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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

Gaseous and particle emissions from a gasoline direct injection (GDI) and a port fuel injection (PFI) vehicle were measured at various ambient temperatures (22°C, -7°C, -18°C). These vehicles were driven over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) on Tier 2 certification gasoline (E0) and 10% by volume ethanol (E10). Emissions were analyzed to determine the impact of ambient temperature on exhaust emissions over different driving conditions. Measurements on the GDI vehicle with a gasoline particulate filter (GPF) installed were also made to evaluate the GPF particle filtration efficiency at cold ambient temperatures. The GDI vehicle was found to have better fuel economy than the PFI vehicle at all test conditions. Reduction in ambient temperature increased the fuel consumption for both vehicles, with a much larger impact on the cold-start FTP-75 drive cycle observed than for the hot-start US06 drive cycle.

Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.

A gasoline engine with an electronically controlled fuel injection system has substantially better fuel economy and lower emissions than a carburetted engine. In general, the stability of engine operation is improved with fuel injector, but the stability of engine operation at idle is not improved compared with a carburetted gasoline engine. In addition, the increase in time that an engine is at idle due to traffic congestion has an effect on the engine stability and vehicle reliability. Therefore, in this research, we will study the influence of fuel injection timing, spark timing, dwell angle, and air-fuel ratio on engine stability at idle.

The characteristics of the early development of fuel sprays from pressure swirl atomizer injectors of the type used in direct injection gasoline engines is investigated. Planar laser-induced fluorescence (PLIF) was used to visualize the fuel distribution inside a firing optical engine. The early spray development of three different injectors at three different fuel pressures (3, 5, and 7 MPa) was followed as a function of time in 30 μsec intervals. Four phases could be identified: 1) A delay phase between the rising edge of the injection pulse and the first occurrence of fuel in the combustion chamber, 2) A solid jet or pre-spray phase, in which a poorly atomized stream of liquid fuel during the first 150 μsec of the injection. 3) A wide hollow cone phase, separation of the liquid jet into a hollow cone spray once sufficient tangential velocity has been established and 4) A fully developed spray, in which the spray cone angle is narrowed due to a low pressure zone at the center.

This paper presents the emission characteristics of a HCCI engine operation using n-heptane. The experiments were conducted in a single cylinder Co-operative Fuel Research (CFR) engine equipped with an air-assist port fuel injector. The effects of intake temperature, air/fuel ratio, compression ratio, turbo-charging, and EGR rate on exhaust emissions were explored. The analysis of the exhaust gases included oxides of nitrogen (NOx), nitrous oxide (N2O), carbon monoxide (CO), total hydrocarbon (THC), and soot. The hydrocarbon species present in exhaust gases and their concentrations at several operating conditions were also characterized. The strategies to obtain low HC, CO and NOx emissions are presented and discussed. The approaches to effectively retard HCCI combustion phase without deteriorating combustion efficiency are examined. It was found that HCCI combustion produces extremely low soot and NOx emissions.

The presence of liquid fuel inside the engine cylinder is believed to be a strong contributor to the high levels of hydrocarbon emissions from spark ignition (SI) engines during the warm-up period. Quantifying and determining the fate of the liquid fuel that enters the cylinder is the first step in understanding the process of emissions formation. This work uses planar laser induced fluorescence (PLIF) to visualize the liquid fuel present in the cylinder. The fluorescing compounds in indolene, and mixtures of iso-octane with dopants of different boiling points (acetone and 3-pentanone) were used to trace the behavior of different volatility components. Images were taken of three different planes through the engine intersecting the intake valve region. A closed valve fuel injection strategy was used, as this is the strategy most commonly used in practice. Background subtraction and masking were both performed to reduce the effect of any spurious fluorescence.

A gasoline direct injection fuel spray was observed using a fired, optical access, square cross-section single cylinder research engine and high-speed video imaging. Spray interaction with the piston is described qualitatively, and the results are compared with Computational Fluid Dynamics (CFD) simulation results using KIVA-3V version 2. CFD simulations predicted that within the operating window for stratified charge operation, between 1% and 4% of the injected fuel would remain on the piston as a liquid film, dependent primarily on piston temperature. The experimental results support the CFD simulations qualitatively, but the amount of fuel film remaining on the piston appears to be under-predicted. High-speed video footage shows a vigorous spray impingement on the piston crown, resulting in vapor production.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

Comparisons have been made between dual-fuel (80% port-injection gasoline and 20% direct-injection diesel by mass) Highly Premixed Charge Combustion (HPCC) and blended-fuel (80% gasoline and 20% diesel) Low Temperature Combustion (LTC) modes on a 1-L single-cylinder test engine. In the HPCC mode, both early-injection (E-HPCC) and late-injection (L-HPCC) of diesel have been used. The comparisons have been conducted with a fixed fuel injection rate of 50 mg/cycle at 1500 rpm, and with the combustion phasing fixed (by adjusting the injection timing) so that the 50% heat release point (CA50) is at 8° ATDC. The rapid heat release process of LTC leads to the highest maximum pressure rise rate (MPRR). A two-peak heat release process is observed in L-HPCC, resulting in a lower MPRR. The heat release rate and MPRR values for the E-HPCC are comparable to the L-HPCC values. The EHPCC mode provides the lowest NOX emission. The soot emissions for all three modes are low.

A 1.9L turbocharged direct-injection engine representing a model year 1998-2003 Volkswagen vehicle, equipped with the OEM diesel oxidation catalyst (DOC) and exhaust gas recirculation (EGR), was tested on an eddy-current engine dynamometer with a critical flow venturi-constant volume sampling system (CFV-CVS). The engine was operated over three steady-state modes: 1600 rev/min at 54 Nm; 1800 rev/min at 81 Nm; and 2000 rev/min at 98 Nm. Commercially available ultra-low sulfur diesel fuel (≺15 ppm S) was splash-blended with fatty acid methyl ester biodiesels derived from three different feedstocks: canola, soy, and tallow/waste fry oil. Test blend levels included: 0%, 2%, 5%, 20%, 50%, and 100% biodiesel for each feedstock.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

In internal combustion engines, a portion of liquid fuel spray may directly land on the liner and mix with oil (lubricant), forming a fuel-oil film (~10μm) that is much thicker than the original oil film (~0.1μm). When the piston retracts in the compression stroke, the fuel-oil mixture may have not been fully vaporized and can be scraped by the top ring into the 1st land crevice and eventually enter the combustion chamber in the format of droplets. Studies have shown that this mechanism is possibly a leading cause for low-speed pre-ignition (LSPI) as the droplets contain oil that has a much lower self-ignition temperature than pure fuel. In this interest, this work aims to study the oil-fuel interactions on the liner during an engine cycle, addressing molecular diffusion (in the liquid film) and vaporization (at the liquid-gas interface) to quantify the amount of fuel and oil that are subject to scraping by the top ring, thereby exploring their implications on LSPI and friction.

The recent tightening of emission standards for new heavy duty engines has lead to the development and implementation of alternative fuel engines, particularly for urban transit bus applications. Alternative fuels are intended to offer a potential emissions benefit with regards to the regulated emissions, and especially the particulate matter, which has received the greatest degree of regulatory action. However, the entire composition of the engine emissions should be considered when evaluating the environmental benefits of these new fuels, and also the continued performance of these engines in actual fleet service. In this study the exhaust emissions from methanol, ethanol, and diesel - powered buses were determined during transient operation of the vehicles on a heavy duty chassis dynamometer. The tests of the alcohol fuelled buses, and a control diesel bus were conducted as the buses accumulated mileage in revenue generating service.

As more stringent vehicle emission standards are introduced worldwide, there is an increased need to provide a thorough assessment of the environmental impact of alternative fuels. With the advent of CNG as a viable transportation fuel, the development of advanced computer controlled fuel delivery systems is imperative in order to ensure acceptable emission performance. At present, the majority of light and medium duty engines operating on natural gas are primarily gasoline automotive engines which have been retrofitted to allow for the use of CNG. The Mobile Sources Emissions Division of Environment Canada and the Canadian Gas Association have conducted a joint test program in order to develop a database of exhaust emissions from vehicles typically converted for operation on either gasoline or natural gas at various operating temperatures.

The fuel injection process in the port of a firing 4-valve SI engine at part load and 25°C head temperature was observed by a high speed video camera. Fuel was injected when the valve was closed. The reverse blow-down flow when the intake valve opens has been identified as an important factor in the mixture preparation process because it not only alters the thermal environment of the intake port, but also strip-atomizes the liquid film at the vicinity of the intake valve and carries the droplets away from the engine. In a series of “fuel-on” experiments, the fuel injected in the current cycle was observed to influence the fuel delivery to the engine in the subsequent cycles.

Photographic and performance studies with a Rapid Compression Machine at the Massachusetts Institute of Technology have been used to develop insight into the role of mixing in diesel engine combustion. Combustion photographs and performance data were analyzed. The experiments simulate a single fuel spray in an open chamber diesel engine with direct injection. The effects of droplet formation and evaporation on mixing are examined. It is concluded that mixing is controlled by the rate of entrainment of air by the fuel spray rather than the dynamics of single droplets. Experimental data on the geometry of a jet in a quiescent combustion chamber were compared with a two-phase jet model; a jet model based on empirical turbulent entrainment coefficients was developed to predict the motion of a fuel jet in a combustion chamber with swirl. Good agreement between theory and experiment was obtained.

A model has been developed to predict the performance of the Texaco Controlled Combustion, Stratified Charge Engine starting from engine geometry, fuel characteristics and the operating conditions. This performance model divides the engine cycle into the following phases: Intake, Compression, Rapid Combustion, Mixing-Dominated Expansion, Heat-Transfer Dominated Expansion and Exhaust. During the rapid combustion phase, the rate of heat release is assumed to be controlled by the rate of fuel injection and the air-to-fuel ratio. The burning rate in the mixing controlled stage appears to be dominated by the rate of entrainment of the surrounding gas by the plume of burning products and this rate is assumed to be controlled by the turbulent eddy entrainment velocity. A plume geometry model has been developed to obtain the surface area of the plume for entrainment during the mixing dominated phase.

The development of a cycle simulation model for the jet ignition prechamber stratified charge engine is described. Given the engine geometry, load, speed, air-fuel ratios and pressures and temperatures in the two intakes, flow ratio and a suitable combustion model, the cycle simulation predicts engine indicated efficiency and NO emissions. The relative importance of the parameters required to define the combustion model are then determined, and values for ignition delay and burn angle are obtained by matching predicted and measured pressure-time curves. The variation in combustion parameters with engine operating variables is then examined. Predicted and measured NO emissions are compared, and found to be in reasonable agreement over a wide range of engine operation. The relative contribution of the prechamber NO to total exhaust NO is then examined, and in the absence of EGR, found to be the major source of NO for overall air-fuel ratios leaner than 22:1.