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This work reports on measurement and analysis of the galvanic interaction between steel self-piercing rivets (SPRs) having several different surface conditions and magnesium alloy substrates under consideration for use in automotive structural assemblies. Rivet surface conditions included uncoated steel, conventional Zn-Sn barrel plating and variations of commercial aluminizing processes, including supplemental layers and sealants. Coating characteristics were assessed using open circuit potential (OCP) measurement, potentiodynamic polarization scanning (PDS), and electrochemical impedance spectroscopy (EIS). The degree of galvanic coupling was determined using zero-resistance ammeter (ZRA) and the scanning vibrating electrode technique (SVET), which also permitted characterization of galvanic current flows in situ.

Corrosion tendency is one of the major inhibitors for increased use of magnesium alloys in automotive structural applications. Moreover, systematic or standardized methods for evaluation of both general and galvanic corrosion of magnesium alloys, either as individual components or eventually as entire subassemblies, remains elusive, and receives little attention from professional and standardization bodies. This work reports outcomes from an effort underway within the U.S. Automotive Materials Partnership - ‘USAMP’ (Chrysler, Ford and GM) directed toward enabling technologies and knowledge base for the design and fabrication of magnesium-intensive subassemblies intended for automotive “front end” applications. In particular, subassemblies consisting of three different grades of magnesium (die cast, sheet and extrusion) and receiving a typical corrosion protective coating were subjected to cyclic corrosion tests as employed by each OEM in the consortium.