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Journal Article

Real-time Sensing of Particulate Matter in a Vehicle Exhaust System

2017-03-28
2017-01-1639
Onboard diagnostic regulations require performance monitoring of diesel particulate filters used in vehicle aftertreatment systems. Delphi has developed a particulate matter (PM) sensor to perform this function. The objective of this sensor is to monitor the soot (PM) concentration in the exhaust downstream of the diesel particulate filter which provides a means to calculate filter efficiency. The particulate matter sensor monitors the deposition of soot on its internal sensing element by measuring the resistance of the deposit. Correlations are established between the soot resistance and soot mass deposited on the sensing element. Currently, the sensor provides the time interval between sensor regeneration cycles, which, with the knowledge of the exhaust gas flow parameters, is correlated to the average soot concentration.
Technical Paper

Thermally-Induced Microstructural Changes in a Three-Way Automotive Catalyst

1997-10-01
972905
The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.
Technical Paper

Palladium/Rhodium Dual-Catalyst LEV 2 and Bin 4 Close-Coupled Emission Solutions

2007-04-16
2007-01-1263
Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.
Technical Paper

Emission Formation Mechanisms in a Two-Stroke Direct-Injection Engine

1998-10-19
982697
Engine tests were conducted to study the effect of fuel-air mixture preparation on the combustion and emission performance of a two-stroke direct-injection engine. The in-cylinder mixture distribution was altered by changing the injection system, injection timing, and by substituting the air in an air-assisted injector with nitrogen. Two injection systems which produce significantly different mixtures were investigated; an air-assisted injector with a highly atomized spray, and a single-fluid high pressure-swirl injector with a dense penetrating spray. The engine was operated at overall A/F ratios of 30:1, where stratification was necessary to ensure stable combustion; and at 20:1 and 15:1 where it was possible to operate in a nearly homogeneous mode. Moderate engine speeds and loads were investigated. The effects of the burning-zone A/F ratio were isolated by using nitrogen as the working fluid in the air-assist injector.
Technical Paper

Dynamic EGR Estimation for Production Engine Control

2001-03-05
2001-01-0553
A dynamic EGR State Estimator (ESE) intended for production engine management systems (EMS) implementation is presented. It better describes the development of external exhaust gas recirculation (EGR) concentration at the engine intake ports during EGR transients than traditional models. The dynamics of EGR concentration time and spatial development in the intake manifold are described as a perfect mixing model in the intake manifold plenum volume and non-mixing plug flow in the intake manifold runners. The time scale of EGR transients precludes the use of traditional EGR measurement techniques for model verification. Instead a wide range air fuel (WRAF) sensor is used. Results are shown for a large variation in operating conditions and compared to the performance of a traditional model.
Technical Paper

Comparative Study of Hybrid Powertrain Strategies

2001-08-20
2001-01-2501
Hybrid electric vehicles have the potential to reduce air pollution and improve fuel economy without sacrificing the present conveniences of long range and available infrastructure that conventional vehicles offer. Hybrid vehicles are generally classified as series or parallel hybrids. A series hybrid vehicle is essentially an electric vehicle with an on-board source of power for charging the batteries. In a parallel hybrid vehicle, the engine and the electric motor can be used to drive the vehicle simultaneously. There are various possible configurations of parallel hybrid vehicles depending on the role of the electric motor/generator and the engine. In this paper, a comparative study of the drivetrains of five different hybrid vehicles is presented. The underlying design architectures are examined, with analysis as to the tradeoffs and advantages represented in these architectures.
Technical Paper

Solid Oxide Fuel Cell Auxiliary Power Unit - A Development Update

2002-03-04
2002-01-0411
Delphi Automotive Systems and BMW are jointly developing Solid Oxide Fuel Cell (SOFC) technology for application in the transportation industry primarily as an on-board Auxiliary Power Unit (APU). In the first application of this joint program, the APU will be used to power an electric air conditioning system without the need for operating the vehicle engine. The SOFC based APU technology has the potential to provide a paradigm shift in the supply of electric power for passenger cars. Furthermore, by supplementing the conventional fuel with reformate in the internal combustion engine, extremely low emissions and high system efficiencies are possible. This is consistent with the increasing power demands in automobiles in the new era of more comfort and safety along with environmental friendliness. Delphi Automotive Systems and BMW were successful in demonstrating an Auxiliary Power Unit (APU) based on Solid Oxide Fuel Cell (SOFC) technology in February, 2001.
Technical Paper

Impact of Alkali Metals on the Performance and Mechanical Properties of NOx Adsorber Catalysts

2002-03-04
2002-01-0734
Performance of two types of NOx adsorber catalysts, one based on Ba and the other based on Ba with alkali metals, was compared fresh and after thermal aging. Incorporation of sodium(Na), potassium(K) and cesium(Cs) into NOx adsorber washcoat containing barium significantly increases the NOx conversions in the temperature range of 350-600°C over that of the alkali metal free NOx adsorber catalysts. NOx performance benefit and HC performance penalty were observed on both engine dynamometer and vehicle tests for the “Ba+alkali metals” NOx adsorber catalysts. “Ba+alkali metals” NOx adsorber catalysts also demonstrate superior sulfur resistance with better NOx performance after repeated sulfur poisonings and desulfations over the “Ba based” NOx adsorber catalysts.
Technical Paper

A Comparison of Extruded Powder Metal Heating Elements and Metallic Foil Heating Elements

1996-10-01
962081
California Ultra Low Emission Vehicle (ULEV) standards call for a significant reduction in the amount of harmful gases that enter the environment from vehicle exhaust. The Electrically Heated Catalyst (EHC) is a possible solution to reduce emissions. A competitive analysis benchmarking study was completed in order to find an optimum EHC design that will perform to ULEV standards. Four suppliers submitted samples and the EHC designs were rigorously tested for temperature, pressure drop, and emissions performance while being aged at different levels.
Technical Paper

Energy Harvesting as Strategy for Reducing Vehicles Emissions

2012-10-02
2012-36-0114
In vehicular mobility context, it is extremely important for the environmental sustainability that the available energy will be used as efficiently as possible, both in the use of internal combustion engines (ICE) as powertrain, as well in the application of Hybrid and Electric Vehicle Motors (HEV/EV). In this comparison, ICE has a lower efficiency when compared to electric motors, wasting much of the potential energy of the fuel in form of heat and noise. On the other hand, the electric vehicles face limitation in autonomy and recharge time, demanding for a more efficient use of energy stored in batteries. This study aims to present emerging technologies for reuse of energy within the automotive context, originally known as “Energy Harvesting” and “Renewable Energies”.
Technical Paper

Use of CFD Simulation to Predict Fan Power and Airflow Pattern Inside the Climatic Chamber

2004-11-16
2004-01-3254
For A/C and cooling systems development is usual send vehicles to US or Europe for wind tunnel tests, witch is expensive and has a long lead-time. Here in Brazil Delphi has at the Piracicaba Technical Center a chamber equipped with temperature control and chassis dynamometer. There is a up-grade project for it that consist in add ducts with fans inside the chamber that will get air from the chamber, already in the right temperature, accelerate and homogenate the air flow and blow it out direct to the front end of the vehicle. For development purposes may be possible eliminate totally the necessity of sending vehicle abroad. It was then decided to use CFD simulation to predict firstly the required fan power necessary to supply winds until 120 km/h at the front end of the vehicle and secondly predict the airflow pattern inside the chamber, considering chamber inlet air, chamber outlet air, exhaust outlet, duct outlet and flow pattern around the vehicle.
Technical Paper

A Study of a Fast Light-Off Planar Oxygen Sensor Application for Exhaust Emissions Reduction

2000-03-06
2000-01-0888
It is well known that hydrocarbon reduction during a cold start is a major issue in achieving ultra low emissions standards. This paper describes one of the possible approaches for reducing the cold-start hydrocarbon emissions by using a fast “light-off” planar oxygen sensor. The goal of this study was to verify the operation characteristics of Delphi's fast “light-off” planar oxygen sensor's (INTELLEK OSP) operating characteristics and the closed-loop performance for achieving improved hydrocarbon control for stringent emission standards. Tests were conducted in open-loop and closed-loop mode under steady and transient conditions using a 1996 model year 2.4-liter DOHC in-line 4-cylinder engine with a close-coupled catalytic converter. Overall performance of the OSP showed relatively quick reaction time to reach the operating temperature.
Technical Paper

Palladium and Platinum/Rhodium Dual-Catalyst Emission Solutions for Close-Coupled or Underfloor Applications

2000-03-06
2000-01-0860
Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.
Technical Paper

An Engine Coolant Temperature Model and Application for Cooling System Diagnosis

2000-03-06
2000-01-0939
A coolant temperature model of an internal combustion engine has been formulated to meet the new On-Board Diagnostics II (OBD II) requirement for coolant temperature rationality. The model utilizes information available within the production Engine Control Module (ECM). The temperature prediction capability has been tested for various “real-world” driving conditions and cycles along with regulated drive cycles. The model can be calibrated to find the appropriate timing for initiation of a diagnostic algorithm for engine cooling system and Coolant Temperature Sensor (CTS) faults. A diagnostic scheme has been developed to detect and isolate various types of cooling system failures using engine soak time information available from a low power timer in the ECM.
Technical Paper

Evaluation of Propulsion Drive System Technologies for Hybrid Vehicles

2000-04-02
2000-01-1532
This paper summarizes the results of an investigation of high risk, high potential technologies for hybrid vehicle drive applications and investigate potential solutions for the technical risk items associated with these technologies. The study consisted of the design, build, and test of different types of electric machines to understand their performance, efficiency, and manufacturability to develop hybrid vehicles with cost and performance similar to the present day IC engine based vehicles, but with lower emissions and better fuel economy. Machine technologies examined include synchronous reluctance, permanent magnet, and switched reluctance. Test data for various machine technologies is presented along with a discussion of the technical risk associated with each technology.
Technical Paper

Evaluation of Corona Reactors of Several Geometries for a Plasma Assisted Nitrogen Oxide Emission Reduction Device

2000-10-16
2000-01-2899
Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system.
Technical Paper

Application of Non-Thermal Plasma Assisted Catalyst Technology for Diesel Engine Emission Reduction

2000-08-21
2000-01-3088
With new legislation and federal regulation for vehicle emission levels, automotive and truck manufacturers have been prompted to focus on emission control technologies that limit the level of exhaust pollutants. One of the primary pollutants, especially from diesel engines, is oxides of nitrogen (NOx). One possible solution to this pollution challenge is to design a more efficient internal combustion engine, which would require better engine operating parameter controls. However, there are limitations associated with such tight engine management. This need has led researchers and engineers to focus on the development of exhaust aftertreatment devices that will reduce NOx emissions with current diesel engines. An optimum aftertreatment device must be unaffected by exhaust-gas impurity poisoning such as sulfur products, and must have minimal impact on vehicle operations and fuel economy.
Technical Paper

Analytical Solution for Heat Flow in Cylinder and Its Application in Calculating Converter Skin Temperature

2000-03-06
2000-01-0301
In the catalytic converter, the thermal conductivity of the insulation material (intumescent mat) placed between the ceramic catalyst and the metal shell is strongly dependent on the temperature, resulting in the solving of non-linear heat conduction equations. In this paper, the analytic solution for the steady heat flow in a cylinder with temperature dependent conductivity is given. Using this analytic solution for the mat and including convection and radiation at the converter skin, an analytical expression for calculating converter skin temperature is obtained. This expression can be easily incorporated in a Fortran code to calculate the temperatures.
Technical Paper

Consumers, Electronics, and the Link to Hybrid Vehicles and the Environment

2000-11-01
2000-01-C045
The interdependence of consumer features, new electronic and electrical architectures and hybrid propulsion systems are examined. There are two major forces driving future vehicle electronic and electrical systems, one is consumer demand for comfort and safety, and two is the demand for reduced fuel consumption and emissions. These forces are linked by the use of electronics to control vehicle energy generation and usage while providing managed solutions to these demands. Automobile consumer features are discussed and the case is made that these features will require more electric power to be installed on the vehicle. The presence of this increased electric power will then enable the hybrid vehicle functions that will benefit fuel economy and emissions performance.
Technical Paper

Evaluation of a Non-Thermal Plasma System for Remediation of NOx in Diesel Exhaust

1999-10-25
1999-01-3639
With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.
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