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GDI (Gasoline Direct Injection) engine adopting new combustion control technologies was developed and introduced into Japanese domestic market in August of 1996. In order to extend its application to the European market, various system modifications have been performed. Injectors are located with a smaller angle to the vertical line in order to improve the combustion stability in the higher speed range. A new combustion control method named “two-stage mixing” is adopted to suppress the knock in the low speed range. As a result of this new method, the compression ratio was increased up to 12.5 to 1 while increasing the low-end torque significantly. Taking the high sulfur gasoline in the European market into account, a selective reduction lean-NOx catalyst with improved NOx conversion efficiency was employed. A warm-up catalyst can not be used because the selective reduction lean NOx catalyst requires HC for the NOx reduction.

Protection of the Earth's environment by means of energy saving and cleaning up of air pollution on a global scale is one of the most important subjects in the world today. Because of this, the requirements for better fuel economy and cleaner exhaust emissions of internal combustion engines have been getting stronger, and, in particular, simultaneous reduction in nitrogen oxides (NOx) and particulate matter (PM) from heavy-duty diesel engines (HDDEs) without degrading fuel economy has become a major subject. Mitsubishi Motors Corporation (MM) has been selling diesel-powered heavy-duty trucks in the U.S. market since 1985 and has agressively carried out development work for meeting the 1991 model year exhaust emission standards.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.

In this paper, we studied the influence of support materials on Pd in three-way catalysts for the aim of enhancing the durability of Pd, particularly CO and NOx conversion efficiencies which are usually seriously damaged after aging. Since the durability of precious metals was found to be strongly influenced by the support material chosen, it should be possible to optimize catalyst performance by finding the appropriate support. The performance of Pd three-way catalysts with different support materials (Aluminum oxide, Cerium - Zirconium Oxide, Cerium - Zirconium -Yttrium Oxide, Zirconium Oxide, or Titanium Oxide) was compared after high temperature agings under various gas conditions. To assess Pd deterioration, the crystallite size of Pd was measured with XRD and the micro surface was observed by FE-SEM. The performance of the catalysts was evaluated.

Three-way catalysts which remove different kinds of pollutants, such as CO, THC(total hydro-carbon) and NOx, simultaneously from the automotive exhaust gas employ Rhodium(Rh) in combination with Platinum(Pt) and Palladium(Pd). Rh is the most effective for reducing NOx to N2, but Rh is the most expensive of these precious metals. The ratio of Rh to Pt applied for automobiles frequently exceeds the natural production. The gap between supply and demand of Rh sometimes causes the big price fluctuation. Accordingly, many attempts to reduce the amount of Rh loaded or to develop non-Rh three-way catalysts have been made. Although Pd catalysts are considered to be promising candidates for non-Rh automotive three-way catalysts, some performance are still inferior to Pt-Rh catalysts. We have found that an excellent three-way catalytic activity appears by compounding new Perovskite-structured oxides with Pd and auxiliary oxides.

In order to reduce exhaust emission and combustion noise and to improve fuel consumption, the effects of the combustion system parameters of a diesel engine, such as injection pressure, injection nozzle hole diameter, swirl ratio, and EGR rate on exhaust emissions, combustion noise and fuel consumption are investigated and described in detail by analyzing rate of heat release, needle valve lift and injection pressure. Based on these results, reduction of exhaust emission and combustion noise and improvement of fuel consumption are described in the latter part of this paper. These results are shown as follows. The smaller nozzle hole diameter is effective for reducing smoke and PM, and by optimizing the injection timing and swirl ratio, NOx can also be reduced. In addition to the above, by applying EGR and higher injection pressure it is possible to improve the fuel consumption with the remaining low NOx and PM.

In the diesel engine industry, the growing trends are toward wider use of electronically controlled high pressure fuel injection equipment to provide better engine performance, while conforming to the stringent exhaust emission standards. Although there have been some recent announcements of a diesel engine that applies an electronically controlled common rail type fuel injection system, there is little literature published about any attempt to reduce both exhaust emissions and noise and to improve engine performance by varying injection pressure and injection timing independently and introducing pilot injection in combination. This paper describes the details of a study made on the parameters associated with injection timing, injection pressure and pilot injection and the procedures for their optimization, with an electronically controlled common rail type fuel injection system installed in an in-line 6-cylinder 6.9 liter turbocharged and intercooled DI diesel engine.

In this study a new water injection system was applied to an 11 liter naturally aspirated DI diesel engine in order to reduce exhaust emissions. In this system, the water and fuel were arranged in the injection nozzle during the time between injections as fuel, water and then fuel. The fuel and water were then injected into the cylinder in that order. The tests were conducted at several engine operating conditions from the Japanese 13 mode test cycle to clarify effects of water injection on exhaust emissions and fuel consumption. The results showed that NOx reduction was directly proportional to the relative amount of water injection, regardless of engine speed and load. By using the optimal relative amount of water injection at each engine operating condition, total NOx and particulate matter (PM) in the Japanese 13 mode test cycle were reduced by 50% and 25%, respectively, without a fuel consumption penalty.

The major problems of the various mixture formation concepts for direct injection gasoline engines that have been proposed up to the present were caused by the difficulties of preparing the mixture with adequate strength at spark plug in wide range of engine operating conditions. Novel combustion control technologies proposed by Mitsubishi is one of the solution for these problems. By adopting upright straight intake ports to generate air tumble, an electromagnetic swirl injector to realize optimized spray dispersion and atomization and a compact piston cavity to maintain charge stratification, it has become possible to achieve super-lean stratified combustion for higher thermal efficiency under partial loads as well as homogeneous combustion to realize higher performance at full loads. GDI™ (Gasoline Direct Injection) engine adopting these technologies is developed. At partial loads, fuel economy improvement exceeding 30 % is realized.

In this study three EGR methods were applied to a 12 liter turbocharged and intercooled Dl diesel engine, and the exhaust emission and fuel consumption characteristics were compared. One method is the Low Pressure Route system, in which the EGR is taken from down stream of the turbine to the compressor entrance. The other two systems are variations of the High Pressure Route system, in which the EGR is taken from the exhaust manifold to the intake manifold. One of the two High Pressure Route EGR systems is with back pressure valve located at downstream of the turbine and the other uses a variable geometry(VG) turbocharger. It was found that the High Pressure Route EGR system using VG turbocharger was the most effective and practical. With this method the EGR area could be enlarged and NOx reduced by 22% without increase in smoke or fuel consumption while maintaining an adequate excess air ratio.