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Journal Article

Lab Evaluation and Comparison of Corrosion Performance of Mg Alloys

2010-04-12
2010-01-0728
More Mg alloys are being considered for uses in the automotive industry. Since the corrosion performance of Mg alloy components in practical service environments is unknown, long term corrosion testing at automotive proving grounds will be an essential step before Mg alloy components can be implemented in vehicles. However, testing so many Mg alloy candidates for various parts is labor intensive for the corrosion engineers at the proving grounds. This report presents preliminary results in evaluating corrosion performance of Mg alloys based on rapid corrosion and electrochemical tests in the lab. In this study, four Mg alloy candidates for transmission cases and oil pans: AE44, AXJ530, MRI153M and MRI230D were tested in the lab and at General Motors Corporation Milford Proving Ground and their corrosion results were compared.
Journal Article

Process Robustness of Laser Braze-Welded Al/Cu Connectors

2016-04-05
2016-01-1198
Laser welding of dissimilar metals such as Aluminum and Copper, which is required for Li-ion battery joining, is challenging due to the inevitable formation of the brittle and high electrical-resistant intermetallic compounds. Recent research has shown that by using a novel technology, called laser braze-welding, the Al-Cu intermetallics can be minimized to achieve superior mechanical and electrical joint performance. This paper investigates the robustness of the laser braze-welding process. Three product and process categories, i.e. choice of materials, joint configurations, and process conditions, are studied. It is found that in-process effects such as sample cleanness and shielding gas fluctuations have a minor influence on the process robustness. Furthermore, many pre-process effects, e.g. design changes such as multiple layers or anodized base material can be successfully welded by process adaption.
Technical Paper

Effect of Pre-treatment on Corrosion Performance of AZ31B Magnesium Alloy Panel

2010-04-12
2010-01-0725
AZ31B Mg sheet is being considered for automotive applications. This study investigates the effect of pre-treatments, such as heat-treatments and surface treatments, on the corrosion performance of AZ31B sheet, with a goal of learning which pre-treatment can improve corrosion resistance of the sheet material in production. It is found that the heat-treatment and oxidation during a warm and hot forming (WHF) process will not deteriorate the corrosion performance of the AZ31B sheet; polishing and acid etching can clean the surface and significantly increase the corrosion resistance, but corrosion can be accelerated by sandblasting which contaminates the surface. The change in corrosion performance can be associated with surface cleaning or contamination of the sheet by these pre-treatments. Furthermore, the influence of a pre-treatment on the uncoated AZ31B sheet may affect its corrosion behavior after coating.
Technical Paper

Self-deposited E-coating for Mg Alloys

2010-04-12
2010-01-0727
Magnesium alloys are not corrosion resistant in many applications and they require coating protection. In this study, we developed an electroless E-coating technique for magnesium alloys and discussed a cathodic E-coating deposition mechanism for the electroless E-coating process. This coating can be formed within a few seconds by dipping a magnesium alloy (i.e., AZ91D) in an E-coat bath without applying a current or voltage. The deposited electroless coat can offer good protection to the AZ91D magnesium alloy in 5 wt% NaCl corrosive solution as well as in a phosphating bath. The most interesting finding is that the electroless coating is not sensitive to local damage. No preferential corrosion attack occurred along the scratches made on the coating.
Technical Paper

Development of the ASTM Sequence IIIE Engine Oil Oxidation and Wear Test

1988-10-01
881576
The ASTM Sequence IIID engine-dynamometer test has been used to evaluate the high-temperature protection provided by engine oils with respect to valve train wear, viscosity increase (oil thickening), deposits, and oil consumption. The obsolescence of the engine used in this test along with the need to define even higher levels of performance associated with a new oil category (SG) prompted efforts at developing a replacement test. This paper describes the hardware and procedure development of this replacement test, the ASTM Sequence IIIE test. Test precision and correlation with field and Sequence IIID results on a series of reference oils is also discussed.
Technical Paper

Effects of Gasoline and Ethanol Fuel Corrosion Inhibitors and Fuel Detergents on Powertrain Intake Valve Deposits

2014-04-01
2014-01-1383
Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution systems used for transportation of fuel from refineries. They are also used to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of the types of inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and to show how variation in concentration of components of CIs and detergents impact intake valve deposit formation.
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