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Individual hydrocarbon conversion efficiencies of engine-out emissions have been measured for four different catalyst formulations (Pd-only, trimetallic, Pd/Rh, and Pt/Rh) during stoichiometric and rich operation. The measurements were carried out as a function of fuel-air equivalence ratio (Φ) using a dynamometer-controlled 1993 Ford V8 engine and capillary gas chromatography. HC conversion efficiency was examined in terms of mass conversion efficiency and also using three new definitions of catalyst conversion efficiency. The efficiencies across the four catalysts show similar trends with Φ for almost all HC species. The catalyst efficiencies for alkanes, alkenes, and aromatic species decrease as Φ increases above stoichiometric: alkane efficiencies decrease faster than alkenes which in turn decrease faster than aromatics. All efficiencies fall to zero near Φ = 1.08 except those of MTBE and acetylene, which remain near 100%.

In 1999, the first generation NOx sensor from NGK Spark Plug, Co., Ltd. was commercialized for use in gasoline LNT NOx after-treatment systems [ 1 ]. Since then, as emissions regulations and OBD requirements have become more stringent, the demand for a high-accuracy NOx sensor with fast light-off has increased, particularly for diesel after-treatment systems. To meet such market demands, NGK Spark Plug, Co., Ltd. has developed, in collaboration with Ford Motor Company, a second generation NOx sensor.

Nonthermal plasma discharges in combination with catalysts are being developed for diesel aftertreatment. NOx conversion has been shown over several different catalyst materials. Particulate removal has also been demonstrated. The gas phase chemistry of the plasma discharge is described. The plasma is oxidative. NO is converted to NO2, CH3ONO2 and HNO3. Hydrocarbons are partially oxidized resulting in aldehydes and CO along with various organic species. Soot will oxidize if it is held in the plasma. When HC is present, SO2 is not converted to sulfates. Suitable plasma-catalysts can achieve NOx conversion over 70%, with a wider effective temperature range than non-plasma catalysts. NOx conversion requires HC and O2. Electrical power consumption and required exhaust HC levels increase fuel consumption by several percent. A plasma catalyst system has demonstrated over 90% particulate removal in vehicle exhaust.

Environmental concerns have prompted increasingly stringent government legislation regulating automotive fuel economy and emissions. Recent rules not only mandate lower total emissions, but also require on-board diagnostics which monitor the vehicle exhaust systems. In order to satisfy these requirements, new and improved exhaust gas sensors are continually being developed to serve as part of the engine feedback control and emissions monitoring systems. Before we can properly design these new sensors, we must attempt to better understand the harsh environment in which they will operate. In this paper, we examine the high frequency nature of pressure fluctuations found in the exhaust system for both steady state and transient engine operating conditions. We also investigate temperature fluctuations, but restrict these measurements to the sampling environment found in the packaging of a Ford Si-based microcalorimeter.

Ford Motor Company is participating in the Department of Energy's (DOE) Ultra-Clean Transportation Fuels Program with the goal to explore the development of innovative emission control systems for advanced compression-ignition direct-injection (CIDI) transportation engines. CIDI (or diesel) engines have the advantages of a potential 40% fuel economy improvement and 20% less CO2 emissions than current gasoline counterparts. To support this goal, Ford plans to demonstrate an exhaust emission control system that provides high efficiency particulate matter (PM) and NOx reduction. Very low sulfur diesel fuel will be used to enable low PM emissions, reduce the fuel economy penalty associated with the emission control system, and increase the long-term durability of the system. The end result will allow vehicles with CIDI engines to be Tier II emissions certified at a minimum cost to the consumer.

Diesel vehicles have significant advantages over their gasoline counterparts including a more efficient engine, higher fuel economy, and lower emissions of HC, CO, and CO2. However, NOx control is more difficult on a diesel because of the high O2 concentration in the exhaust, making conventional three-way catalysts ineffective. The most promising technology for continuous NOx reduction onboard diesel vehicles is Selective Catalytic Reduction (SCR) using aqueous urea. Recent work with urea SCR has involved aftertreatment for the 1.2L DIATA common-rail diesel engine. This engine was used in Ford's hybrid-electric vehicle, the Prodigy, which was developed under the PNGV (Partnership for a New Generation of Vehicles) program. An emission control system consisting of a diesel particulate filter followed by an underbody SCR system was used successfully to meet ULEV emission standards (0.2 g/mi NOx, 0.04 g/mi particulate matter (PM)).

A diesel fuel and air diffusion flame burner system has been designed for laboratory simulation of diesel exhaust gas. The system consists of mass flow controllers and a fuel pump, and employs several unique design and construction features. It produces particulate emissions with size, number distribution, and morphology similar to diesel exhaust. At the same time, it generates NOx emissions and HC similar to diesel. The system has been applied to test plasma discharges. Different design discharge devices have been tested, with results indicating the importance of testing devices with soot and moisture. Both packed bed reactor and flat plate dielectric barrier discharge systems remove some soot from the gas, but the designs tested are susceptible to soot fouling and related electrical failures. The burner is simple and stable, and is suitable for development and aging of plasma and catalysts systems in the laboratory environment.

Previously reported experiments revealed the presence of a small number of clusters or very small particles in the effluent of a nonthermal plasma reactor when treating a simulated engine exhaust mixture. These clusters are smaller than 7 nm. The quantity of clusters is orders of magnitude smaller than the particulate diesel or gasoline engine exhaust typically contains. In this report, we describe further experiments designed to determine the chemical composition of the clusters. Clusters were collected on the surface of a silicon substrate by exposing it to the effluent flow for extended time periods. The resulting deposits were analyzed by high mass resolution SIMS and by XPS. The SIMS analysis reveals NH4+, CH6N+, SO-, SO2-, SO3- and HSO4- ions. XPS reveals the presence of N and S at binding energies consistent with that of ammonium sulfate.

Spark retard is desirable for decreasing cold start hydrocarbon emissions and lighting off the catalyst more rapidly. The focus of this work is to better understand the nature of the HC emissions as spark is retarded and investigate the location of the oxidation (in-cylinder or in the exhaust port and manifold). Fast FID measurements were taken in the exhaust port of a single cylinder research engine during cold, retarded spark engine operation (1200 rpm, 2.5 bar IMEP, 20 °C fluids). At moderate spark retard both Fast FID (exhaust port) and exhaust plenum HC levels decreased due to reduced crevice volume fraction at the end of burn, and increased in-cylinder burn up. In contrast, at large spark retard the port HC's increased dramatically while the exhaust plenum levels continued to fall to near zero. This is thought to be due to the onset of incomplete in-cylinder combustion along with increased exhaust port and manifold after-burning caused by the increasing exhaust gas temperatures.

The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and doublespark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray.

Projected NOx and fuel costs are compared for a plasma-catalyst system and an active lean NOx catalyst system. Comparisons are based on modeling of FTP cycle performance. The model uses steady state laboratory device characteristics, combined with measured vehicle exhaust data to predict NOx conversion efficiency and fuel economy penalties. The plasma system uses a proprietary catalyst downstream of a plasma discharge. The active lean NOx catalyst uses a catalyst along with addition of hydrocarbons to the exhaust. For the plasma catalyst system, NOx conversion is available over a wide temperature range. Increased electrical power improves conversion but degrades vehicle fuel economy; 10 J/L energy deposition costs roughly 3% fuel economy. Improved efficiency is also available with larger catalyst size or increased exhaust hydrocarbon content. For the active lean NOx system, NOx conversion is available only in a narrow temperature range.

The effects of port fuel injection (PFI) timing and targeting on air/fuel (A/F) control, exhaust emissions, and combustion stability at retarded spark timing were investigated on a 2.0L I-4 engine with production injectors (300-350 micron SMD droplet spray). Timings were fully closed valve injection (CVI) or fully open valve injection (OVI), and selected targetings were towards the valve or port floor. An “ideal” pre-vaporized, pre-mixed fuel system was also tested to provide a baseline with which to isolate PFI fuel preparation effects. The key findings were: Transient A/F excursions with PFI were minimized over the full temperature range with OVI timing and valve targeting. The X-tau modeled film mass for OVI/valve target was 50% less than CVI/valve target and 30% less than OVI/port target with a cold engine (20° C). When fully warm (90° C), the A/F response of CVI/valve target improved to near that of OVI.

In order to assess the amount of airborne particulate matter (PM) attributable to vehicle disk brakes, a system was devised for collecting brake wear debris on a laboratory brake dynamometer. The brake dynamometer test hardware was enclosed and vented through a duct in which the airflow was controlled to ensure isokinetic sampling. Two brake dynamometer simulations were implemented: urban driving (low velocity, low g) and the Auto Motor und Sport (AMS, high velocity, high g). These test procedures were performed repeatedly on the brake system hardware of vehicles utilizing three different friction material types: low-metallic, semi-metallic, and non-asbestos organic (NAO). Airborne brake wear was collected on filters and via other airborne PM sampling techniques. Larger, non-airborne wear debris was collected from the wheel, below the brake, and brushed off the hardware. Considering the effect of the wheel, 50-70% of the collected wear debris was airborne PM.

The requirement of reducing HC emissions during cold start and improving transient performance has prompted a study of the fuel injection process. Port-fuel-injection with the Intake-valve open using small droplets is a potentially feasible option to achieve the goals. To gain a better understanding of the injection process, the effects of droplet size, injection timing, and coolant temperature on the total and speciated HC emissions were tested In a Single-cylinder engine. It was found that droplet size plays an important role in the total HC emission increase during open-valve injection, especially with cold operation. Large droplets (300 μm SMD) produced a substantial HC increase while small droplets (14 μm SMD) produced no observable increase. Increase In the total HC emissions was always accompanied by an increase in the heavy fuel components in the exhaust gases.