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Journal Article

Investigation of SCR Catalysts for Marine Diesel Applications

2017-03-28
2017-01-0947
Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.
Journal Article

Investigation of LEV-III Aftertreatment Designs

2011-04-12
2011-01-0301
Proposed LEV-III emission level will require improvements in NMOG, CO and NOx emissions as measured over FTP and US06 emission cycles. Incremental improvements in washcoat technologies, cold start calibration and catalyst system design are required to develop a cost effective solution set. New catalyst technologies demonstrated both lower HC and NOx emissions with 25% less platinum group metals (PGM). FTP and US06 emissions were measured on a 4-cylinder 2.4L application which compares a close-coupled converter and close-coupled + underfloor converter systems. A PGM placement study was performed with the close-coupled converter system employing these new catalyst technologies. Emissions results suggest that the placement of PGM is critical in minimizing emissions and PGM costs.
Technical Paper

Evaluation of Mixer Designs for Large Diesel Exhaust Aftertreatment Systems

2010-10-05
2010-01-1943
The presented work evaluates several mixer designs being considered for use in large Diesel exhaust aftertreatment systems. The mixers are placed upstream of a diesel oxidation catalyst (DOC) in the exhaust system, where a liquid hydrocarbon fuel is injected. DOC exothermic behaviour resulting from each mixer at different operating conditions is evaluated. A gas flow bench equipped with a XY-Table measurement system is used to determine gas velocity, temperature, and hydrocarbon species uniformity, as well as, pressure drop. Experimental mixer data obtained from a flow bench and an engine dynamometer are compared and discussed. The experimental methodology used in this study can be used to evaluate mixers via comprehensive testing.
Technical Paper

SOLID SCR®: Demonstrating an Improved Approach to NOx Reduction via a Solid Reductant

2011-09-13
2011-01-2207
Stringent global emissions legislation demands effective NOx reduction strategies, particularly for the aftertreatment, and current typical liquid urea SCR systems achieve efficiencies greater than 90% [1]. However, with such high-performing systems comes the trade-off of requiring a tank of reductant (urea water solution) to be filled regularly, usually as soon as the fuel fillings or as far as oil changes. Advantages of solid reductants, particularly ammonium carbamate, include greater ammonia densities, enabling the reductant refill interval to be extended several multiples versus a given reductant volume of urea, or diesel exhaust fluid (DEF) [2]. An additional advantage is direct gaseous ammonia dosing, enabling reductant injection at lower exhaust temperatures to widen its operational coverage achieving greater emissions reduction potential [3], as well as eliminating deposits, reducing mixing lengths, and avoiding freeze/thaw risks and investments.
Technical Paper

Performance Characterization of a Thermal Regeneration Unit for Exhaust Emissions Controls Systems

2011-09-13
2011-01-2208
Diesel Particulate Filters have been successfully applied for several years to reduce Particulate Matter (PM) emissions from on-highway applications, and similar products are now also applied in off-highway markets and retrofit solutions. As soot accumulates on the filter, backpressure increases, and eventually exhaust temperatures are elevated to burn off the soot, actively or passively. Unfortunately, in many real-world instances, some duty cycles never achieve necessary temperatures, and the ability of the engine and/or catalyst to elevate exhaust temperatures can be problematic, resulting in overloaded filters that have become clogged, necessitating service attention. An autonomous heat source is developed to eliminate such risks, applying an ignition-based combustor that leverages the current diesel fuel supply, providing necessary temperatures when needed, regardless of engine operating conditions.
Technical Paper

The Effects of Catalytic Converter Location and Palladium Loading on Tailpipe Emissions

2012-04-16
2012-01-1247
Meeting regulated tailpipe emission standards requires a full system approach by automotive engineers encompassing: engine design, combustion system metrics, exhaust heat management, aftertreatment design and exhaust system packaging. Engine and combustion system design targets define desired engine out exhaust constituents, exhaust gas temperatures and oil consumption rates. Protecting required catalytic converter volume in the engine bay for stricter tailpipe emission standards is becoming more difficult. Future fuel economy mandates are leading to vehicle downsizing which is affecting all aspects of vehicle component packaging. In this study, we set out to determine the potential palladium (Pd) cost penalty as a result of increased light-off time required as a catalyst is positioned further away from the engine. Two aged converter systems with different Pd loadings were considered, and EPA FTP-75 emission tested at six different catalyst positions.
Technical Paper

Cause and Effect of Reversible Deactivation of Diesel Oxidation Catalysts

2014-04-01
2014-01-1518
To meet TierII/LEVII emissions standards, light duty diesel (LDD) vehicles require high conversion efficiencies from the Aftertreatment Systems (ATS) for the removal of both Hydrocarbon (HC) and Nitrogen Oxide (NOx) species. The most populous configuration for LDD ATS have the Selective Catalytic Reduction (SCR) catalyst positioned on the vehicle behind the close coupled Diesel Oxidation Catalyst (DOC) and Catalyzed Diesel Particulate Filter (CDPF). This SCR position may require active heating measures which rely on the DOC/CDPF to provide heat through the combustion of HC and CO in the exhaust. Although DOCs are always impacted by their aging conditions, some aging conditions are shown to be both reversible and irreversible.
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