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Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

While metal fiber filters have successfully shown a high degree of particle retention functionality for various sizes of diesel engines with a low pressure drop and a relatively high filtration efficiency, little is known about the effects of lubricant-derived ash on the fiber filter systems. Sintered metal fiber filters (SMF-DPF), when used downstream from a diesel engine, effectively trap and oxidize diesel particulate matter via an electrically heated regeneration process where a specific voltage and current are applied to the sintered alloy fibers. In this manner the filter media essentially acts as a resistive heater to generate temperatures high enough to oxidize the carbonaceous particulate matter, which is typically in excess of 600°C.

Sintered metal fiber (SMF) diesel particulate filters (DPF) has more than one order of magnitude lower pressure drop compared to a granular or reaction-born DPF of the same (clean) filtration efficiency. To better understand the filtration process and optimize the filter performance, metal fiber filter models are developed in this study. The major previous theoretical models for clean fibrous filter are summarized and compared with experimental data. Furthermore, a metal fiber DPF soot loading model, using similar concept developed in high efficiency particulate air (HEPA) filter modeling, is built to simulate filter soot loading performance. Compared with experimental results, the soot loading model has relatively good predictions of filter pressure drop and filtration efficiency.