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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Journal Article

Self-Pierce Riveting of Magnesium to Aluminum Alloys

2011-04-12
2011-01-0074
Magnesium and aluminum alloys offer lightweighting opportunities in automotive applications. Joining of dissimilar materials, however, generally requires methods that do not involve fusion. This paper explores the use of self-pierce riveting (SPR) to join magnesium to aluminum alloys for structural and closure applications. The preliminary results indicate that SPR is a viable option for joining aluminum extrusions to magnesium die castings, as well as stamped sheet aluminum to quick-plastic-formed (QPF) sheet magnesium.
Journal Article

Structural Evaluation of an Experimental Aluminum/Magnesium Decklid

2011-04-12
2011-01-0075
Experimental decklids for the Cadillac STS sedan were made with Al AA5083 sheet outer panels and Mg AZ31B sheet inner panels using regular-production forming processes and hardware. Joining and coating processes were developed to accommodate the unique properties of Mg. Assembled decklids were evaluated for dimensional accuracy, slam durability, and impact response. The assemblies performed very well in these tests. Explicit and implicit finite element simulations of decklids were conducted, and showed that the Al/Mg decklids have good stiffness and strength characteristics. These results suggest the feasibility of using Mg sheet closure panels from a structural perspective.
Journal Article

A Comparison of Spray-Guided Stratified-Charge Combustion Performance with Outwardly-Opening Piezo and Multi-Hole Solenoid Injectors

2011-04-12
2011-01-1217
This investigation was aimed at measuring the relative performance of two spray-guided, single-cylinder, spark-ignited direct-injected (SIDI) engine combustion system designs. The first utilizes an outwardly-opening poppet, piezo-actuated injector, and the second a conventional, solenoid operated, inwardly-opening multi-hole injector. The single-cylinder engine tests were limited to steady state, warmed-up conditions. The comparison showed that these two spray-guided combustion systems with two very different sprays had surprisingly close results and only differed in some details. Combustion stability and smoke emissions of the systems are comparable to each other over most of the load range. Over a simulated Federal Test Procedure (FTP) cycle, the multi-hole system had 15% lower hydrocarbon and 18% lower carbon monoxide emissions.
Journal Article

Fatigue Behavior and Life Prediction for Aluminum Castings in the Absence of Casting Flaws

2011-04-12
2011-01-0193
Cast aluminum alloys are increasingly used in cyclically loaded automotive structural applications for light weight and fuel economy. The fatigue resistance of aluminum castings strongly depends upon the presence of casting flaws and characteristics of microstructural constituents. The existence of casting flaws significantly reduces fatigue crack initiation life. In the absence of casting flaws, however, crack initiation occurs at the fatigue-sensitive microstructural constituents. Cracking and debonding of large silicon (Si) and Fe-rich intermetallic particles and crystallographic shearing from persistent slip bands in the aluminum matrix play an important role in crack initiation. This paper presents fatigue life models for aluminum castings free of casting flaws, which complement the fatigue life models for aluminum castings containing casting flaws published in [1].
Journal Article

Effects on Surface Roughness and Friction on Aluminum Sheet under Plain Strain Cyclic Bending and Tension

2011-04-12
2011-01-0535
During sheet metal forming, the friction and surface roughness change as the sheet slides, bends and stretches against the tools. This study assessed evolution of friction and surface roughness changes on aluminum sheet with two surface finish conditions, mill finish (MF) and electron discharge texture (EDT), in both the longitudinal and the transverse rolling directions of the sheet. The sheets were tested using a three pin Draw Bead Simulator (DBS). Surface roughness of the sheet evolved as a result of bending at the first shoulder, reverse bending at the middle pin, bending at the second shoulder and unbending at the exit. Stretching conditions and sheet-pin contact were also varied to see the impact on surface roughness. In general, the largest surface roughness change for the transverse direction was observed at the convex side of the exit shoulder pin and on the convex side of the first shoulder for the longitudinal direction.
Journal Article

The Effect of Surface Finish on Aluminum Sheet Friction Behavior

2011-04-12
2011-01-0534
Aluminum sheet is commercially available in three surface finishes, mill finish (MF), electric discharge texture (EDT), and dull finish (DF). This surface finish impacts the friction behavior during sheet metal forming. A study was done to compare ten commercially available sheet samples from several suppliers. The friction behavior was characterized in the longitudinal and transverse directions using a Draw Bead Simulator (DBS) test, resulting in a coefficient of friction (COF) value for each material. Characterization of the friction behavior in each direction provides useful data for formability analysis. To quantitatively characterize the surface finish, three-dimensional MicroTexture measurements were done with a WYKO NT8000 instrument. In general, the MF samples have the smoothest surface, with Sa values of 0.20-0.30 μm and the lowest COF values. The EDT samples have the roughest surface, with Sa values of 0.60-1.00 μm, and the highest COF values.
Journal Article

A Demonstration of Local Heat Treatment for the Preform Annealing Process

2011-04-12
2011-01-0538
The preform annealing process is a two-stage stamping method for shaping non age-hardenable (i.e. 5000 series) aluminum sheet panels in which the panel is heat treated in between the two steps to improve overall formability of the material. The intermediate annealing heat treatment eliminates the cold work accumulated in the material during the first draw. The process enables the ability to form more complex parts than a conventional aluminum stamping process. A demonstration of local annealing for this process was conducted to form a one-piece aluminum liftgate inner panel for a large sport utility vehicle using the steel product geometry without design concessions. In prior work, this process was demonstrated by placing the entire panel in a convection oven for several minutes to completely anneal the cold work.
Journal Article

Formability Analysis Predictions for Preform Annealing of Aluminum Sheet

2011-04-12
2011-01-0533
It is important to understand the accuracy level of the formability analysis for any new process so that correct predictions can be made in product and die design. This report focuses on the formability analysis methodology developed for the preform anneal process. In this process, the aluminum panel is partially formed, annealed to eliminate the cold work from the first step, and then formed to the final shape using the same die. This process has the ability to form more complex parts than conventional aluminum stamping, and has been demonstrated on a complex one-piece door inner and a complex one-piece liftgate inner with AA5182-O3. Both panels only required slight design modifications to the original steel product geometry. This report focuses on the formability analysis correlation with physical panels for the liftgate inner, considering both full panel anneal in a convection oven and local annealing of critical areas.
Journal Article

Numerical Investigation of Buoyancy-Driven Flow in a Simplified Underhood with Open Enclosure

2013-04-08
2013-01-0842
Numerical results are presented for simulating buoyancy driven flow in a simplified full-scale underhood with open enclosure in automobile. The flow condition is set up in such a way that it mimics the underhood soak condition, when the vehicle is parked in a windbreak with power shut-down after enduring high thermal loads due to performing a sequence of operating conditions, such as highway driving and trailer-grade loads in a hot ambient environment. The experimental underhood geometry, although simplified, consists of the essential components in a typical automobile underhood undergoing the buoyancy-driven flow condition. It includes an open enclosure which has openings to the surrounding environment from the ground and through the top hood gap, an engine block and two exhaust cylinders mounted along the sides of the engine block. The calculated temperature and velocity were compared with the measured data at different locations near and away from the hot exhaust plumes.
Technical Paper

Balance of Electrical Power Requirements through Smart Electric Power Management

2011-04-12
2011-01-0042
This paper examines Smart Electric Power Management as it pertains to when the vehicle charging system is active. Over the past decade there have been several factors at play which have stressed the demands placed upon the vehicle electrical power system. Many of these factors present challenges to electrical power that are at cross-purposes with one another. For example, demands of new and existing electrical loads, customer expectations about load performance and battery life, and the push by governments' world-wide for increased fuel economy (FE) and reduced CO2 emissions all have direct impact and can be directly impacted by decisions made in electric power design. As the electrification of the vehicle has progressed we now have much more specific vehicle state data available and the means to share this information among on-board computers through serial data link connectivity.
Technical Paper

Determination of Molding Parameter Effects on the Physical Properties of a Carbon Powder Filled, Impact Modified Acetal Copolymer

2011-04-12
2011-01-0250
Polyacetals have high strength, modulus, and chemical resistance with good dimensional stability. Because of these properties, they are used in a number of automotive applications. The injection molding process used for the molding of these components is complex and requires the adjustment of multiple process parameters to produce parts. Typically, physical tests are used to confirm that tensile strength is achieved in processing. A study was undertaken with an impact modified carbon powder filled, acetal copolymer to determine the effect of variation in process parameters on other material properties in addition to tensile strength. These material properties were measured dry as-molded and after exposure to heat and to a test fluid. It was determined that in the case of this specific polymer, the barrel temperature, and to a lesser extent the cooling time during processing, affected the strain at break.
Technical Paper

Dimensional Quality Control of Repeated Molded Polymer Battery Cell Housings in Automotive Energy Systems

2011-04-12
2011-01-0244
Current manufacture of alternative energy sources for automobiles, such as fuel cells and lithium-ion batteries, uses repeating energy modules to achieve targeted balances of power and weight for varying types of vehicles. Specifically for lithium-ion batteries, tens to hundreds of identical plastic parts are assembled in a repeating fashion; this assembly of parts requires complex dimensional planning and high degrees of quality control. This paper will address the aspects of dimensional quality for repeated, injection molded thermoplastic battery components and will include the following: First, dimensional variation associated with thermoplastic components is considered. Sources of variation include the injection molding process, tooling or mold, lot-to-lot material differences, and varying types of environmental exposure. Second, mold tuning and cavity matching between molds for multi-cavity production will be analyzed.
Technical Paper

Experimental Study of NOx Reduction by Passive Ammonia-SCR for Stoichiometric SIDI Engines

2011-04-12
2011-01-0307
As vehicle fuel economy requirements continue to increase it is becoming more challenging and expensive to simultaneously improve fuel consumption and meet emissions regulations. The Passive Ammonia SCR System (PASS) is a novel aftertreatment concept which has the potential to address NOx emissions with application to both lean SI and stoichiometric SI engines. PASS relies on an underfloor (U/F) SCR for storage of ammonia which is generated by the close-coupled (CC) TWCs. For lean SI engines, it is required to operate with occasional rich pulses in order to generate the ammonia, while for stoichiometric application ammonia is passively generated through the toggling of air/fuel ratio. PASS serves as an efficient and cost-effective enhancement to standard aftertreatment systems. For this study, the PASS concept was demonstrated first using lab reactor results which highlight the oxygen tolerance and temperature requirements of the SCR.
Technical Paper

Three-Way Catalyst Design for Urealess Passive Ammonia SCR: Lean-Burn SIDI Aftertreatment System

2011-04-12
2011-01-0306
Lean-burn SIDI engine technology offers improved fuel economy; however, the reduction of NOx during lean-operation continues to be a major technical hurdle in the implementation of energy efficient technology. There are several aftertreatment technologies, including the lean NOx trap and active urea SCR, which have been widely considered, but they all suffer from high material cost and require customer intervention to fill the urea solution. Recently reported passive NH₃-SCR system - a simple, low-cost, and urea-free system - has the potential to enable the implementation of lean-burn gasoline engines. Key components in the passive NH₃-SCR aftertreatment system include a close-coupled TWC and underfloor SCR technology. NH₃ is formed on the TWC with short pulses of rich engine operation and the NH₃ is then stored on the underfloor SCR catalysts.
Technical Paper

The Influence of DISI Engine Operating Parameters on Particle Number Emissions

2011-04-12
2011-01-0143
The future EURO 6 emission standard will limit the particle number and mass for gasoline engines. The proposed limit for particle mass is 4.5 mg/km. For particle number there is not yet a limit defined but a wide range of proposals are under discussion (6E11 - 8E12 Particles/km) The particle emissions on a homogeneous SIDI engine are mainly caused by insufficient mixture preparation. A combustion improvement could be achieved by a careful recalibration as well as a hardware optimization that mainly avoids wall impingement and substoichiometric zones in the combustion chamber. The analyses of current SIDI vehicles show significant PN emission peaks during cold start and transient operation on a NEDC cycle. To give a better understanding of cause and effect of the particle formation at steady state results so as transient load steps were performed at an engine dynamometer.
Technical Paper

Particle Number, Size and Mass Emissions of Different Biodiesel Blends Versus ULSD from a Small Displacement Automotive Diesel Engine

2011-04-12
2011-01-0633
Experimental work was carried out on a small displacement Euro 5 automotive diesel engine alternatively fuelled with ultra low sulphur diesel (ULSD) and with two blends (30% vol.) of ULSD and of two different fatty acid methyl esters (FAME) obtained from both rapeseed methyl ester (RME) and jatropha methyl ester (JME) in order to evaluate the effects of different fuel compositions on particle number (PN) emissions. Particulate matter (PM) emissions for each fuel were characterized in terms of number and mass size distributions by means of two stage dilutions system coupled with a scanning mobility particle sizer (SMPS). Measurements were performed at three different sampling points along the exhaust system: at engine-out, downstream of the diesel oxidation catalyst (DOC) and downstream of the diesel particulate filter (DPF). Thus, it was possible to evaluate both the effects of combustion and after-treatment efficiencies on each of the tested fuels.
Technical Paper

Optimization of Scratch Resistance for Molded in Color Interior Thermoplastic Olefin Injection Molded Plastics

2011-04-12
2011-01-0464
As customer dissatisfaction with interior trim components is tracked by the JDPowers question on “surface durability”, there is a need to increase the durability of the parts that are molded in color. In particular, door trim panel lowers are susceptible to surface damage which results in an unfavorable appearance. To address this issue, an assessment of the various factors that can affect surface durability was conducted using talc filled TPO materials in order to determine the optimum set of physical properties. The team used Design for Six Sigma (DFSS) methodology. A Taguchi orthogonal experiment was used and included control system factors of material, grain, gloss, and color. Noise factors included molding process parameters, aging, and piece to piece variation. The output was a measure of the scratch resistance of the molded plaque which was defined by a Delta L calculation.
Technical Paper

Particle Size and Number Emissions from Modern Light-Duty Diesel Vehicles

2011-04-12
2011-01-0632
This paper focuses on measuring particle emissions of a representative light-duty diesel vehicle equipped with different engine exhaust aftertreatment in close-coupled position, including one designed to meet the upcoming Euro 6 emission standards. The latter combines a lean NOx trap (LNT) and a diesel particulate filter (DPF) in series to simultaneously reduce NOx and PM. Particle Matter (PM) and particle number emissions are measured throughout testing procedure and instrumentation which are compliant with the UN-ECE Regulation 83 proposals. Specifically measuring devices for particle number emissions, provided by two different suppliers, are alternatively used. No significant differences are observed due to the different system employed. On the other hand particle size distributions are measured by means of a specific experimental set-up including a two stage dilution system and an electrical low pressure impactor (ELPI).
Technical Paper

Electrically Heated Catalysts for Cold-Start Emissions in Diesel Aftertreatment

2012-04-16
2012-01-1092
With a tighter regulatory environment, reduction of hydrocarbon (HC) and NOx emissions during cold-start has emerged as a major challenge for diesel engines. In the complex diesel aftertreatment system, more than 90% of engine-out NOx is removed in the underfloor SCR. However, the combination of low temperature exhaust and heat sink over DOC delays the SCR light-off during the cold start. In fact, the first 350 seconds during the cold light-duty FTP75 cycle contribute more than 50% of the total NOx tailpipe emission due to the low SCR temperature. For a fast SCR light-off, electrically heated catalyst (EHC) technology has been suggested to be an effective solution as a rapid warm-up strategy. In this work, the EHC, placed in front of DOC, utilizes both electrical power and hydrocarbon fuel. The smart energy management during the cold-start was crucial to optimize the EHC integrated aftertreatment system.
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