils with long time durability. Engine oil additives have been found to affect abnormal combustion in turbocharged gasoline direct injection (TGDI) engines, called low speed pre-ignition (LSPI). Some of metal containing additives such as zinc dithiophosphates (ZnDTP) and molybdenum dithiocarbamates (MoDTC) have been found to reduce LSPI events. In this study, we investigated degradation of ZnDTP and MoDTC in gasoline engine operation and effects of the degradation on LSPI performance.