Search Results

A Mercedes E320 CDI vehicle has been modified for more optimal operation on Gas-To-Liquids (GTL) diesel fuel, in order to demonstrate the extent of exhaust emission reductions which are enabled by the properties of this fuel. The engine hardware changes employed comprised the fitment of re-specified fuel injectors and the reduction of the compression ratio from 18:1 to 15:1, as well as a re-optimisation of the software calibration. The demonstration vehicle has achieved a NOx emission of less that 0.08 g/km in the NEDC test cycle, while all other regulated emissions still meet the Euro 4 limits, as well as those currently proposed for Euro 5. CO2 emissions and fuel consumption, were not degraded with the optimised engine. This was achieved whilst employing only cost-neutral engine modifications, and with the standard vehicle exhaust system (oxidation catalyst and diesel particulate filter) fitted.

External Exhaust Gas Recirculation, EGR, is a central issue in controlling emissions in up-to-date diesel engines. An empirical model has been developed that calculates the EGR ratio as a function of the engine speed, the engine load and special characteristics of the heat release rate. It was found that three combustion characteristics correlate well with the EGR ratio. These characteristics are the ignition delay, the premixed combustion ratio and the mixing-controlled combustion ratio. The calculation of these characteristics is based on parameter subsets, which were determined using an optimization routine. The model presented was developed based on these optimized characteristics.

To fulfill future emission standards for diesel engines, combined after-treatment systems consisting of different catalyst technologies and diesel particulate filters (DPF) are necessary. For designing and optimizing the resulting systems of considerable complexity, effective simulation models of different catalyst and DPF technologies have been developed and integrated into a common simulation environment called ExACT (Exhaust After-treatment Components Toolbox). This publication focuses on a model for the NOx storage and reduction catalyst as a part of that simulation environment. A heterogeneous, spatially one-dimensional (1D), physically and chemically based mathematical model of the catalytic monolith has been developed. A global reaction kinetic approach has been chosen to describe reaction conversions on the washcoat. Reaction kinetic parameters have been evaluated from a series of laboratory experiments.

A numerical model describing the ammonia based SCR process of NOX on zeolite catalysts is presented. The model is able to simulate coated and extruded monoliths. The development of the reaction kinetics is based on a study which compares the activity of zeolite and vanadium based catalysts. This study was conducted in a microreactor loaded with washcoat powder and with crushed coated monoliths. A model for the SCR reaction kinetics on zeolite catalysts is presented. After the parameterization of the reaction mechanism the reaction kinetics were coupled with models for heat and mass transport. The model is validated with laboratory data and engine test bench measurement data over washcoated monolith catalysts. A numerical simulation study is presented, aiming to reveal the differences between zeolite and vanadium based SCR catalysts.

This paper presents velocity and pressure measurements obtained around an isolated wheel in a rotating and stationary configuration. The flow field was investigated using LDA and a total pressure probe in the model scale wind tunnel at IVK/FKFS. Drag and lift were determined for both configurations as well as for the wheel support only. These results were used as a reference for comparing numerical results obtained from two different CFD codes used in the automotive industry, namely STAR-CD™ and PowerFLOW™. The comparison gives a good overall agreement between the experimental and the simulated data. Both CFD codes show good correlation of the integral forces. The influence of the wheel rotation on drag and lift coefficients is predicted well. All mean flow structures which can be found in the planes measured with LDA can be recognized in the numerical results of both codes. Only small local differences remain, which can be attributed to the different CFD codes.

After-treatment systems (ATS) consisting of new catalyst technologies and particulate filters will be necessary to meet increasingly stringent global regulations limiting particulate matter (PM) and NOx emissions from heavy duty and light duty diesel vehicles. Fuels and lubes contain elements such as sulfur, phosphorus and ash-forming metals that can adversely impact the efficiency and durability of these systems. Investigations of the impact of lubricant formulation on the transfer of ash-forming elements to diesel particulate filters (DPF) and transfer of sulfur to NOx storage catalysts were conducted using passenger car diesel engine technology. It was observed that for ATS configurations with catalyst(s) upstream of the DPF, transfer of ash-forming elements to the DPF was significantly lower than expected on the basis of oil consumption and lube composition. Sulfur transfer strongly correlated with oil consumption and lubricant sulfur content.

To meet future emission levels the industry is trying to reduce tailpipe emissions by both, engine measures and the development of novel aftertreatment concepts. The present study focuses on a joint development of aftertreatment concepts for gasoline engines that are optimized in terms of the exhaust system design, the catalyst technology and the system costs. The best performing system contains a close-coupled catalyst double brick arrangement using a new high thermal stable catalyst technology with low precious metal loading. This system also shows an increased tolerance against catalyst poisoning by engine oil.

We are the first to report about a micromachined flow sensor directly integrated in the Common Rail injection nozzle body between the double guidance and the tip of the nozzle. The thermal measurement principle is chosen, because it enables a very precise and fast detection of gaseous and liquid mass flows. Additionally, the velocity field in the nozzle is only slightly influenced by the integration of the sensor in the nozzle body due to the negligible height of the sensitive layer. For a hot film anemometer, a high pressure stable ceramic substrate can be used, fabricated in a low cost batch process. The technology, to fabricate the sensor, as well as the first flow measurements, carried out at a high pressure test set up, are presented.

This paper describes the results of a joint development program focussing on the introduction of the new generation of Pt/Rh-technology for current and future emission standards as a cost effective alternative to the in serial Pd/Rh based exhaust gas concepts. In the initial phase of the program combinations of Pd- and Pt-based three-way catalyst technologies were evaluated on vehicles equipped with a 8 cylinder engine. One goal in this portion of the study was to achieve technical equivalence between a viable Pd-based technology and the new Pt/Rh technology in the underfloor position at lower precious metal loading. A combination of a close-coupled Pd/Rh technology and the new Pt/Rh in the underfloor position was able to meet the emission targets at significant lower costs of the system after a catalyst aging that resembles more than 100.000 km of vehicle German highway driving.

The influence of adsorption and desorption processes on the non-thermal plasma enhanced catalytic reduction of NOx on NaZSM5- and Al2O3-based lean-NOx catalysts (Pt-NH4ZSM5, Cu-NaZSM5, Fe-NaZSM5, Pt-Al2O3, Pd-Al2O3, CuO-Al2O3, Ag-Al2O3) was investigated by temperature programmed reaction experiments in the temperature range from 100 °C to 600 °C. Dodecane was used as a reducing agent. Strong HC adsorption- and desorption effects were observed on the zeolite catalysts, which were not influenced by plasma-pretreatment. Adsorption of NO2 and desorption of NO occurred on Al2O3-based catalysts. By plasma-pretreatment adsorption of NO2 was induced at low temperatures. NOx-reduction rates of the catalysts Cu-NaZSM5, Fe-NaZSM5, and the Ag-Al2O3 were increased substantially by plasma-pretreatment. Both plasma-induced and catalytic oxidation of HCs were limiting factors of the NOx-reduction obtained on these catalysts.

The likely transition from today's conventional to future alternative fuels will be discussed. It will be shown that in the very long term renewable fuels might be the most promising road fuels with respect to low CO2 emissions. In the short and medium term, however, liquid alternative fuels will prevail being produced initially from natural gas and later increasingly from biomass. Methanol, Ethanol, GTL Hydrocarbons and other fuels are still under study since lowest WTW CO2 emissions and overall system costs are not yet clarified. The availability of alternative fuels in large quantities will depend on the costs for production and infra-structure, and not least of all, on the market benefits of the resulting fuel / power train systems in a holistic assessment. Cost trends for conventional and alternative fuels will be discussed.

The launching of direct injection gasoline engines is currently one of the major challenges for the automotive industry in the European Union. Besides its potential for a notable reduction of fuel consumption, the engine with direct gasoline injection also offers increased power during stoichiometric and stratified operation. These advantages will most probably lead to a significant market potential of the direct injection concept in the near future. In order to meet the increasingly more stringent European emission levels (EURO IV), new strategies for the exhaust gas aftertreatment are required. The most promising technique developed in recent years, especially for NOx conversion in lean exhaust gases, is the so-called NOx storage catalyst.

In view of tight emission standards, injection strategies to reduce raw HC-emissions during the cold starting of port fuel injected engines are evaluated in this study. The relevance of spray targeting and atomization is outlined in the first part of this paper. The foundation and performance of different injector concepts with respect to spray characteristics are discussed. Laboratory experiments demonstrate that concepts relying on auxiliary energy, such as air-assistance, fuel heating and injection at elevated system pressures, are capable of producing spray droplet sizes in the SMD-range of 25μm. For future injection strategies aimed at the compliance of SULEV emission levels, this target value is considered to be essential. In the second part of this paper, emission tests of selected injector concepts are carried out using a V6-3.2I ULEV engine operated both in a vehicle and on a test bench.

In view of limited crude oil resources, alternative fuels for internal combustion engines are currently being intensively researched. Synthetic fuels from natural gas offer a promising interim option before the development of CO2-neutral fuels. Up to a certain degree, these fuels can be tailored to the demands of modern engines, thus allowing a concurrent optimization of both the engine and the fuel. This paper summarizes investigations of a Gas-To-Liquid (GTL) diesel fuel in a modern, post-EURO 4 compliant diesel engine. The focus of the investigations was on power output, emissions performance and fuel economy, as well as acoustic performance, in comparison to a commercial EU diesel fuel. The engine investigations were accompanied by injection laboratory studies in order to assist in the performance analyses.

The results of a comprehensive experimental investigation into the exhaust emission performance and combustion properties of neat and blended Gas-To-Liquids (GTL) diesel fuel are presented. A sulphur-free European diesel fuel was used as the reference fuel, and two blends of the GTL diesel fuel with the reference fuel, containing 20% and 50% GTL diesel fuel respectively, were investigated. The study was based on a Mercedes Benz 2.2 liter passenger car diesel engine and presents emission data for both the standard engine calibration settings, as well as settings which were optimized to match the characteristics of each fuel. Vehicle emission tests showed that the GTL diesel fuel results in reductions in HC and CO emissions of greater than 90%, while PM is reduced by 30%, and NOx remains approximately unchanged. Engine bench dynamometer tests showed reductions in soot of between 30% and 60%, and NOx reductions of up to 10% with the GTL diesel fuel, depending on the operating point.

In this article model-based controller design techniques are investigated for the transient operation of a common-rail diesel engine in order to optimize driveability and to reduce soot emissions. The computer-aided design has benefits in reducing controller calibration time. This paper presents a nonlinear control concept for the coordinated control of the exhaust gas recirculation (EGR) valve and the variable geometry turbocharger (VGT) in a common-rail diesel engine. The overall controller structure is set up to regulate the total cylinder air-charge with a desired fresh air-charge amount by means of controlling the intake manifold pressure and estimating the fresh air-charge inducted into the cylinders. During varying engine operating conditions the two control loops are coordinated by a compensation of the EGR valve action through the VGT controller.

Automotive catalysts close coupled to gasoline engines operated under high load are frequently subjected to bed temperatures well above 950 °C. Upon deceleration engine fuel cut is usually applied for the sake of fuel economy, robustness and driveability. Even though catalyst inlet gas temperatures drop down immediately after fuel cut - catalyst bed temperatures may rise significantly. Sources for catalyst temperature rise upon deceleration with fuel cut are discussed in this contribution.

A 1D+1D numerical model describing the ammonia based SCR process of NO and NO2 on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. Basing on a fundamental investigation of the catalytic processes a reaction mechanism for the NO/NO2 - NH3 reacting system is proposed and modeled. After the parameterization of the reaction mechanism the reaction kinetics have been coupled with models for heat and mass transport. Model validation has been performed with engine test bench experiments. Finally the model has been applied to study the influence of NO2 on SCR efficiency within ETC and ESC testcycles, Additional simulations have been conducted to identify the potential for catalyst volume reduction if NO2 is present in the inlet feed.

This paper describes work supporting the development of a new Diesel particulate trap system for heavy duty vehicles based on porous sintered metal materials that exhibit interesting characteristics with respect to ash tolerance. Experimental data characterizing the material (permeability, soot and ash deposit properties) are obtained in a dedicated experimental setup in the side-stream of a modern Diesel engine as well as in an accelerated ash loading rig. System level simulations coupling the new media characteristics to 3-D CFD software for the optimization of complete filter systems are then performed and comparative assessment results of example designs are given.

A two-dimensional numerical model describing the ammonia based SCR-process on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. For the determination of the intrinsic kinetics of the various NH3-NOx reactions, unsteady microreactor experiments were used. In order to account for the influence of transport effects the kinetics were coupled with a fully transient two-phase 1D+1D monolith channel model. The model has been validated extensively with laboratory data and engine test bench measurements. After validation the model has been applied to calculate catalyst NOx conversion maps, which were used to define catalyst sizes. Additional simulations were conducted studying the influence of cell density and NH3-dosage ratio.