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Journal Article

The Effects of Charge Motion and Laminar Flame Speed on Late Robust Combustion in a Spark-Ignition Engine

2010-04-12
2010-01-0350
The effects of charge motion and laminar flame speeds on combustion and exhaust temperature have been studied by using an air jet in the intake flow to produce an adjustable swirl or tumble motion, and by replacing the nitrogen in the intake air by argon or CO₂, thereby increasing or decreasing the laminar flame speed. The objective is to examine the "Late Robust Combustion" concept: whether there are opportunities for producing a high exhaust temperature using retarded combustion to facilitate catalyst warm-up, while at the same time, keeping an acceptable cycle-to-cycle torque variation as measured by the coefficient of variation (COV) of the net indicated mean effective pressure (NIMEP). The operating condition of interest is at the fast idle period of a cold start with engine speed at 1400 RPM and NIMEP at 2.6 bar. A fast burn could be produced by appropriate charge motion. The combustion phasing is primarily a function of the spark timing.
Journal Article

An Assessment of the Rare Earth Element Content of Conventional and Electric Vehicles

2012-04-16
2012-01-1061
Rare earths are a group of elements whose availability has been of concern due to monopolistic supply conditions and environmentally unsustainable mining practices. To evaluate the risks of rare earths availability to automakers, a first step is to determine raw material content and value in vehicles. This task is challenging because rare earth elements are used in small quantities, in a large number of components, and by suppliers far upstream in the supply chain. For this work, data on rare earth content reported by vehicle parts suppliers was assessed to estimate the rare earth usage of a typical conventional gasoline engine midsize sedan and a full hybrid sedan. Parts were selected from a large set of reported parts to build a hypothetical typical mid-size sedan. Estimates of rare earth content for vehicles with alternative powertrain and battery technologies were made based on the available parts' data.
Journal Article

The Underlying Physics and Chemistry behind Fuel Sensitivity

2010-04-12
2010-01-0617
Recent studies have shown that for a given RON, fuels with a higher sensitivity (RON-MON) tend to have better antiknock performance at most knock-limited conditions in modern engines. The underlying chemistry behind fuel sensitivity was therefore investigated to understand why this trend occurs. Chemical kinetic models were used to study fuels of varying sensitivities; in particular their autoignition delay times and chemical intermediates were compared. As is well known, non-sensitive fuels tend to be paraffins, while the higher sensitivity fuels tend to be olefins, aromatics, diolefins, napthenes, and alcohols. A more exact relationship between sensitivity and the fuel's chemical structure was not found to be apparent. High sensitivity fuels can have vastly different chemical structures. The results showed that the autoignition delay time (τ) behaved differently at different temperatures. At temperatures below 775 K and above 900 K, τ has a strong temperature dependence.
Technical Paper

Engine Wear Modeling with Sensitivity to Lubricant Chemistry: A Theoretical Framework

2007-04-16
2007-01-1566
The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.
Technical Paper

Making the Case for a Next Generation Automotive Electrical System

1998-10-19
98C006
Introduction of an array of new electrical and electronic features into future vehicles is generating vehicle electrical power requirements that exceed the capabilities of today's 14 volt electrical systems. In the near term (5 to 10 years), the existing 14V system will be marginally capable of supporting the expected additional loads with escalating costs for the associated charging system. However, significant increases in vehicle functional content are expected as future requirements to meet longer-term (beyond 10 years) needs in the areas of emission control, fuel economy, safety, and passenger comfort. A higher voltage electrical system will be required to meet these future requirements. This paper explores the functional needs that will mandate a higher voltage system and the benefits derivable from its implementation.
Technical Paper

Crash Safety of Lithium-Ion Batteries Towards Development of a Computational Model

2010-04-12
2010-01-1078
Battery packs for Hybrids, Plug-in Hybrids, and Electric Vehicles are assembled from a system of modules (sheets) with a tight sheet metal casing around them. Each module consists of an array of individual cells which vary in the composition of electrodes and separator from one manufacturer to another. In this paper a general procedure is outlined on the development of a constitutive and computational model of a cylindrical cell. Particular emphasis is placed on correct prediction of initiation and propagation of a tearing fracture of the steel can. The computational model correctly predicts rupture of the steel can which could release aggressive chemicals, fumes, or spread the ignited fire to the neighboring cells. The initiation site of skin fracture depends on many factors such as the ductility of the casing material, constitutive behavior of the system of electrodes, and type of loading.
Technical Paper

The Effect of Driving Conditions and Ambient Temperature on Light Duty Gasoline-electric Hybrid Vehicles (3): Battery Energy

2010-10-25
2010-01-2289
The dependence of gasoline-electric hybrid vehicle energies on driving conditions and ambient temperature is presented for different drive cycles (2xLA4, 2xLA92, 2xUS06, HWFET and 2xNYCC) and temperatures (20°C and -18°C). The tests were carried out at the Emissions Research and Measurement Division of Environment Canada. Hybrid battery pack current was measured at a frequency of 10 Hz. Regenerative braking energy, charging energy from the engine and battery discharge energy were estimated by using modal speed. The magnitudes of battery energies were found to be directly related to drive cycle properties. Battery discharge energy was very strongly correlated to emission factors of CO₂, while energy recovered by regenerative braking and charging energy from the engine had low to very strong correlations to CO₂ emission factors. CO, NOx and HC had low linear correlations to battery discharge energy.
Technical Paper

Investigating the Effect of Intake Manifold Size on the Transient Response of Single Cylinder Turbocharged Engines

2017-09-04
2017-24-0170
This paper evaluates the lag time in a turbocharged single cylinder engine in order to determine its viability in transient applications. The overall goal of this research is to increase the power output, reduce the fuel economy, and improve emissions of single cylinder engines through turbocharging. Due to the timing mismatch between the exhaust stroke, when the turbocharger is powered, and the intake stroke, when the engine intakes air, turbocharging is not conventionally used in commercial single cylinder engines. Our previous work has shown that it is possible to turbocharge a four stroke, single cylinder, internal combustion engine using an air capacitor, a large volume intake manifold in between the turbocharger compressor and engine intake. The air capacitor stores compressed air from the turbocharger during the exhaust stroke and delivers it during the intake stroke.
Technical Paper

Lab Study of Urea Deposit Formation and Chemical Transformation Process of Diesel Aftertreatment System

2017-03-28
2017-01-0915
Diesel exhaust fluid, DEF, (32.5 wt.% urea aqueous solution) is widely used as the NH3 source for selective catalytic reduction (SCR) of NOx in diesel aftertreatment systems. The transformation of sprayed liquid phase DEF droplets to gas phase NH3 is a complex physical and chemical process. Briefly, it experiences water vaporization, urea thermolysis/decomposition and hydrolysis. Depending on the DEF doser, decomposition reaction tube (DRT) design and operating conditions, incomplete decomposition of injected urea could lead to solid urea deposit formation in the diesel aftertreatment system. The formed deposits could lead to engine back pressure increase and DeNOx performance deterioration etc. The formed urea deposits could be further transformed to chemically more stable substances upon exposure to hot exhaust gas, therefore it is critical to understand this transformation process.
Technical Paper

An Overview of Hydrocarbon Emissions Mechanisms in Spark-Ignition Engines

1993-10-01
932708
This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.
Technical Paper

Chemical Kinetic Modeling of the Oxidation of Unburned Hydrocarbons

1992-10-01
922235
The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.
Technical Paper

Auto-Oil Program Phase II Heavy Hydrocarbon Study: Fuel Species Oxidation Chemistry and Its Relationship to the Auto-Oil Data

1994-10-01
941970
The oxidation chemistry of paraffins, aromatics, olefins and MTBE were examined. Detailed chemical kinetics calculations were carried out for oxidation of these compounds in the engine cycle. The oxidation rates are very sensitive to temperature. At temperatures of over 1400 K (depending on the fuel), all the hydrocarbons are essentially oxidized for typical residence time in the engine. Based on the kinetics calculations, a threshold temperature is defined for the conversion of the fuel species to CO, CO2, H2O and partially oxidized products. The difference in the survival fraction between aromatics and non-aromatics is attributed to the higher threshold temperature of the aromatics.
Technical Paper

Time-Resolved, Speciated Emissions from an SI Engine During Starting and Warm-Up

1996-10-01
961955
A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.
Technical Paper

Air-Fuel Ratio Measurement Diagnostics During Cranking and Startup in a Port-Fuel-Injected Spark-Ignition Engine

2004-06-08
2004-01-1915
Cranking and startup fuel control has become increasingly important due to ever tightening emission requirements. Additionally, engine-off strategies during idle will require substantially more engine startup events with the associated need for very clean starts. Thus, knowledge of an engine's Air-Fuel Ratio (AFR) during its early cycles is necessary in order to optimize cranking and startup fueling. This paper examines and compares two methods of measuring an engine's AFR during engine startup (approximately the first second of operation); an in-cylinder technique using a Fast Flame Ionization Detector (FFID) and the conventional exhaust based Universal Exhaust Gas Oxygen (UEGO) sensor method. Engine starts using a Ford Zetec engine were performed at three different temperatures (0, 20 and 90 C) as well as different initial engine starting positions.
Technical Paper

IGNITION OF FUELS BY RAPID COMPRESSION

1950-01-01
500178
THE autoignition characteristics of several fuels under various conditions of mixture strength, compression ratio, and temperature have been studied by means of a rapid-compression machine. The behaviors of a knock inhibitor, tetraethyl lead, and a knock inducer, ethyl nitrite, have also been studied. Simultaneous records of pressure, volume, and the inflammation have been obtained. These records show the diverse aspects of the autoignition phenomenon and indicate, among other things, according to the authors, that a comparison of the detonating tendencies of fuels must include not only a consideration of the length of the delay period but also an evaluation of the rate of pressure rise during autoignition. Physical interpretations of the data are presented but chemical interpretations have been avoided. The work was exploratory in nature. The authors hope that the results will stimulate activity in this important branch of combustion research.
Technical Paper

Introduction of Functional Periodicity to Prevent Long-Term Failure Mechanism

2006-04-03
2006-01-1203
One of the goals of designing engineering systems is to maximize the system's reliability. A reliable system must satisfy its functional requirements without failure throughout its intended lifecycle. The typical means to achieve a desirable level of reliability is through preventive maintenance of a system; however, this involves cost. A more fundamental approach to the problem is to maximize the system's reliability by preventing failures from occurring. A key question is to find mechanisms (and the means to implement them into a system) that will prevent its system range from going out of the design range. Functional periodicity is a means to achieve this goal. Three examples are discussed to illustrate the concept. In the new electrical connector design, it is the geometric functional periodicity provided by the woven wire structure. In the case of integrated manufacturing systems, it is the periodicity in scheduling of the robot motion.
Technical Paper

Dual-Mode Vehicle, Terminal, and Network Alternatives for Automated Guideway Transportation

1971-02-01
710112
Terminal design has emerged as having critical importance in the planning of dual-mode transportation in cities because the very high line-haul capacity of automated guideways can lead to large space requirements at entry and exit points. In this paper the influence of vehicle size, the method of guidance and propulsion, and the network terminal layouts on the space requirements for the overall transportation systems are discussed. Forecasts are made of the manner in which dual-mode transportation will first be installed.
Technical Paper

Mixture Preparation in a SI Engine with Port Fuel Injection During Starting and Warm-Up

1992-10-01
922170
The in-cylinder hydrocarbon (HC) mole fraction was measured on a cycle-resolved basis during simulated starting and warm-up of a port-injected single-cylinder SI research engine on a dynamometer. The measurements were made with a fast-response flame ionization detector with a heated sample line. The primary parameters that influence how rapidly a combustible mixture builds up in the cylinder are the inlet pressure and the amount of fuel injected; engine speed and fuel injection schedule have smaller effects. When a significant amount of liquid fuel is present at the intake port in the starting process, the first substantial firing cycle is often preceded by a cycle with abnormally high in-cylinder HC and low compression pressure. An energy balance analysis suggests that a large amount of liquid vaporization occurs within the cylinder in this cycle.
Technical Paper

A New Design for Automotive Alternators

2000-11-01
2000-01-C084
This paper introduces a new design for alternator systems that provides dramatic increases in peak and average power output from a conventional Lundell alternator, along with substantial improvements in efficiency. Experimental results demonstrate these capability improvements. Additional performance and functionality improvements of particular value for high-voltage (e.g., 42 V) alternators are also demonstrated. Tight load-dump transient suppression can be achieved using this new design and the alternator system can be used to implement jump charging (the charging of the high-voltage system battery from a low-voltage source). Dual-output extensions of the technique (e.g., 42/14 V) are also introduced. The new technology preserves the simplicity and low cost of conventional alternator designs, and can be implemented within the existing manufacturing infrastructure.
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