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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The high load limit of a boosted homogeneous-charge-compression-ignition (HCCI) engine operating on negative-valve-overlap (NVO) was assessed. When operating under stoichiometric condition with no external dilution, the load, as measured by the net indicated mean effective pressure (NIMEP), increased with increase in manifold absolute pressure (MAP), and with decrease in trapped amount of residual gas. The maximum pressure rise rate (MPRR), however, also increased correspondingly. When the MAP and the amount of residual gas were adjusted so that the engine operating point could be held at a constant MPRR value, the NIMEP increased with the simultaneous decrease in MAP and residual until the misfire limit was reached. Therefore if a MPRR ceiling is imposed, the high load limit of an HCCI engine is at the intersection of the constraining MPRR line and the misfire line.

Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of charge motion and laminar flame speeds on combustion and exhaust temperature have been studied by using an air jet in the intake flow to produce an adjustable swirl or tumble motion, and by replacing the nitrogen in the intake air by argon or CO₂, thereby increasing or decreasing the laminar flame speed. The objective is to examine the "Late Robust Combustion" concept: whether there are opportunities for producing a high exhaust temperature using retarded combustion to facilitate catalyst warm-up, while at the same time, keeping an acceptable cycle-to-cycle torque variation as measured by the coefficient of variation (COV) of the net indicated mean effective pressure (NIMEP). The operating condition of interest is at the fast idle period of a cold start with engine speed at 1400 RPM and NIMEP at 2.6 bar. A fast burn could be produced by appropriate charge motion. The combustion phasing is primarily a function of the spark timing.

An operational scheme with fuel-lean and exhaust gas dilution in spark-ignited engines increases thermal efficiency and decreases NOx emission, while these operations inherently induce combustion instability and thus large cycle-to-cycle variation in engine. In order to stabilize combustion variations, the development of an advanced ignition system is becoming critical. To quantify the impact of spark-ignition discharge, ignitability tests were conducted in an optically accessible combustion vessel to characterize the flame kernel development of lean methane-air mixture with CO₂ simulating exhaust diluent. A shrouded fan was used to generate turbulence in the vicinity of J-gap spark plug and a Variable Output Ignition System (VOIS) capable of producing a varied set of spark discharge patterns was developed and used as an ignition source. The main feature of the VOIS is to vary the secondary current during glow discharge including naturally decaying and truncated with multiple strikes.

Ultrasonic fatigue tests (testing frequency around 20 kHz) have been conducted on four different cast aluminum alloys each with a distinct composition, heat treatment, and microstructure. Tests were performed in dry air, laboratory air and submerged in water. For some alloys, the ultrasonic fatigue lives were dramatically affected by the environment humidity. The effects of different factors like material composition, yield strength, secondary dendrite arm spacing and porosity were investigated; it was concluded that the material strength may be the key factor influencing the environmental humidity effect in ultrasonic fatigue testing. Further investigation on the effect of chemical composition, especially copper content, is needed.

Diffusive combustion of direct injected ethanol is investigated in a heavy-duty single cylinder engine for a broad range of operating conditions. Ethanol has a high potential as fossil fuel alternative, as it provides a better carbon footprint and has more sustainable production pathways. The introduction of ethanol as fuel for heavy-duty compression-ignition engines can contribute to decarbonize the transport sector within a short time frame. Given the resistance to autoignition of ethanol, the engine is equipped with two injectors mounted in the same combustion chamber, allowing the simultaneous and independent actuation of the main injection of pure ethanol and a pilot injection of diesel as an ignition source. The influence of the dual-fuel injection strategy on ethanol ignition, combustion characteristics, engine performance and NOx emissions is evaluated by varying the start of injection of both fuels and the ethanol-diesel ratio.

Renewable fuels from different feedstocks can enable sustainable transport solutions with significant reduction in greenhouse gas emissions compared to conventional petroleum-derived fuels. Nevertheless, the use of biofuels in diesel engines will still require similar exhaust gas cleaning systems as for conventional diesel. Hence, the use of diesel particulate filters (DPF) will persist as a much needed part of the vehicle’s aftertreatment system. Combustion of renewable fuels can potentially yield soot and ash with different properties as well as larger amounts of ash compared to conventional fossil fuels. The faster ash build-up and altered ash deposition pattern lead to an increase in pressure drop over the DPF, increase the fuel consumption and call for premature DPF maintenance or replacement. Prolonging the maintenance interval of the DPF for heavy-duty trucks, having a demand for high up-time, is highly desirable.

The emission of airborne wear particles from friction material / cast iron pairs used in car brakes was investigated, paying special attention to the influence of temperature. Five low-metallic materials and one non-asbestos organic material were tested using a pin-on-disc machine. The machine was placed in a sealed chamber to allow airborne particle collection. The concentration and size distribution of 0.0056 to 10 μm particles were obtained by a fast mobility particle sizer and an optical particle sizer. The temperature was measured by a thermocouple installed in the disc. The experiments show that as the temperature increases from 100 to 300 °C the emission of ultrafine particles intensifies while that of coarse particles decreases. There is a critical temperature at which the ultrafine particle emission rate rises stepwise by 4 to 6 orders of magnitude. For the friction pairs investigated, the critical temperature was found to be between 165 and 190 °C.

The first 3 cycles in the cold crank-start process at 20°C are studied in a GDI engine. The focus is on the dependence of the HC and PM/PN emissions of each cycle on the injection strategy and combustion phasing of the current and previous cycles. The PM/PN emissions per cycle decrease by more than an order of magnitude as the crank-start progresses from the 1st to the 3rd cycle, while the HC emissions stay relatively constant. The wall heat transfer, as controlled by the combustion phasing, during the previous cycles has a more significant influence on the mixture formation process for the current cycle than the amount of residual fuel. The results show that the rise in HC emissions caused by the injection spray interacting with the intake valves and piston crown is reduced as the cranking process progresses. Combustion phasing retard significantly reduces the PM emission. The HC emissions, however, are relatively not sensitive to combustion phasing in the range of interest.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

Turbocharger compressors are limited in their operating range at low mass flows by compressor surge, thus restricting internal combustion engine operation at low engine speeds and high mean effective pressures. Since the exact location of the surge line in the compressor map depends on the whole gas exchange system, a safety margin towards surge must be provided. Accurate early surge detection could reduce this margin. During surge, the compressor outlet pressure fluctuates periodically. The Hurst exponent of the compressor outlet pressure is applied in this paper as an indicator to evaluate how close to the surge limit the compressor operates. It is a measure of the time-series memory that approaches zero for anti-persistence of the time series. That is, a Hurst exponent close to zero means a high statistical preference that a high value is followed by a low value, as during surge.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

A new ring pack model has been developed based on the curved beam finite element method. This paper describes the first part of this model: simulating gas pressure in different regions above piston skirt and ring dynamic behavior of two compression rings and a twin-land oil control ring. The model allows separate grid divisions to resolve ring structure dynamics, local force/pressure generation, and gas pressure distribution. Doing so enables the model to capture both global and local processes at their proper length scales. The effects of bore distortion, piston secondary motion, and groove distortion are considered. Gas flows, gas pressure distribution in the ring pack, and ring structural dynamics are coupled with ring-groove and ring-liner interactions, and an implicit scheme is employed to ensure numerical stability. The model is applied to a passenger car engine to demonstrate its ability to predict global and local effects on ring dynamics and oil transport.

Biofuel can enable a sustainable transport solution and lower greenhouse gas emissions compared to standard fuels. This study focuses on biodiesel, implemented in the easiest way as drop in fuel. When mixing biodiesel into diesel one can run into problems with solubility causing contaminants precipitating out as insolubilities. These insolubilities, also called soft particles, can cause problems such as internal injector deposits and nozzle fouling. One way to overcome the problem of soft particles is by filtration. It is thus of great interest to be able to quantify fuel filters’ ability to intercept soft particles. The aim of this study is to test different fuel filters for heavy-duty engines and their ability to filter out synthetic soft particles. A custom-built fuel filter rig is presented, together with some of its general design requirements. For evaluation of the efficiency of the filters, fuel samples were taken before and after the filters.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.