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Over the last two decades, global emission regulations have become more stringent and have required the use of more advanced fuel injection systems. This includes the use of tighter tolerances, more rapid injections and internal components actuated by weaker injection forces. Unfortunately, these design features make the entire system more susceptible to fuel contaminants. Over the last six years, the composition of these contaminants has evolved from hard insoluble debris, such as dust and rocks, to soluble chemical contaminants. Recent research by the diesel engine manufacturers, fuel injection equipment suppliers and the fuel and fuel additive industry has discovered a major source of the soluble chemical contaminant that leads to injector deposits to be derived from cost effective and commonly used additives used to protect against pipeline corrosion.

Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.

A gasoline engine with an electronically controlled fuel injection system has substantially better fuel economy and lower emissions than a carburetted engine. In general, the stability of engine operation is improved with fuel injector, but the stability of engine operation at idle is not improved compared with a carburetted gasoline engine. In addition, the increase in time that an engine is at idle due to traffic congestion has an effect on the engine stability and vehicle reliability. Therefore, in this research, we will study the influence of fuel injection timing, spark timing, dwell angle, and air-fuel ratio on engine stability at idle.

A technique for rapid in situ measurement of the fuel dilution of oil in a diesel engine is presented. Fuel dilution can occur when advanced in-cylinder fuel injection techniques are employed for the purpose of producing rich exhaust for lean NOx trap catalyst regeneration. Laser-induced fluorescence (LIF) spectroscopy is used to monitor the oil in a Mercedes 1.7-liter engine operated on a dynamometer platform. A fluorescent dye suitable for use in diesel fuel and oil systems is added to the engine fuel. The LIF spectra are monitored to detect the growth of the dye signal relative to the background oil fluorescence; fuel mass concentration is quantified based on a known sample set. The technique was implemented with fiber optic probes which can be inserted at various points in the engine oil system. A low cost 532-nm laser diode was used for excitation.

The characteristics of the early development of fuel sprays from pressure swirl atomizer injectors of the type used in direct injection gasoline engines is investigated. Planar laser-induced fluorescence (PLIF) was used to visualize the fuel distribution inside a firing optical engine. The early spray development of three different injectors at three different fuel pressures (3, 5, and 7 MPa) was followed as a function of time in 30 μsec intervals. Four phases could be identified: 1) A delay phase between the rising edge of the injection pulse and the first occurrence of fuel in the combustion chamber, 2) A solid jet or pre-spray phase, in which a poorly atomized stream of liquid fuel during the first 150 μsec of the injection. 3) A wide hollow cone phase, separation of the liquid jet into a hollow cone spray once sufficient tangential velocity has been established and 4) A fully developed spray, in which the spray cone angle is narrowed due to a low pressure zone at the center.

The presence of liquid fuel inside the engine cylinder is believed to be a strong contributor to the high levels of hydrocarbon emissions from spark ignition (SI) engines during the warm-up period. Quantifying and determining the fate of the liquid fuel that enters the cylinder is the first step in understanding the process of emissions formation. This work uses planar laser induced fluorescence (PLIF) to visualize the liquid fuel present in the cylinder. The fluorescing compounds in indolene, and mixtures of iso-octane with dopants of different boiling points (acetone and 3-pentanone) were used to trace the behavior of different volatility components. Images were taken of three different planes through the engine intersecting the intake valve region. A closed valve fuel injection strategy was used, as this is the strategy most commonly used in practice. Background subtraction and masking were both performed to reduce the effect of any spurious fluorescence.

Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure.

A gasoline direct injection fuel spray was observed using a fired, optical access, square cross-section single cylinder research engine and high-speed video imaging. Spray interaction with the piston is described qualitatively, and the results are compared with Computational Fluid Dynamics (CFD) simulation results using KIVA-3V version 2. CFD simulations predicted that within the operating window for stratified charge operation, between 1% and 4% of the injected fuel would remain on the piston as a liquid film, dependent primarily on piston temperature. The experimental results support the CFD simulations qualitatively, but the amount of fuel film remaining on the piston appears to be under-predicted. High-speed video footage shows a vigorous spray impingement on the piston crown, resulting in vapor production.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

Plug flow reactors, simulating engine exhaust gas, are widely used in emissions control research to gain insight into the reaction mechanisms and engineering aspects that controls activity, selectivity, and durability of catalyst components. The choice of relevant hydrocarbon (HC) species is one of the most challenging factor in such laboratory studies, given the variety of compositions that can be encountered in different application scenarios. Furthermore, this challenge is amplified by the experimental difficulties related to introducing heavier and multi-component HCs and analyzing the reaction products.

Comparisons have been made between dual-fuel (80% port-injection gasoline and 20% direct-injection diesel by mass) Highly Premixed Charge Combustion (HPCC) and blended-fuel (80% gasoline and 20% diesel) Low Temperature Combustion (LTC) modes on a 1-L single-cylinder test engine. In the HPCC mode, both early-injection (E-HPCC) and late-injection (L-HPCC) of diesel have been used. The comparisons have been conducted with a fixed fuel injection rate of 50 mg/cycle at 1500 rpm, and with the combustion phasing fixed (by adjusting the injection timing) so that the 50% heat release point (CA50) is at 8° ATDC. The rapid heat release process of LTC leads to the highest maximum pressure rise rate (MPRR). A two-peak heat release process is observed in L-HPCC, resulting in a lower MPRR. The heat release rate and MPRR values for the E-HPCC are comparable to the L-HPCC values. The EHPCC mode provides the lowest NOX emission. The soot emissions for all three modes are low.

In internal combustion engines, a portion of liquid fuel spray may directly land on the liner and mix with oil (lubricant), forming a fuel-oil film (~10μm) that is much thicker than the original oil film (~0.1μm). When the piston retracts in the compression stroke, the fuel-oil mixture may have not been fully vaporized and can be scraped by the top ring into the 1st land crevice and eventually enter the combustion chamber in the format of droplets. Studies have shown that this mechanism is possibly a leading cause for low-speed pre-ignition (LSPI) as the droplets contain oil that has a much lower self-ignition temperature than pure fuel. In this interest, this work aims to study the oil-fuel interactions on the liner during an engine cycle, addressing molecular diffusion (in the liquid film) and vaporization (at the liquid-gas interface) to quantify the amount of fuel and oil that are subject to scraping by the top ring, thereby exploring their implications on LSPI and friction.

The fuel injection process in the port of a firing 4-valve SI engine at part load and 25°C head temperature was observed by a high speed video camera. Fuel was injected when the valve was closed. The reverse blow-down flow when the intake valve opens has been identified as an important factor in the mixture preparation process because it not only alters the thermal environment of the intake port, but also strip-atomizes the liquid film at the vicinity of the intake valve and carries the droplets away from the engine. In a series of “fuel-on” experiments, the fuel injected in the current cycle was observed to influence the fuel delivery to the engine in the subsequent cycles.

The modern diesel engine is used around the world to power applications as diverse as passenger cars, heavy-duty trucks, electrical power generators, ships, locomotives, agricultural and industrial equipment. The success of the diesel engine results from its unique combination of fuel economy, durability, reliability and affordability - which drive the lowest total cost of ownership. The diesel engine has been developed to meet the most demanding on-highway emission standards, through the introduction of advanced technologies such as: electronic controls, high pressure fuel injection, and cooled exhaust gas recirculation. The standards to be introduced in the U.S. in 2007 will see the introduction of the Clean Diesel which will achieve near-zero NOx and particulate emissions, while retaining the customer values outlined above.

Photographic and performance studies with a Rapid Compression Machine at the Massachusetts Institute of Technology have been used to develop insight into the role of mixing in diesel engine combustion. Combustion photographs and performance data were analyzed. The experiments simulate a single fuel spray in an open chamber diesel engine with direct injection. The effects of droplet formation and evaporation on mixing are examined. It is concluded that mixing is controlled by the rate of entrainment of air by the fuel spray rather than the dynamics of single droplets. Experimental data on the geometry of a jet in a quiescent combustion chamber were compared with a two-phase jet model; a jet model based on empirical turbulent entrainment coefficients was developed to predict the motion of a fuel jet in a combustion chamber with swirl. Good agreement between theory and experiment was obtained.

A model has been developed to predict the performance of the Texaco Controlled Combustion, Stratified Charge Engine starting from engine geometry, fuel characteristics and the operating conditions. This performance model divides the engine cycle into the following phases: Intake, Compression, Rapid Combustion, Mixing-Dominated Expansion, Heat-Transfer Dominated Expansion and Exhaust. During the rapid combustion phase, the rate of heat release is assumed to be controlled by the rate of fuel injection and the air-to-fuel ratio. The burning rate in the mixing controlled stage appears to be dominated by the rate of entrainment of the surrounding gas by the plume of burning products and this rate is assumed to be controlled by the turbulent eddy entrainment velocity. A plume geometry model has been developed to obtain the surface area of the plume for entrainment during the mixing dominated phase.

The influence of charge motion and fuel injection characteristics on diesel combustion was studied in a rapid compression machine (RCM), a research apparatus that simulates the direct-injection diesel in-cylinder environment. An experimental data base was generated in which inlet air flow conditions (temperature, velocity, swirl level) and fuel injection pressure were independently varied. High-speed movies using both direct and shadowgraph photography were taken at selected operating conditions. Cylinder pressure data were analyzed using a one-zone heat release model to calculate ignition delay times, premixed and diffusion burning rates, and cumulative heat release profiles. The photographic analysis provided data on the liquid and vapor penetration rates, fuel-air mixing, ignition characteristics, and flame spreading rates.

The heat transfer characteristics of impinging diesel sprays were studied in a Rapid Compression Machine. The temporal and spatial distributions of the heat transfer around the impingement point -were measured by an array of high frequency response surface thermocouples. Simultaneously, the flow field of the combusting spray was photographed with high speed movie through the transparent head of the apparatus. The results for the auto-ignited fuel sprays were compared to those of non-combusting sprays which were carried out in nitrogen. The values of the heat flux from the combusting sprays were found to be substantially different from those of the non-combusting sprays. The difference was attribute to the radiative heat transfer and the combustion generated bulk, motion and small scale turbulence.

The in-cylinder hydrocarbon (HC) mole fraction was measured on a cycle-resolved basis during simulated starting and warm-up of a port-injected single-cylinder SI research engine on a dynamometer. The measurements were made with a fast-response flame ionization detector with a heated sample line. The primary parameters that influence how rapidly a combustible mixture builds up in the cylinder are the inlet pressure and the amount of fuel injected; engine speed and fuel injection schedule have smaller effects. When a significant amount of liquid fuel is present at the intake port in the starting process, the first substantial firing cycle is often preceded by a cycle with abnormally high in-cylinder HC and low compression pressure. An energy balance analysis suggests that a large amount of liquid vaporization occurs within the cylinder in this cycle.

Numerical calculations of the fuel spray structure from a high-pressure swirl injector were used to enable the interpretation of experimental observations obtained in hot, hollow-cone fuel sprays issued into sub-atmospheric-pressure environments. The experiments show that the spray becomes narrower, more compact, but with a relatively long penetration depth. Model input parameters, including the droplet size distribution, early vapor production, and initial cone angle, were modified to determine which spray characteristics are important in recreating observed spray structures. A very small mean droplet diameter is needed to recreate the experimentally observed structure of the high-temperature, low-pressure sprays. Vapor addition to the emerging spray is then required to increase the axial penetration and provide the observed vapor core.