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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

A comprehensive experimental and theoretical approach was undertaken to understand the phenomenon of pre-ignition and to assess parameters to improve or even eliminate it completely. Oil mixing with fuel was identified as the leading theory of self ignition of the fuel. End of compression temperature has to meet a minimum level for pre-ignition to take place. In this work a comprehensive list of parameters were identified that have a direct and crucial role in the onset of pre-ignition including liner wetting, injection targeting, stratification, mixture motion and oil formulation. Many secondary effects were identified including ring dynamics, ring tension, spark plug electrode temperature and coolant temperature. CFD has been extensively used to understand test results including wall film, A/F ratio distribution and temperature at the end of compression when looked at in the context of fuel evaporation and mixing.

An investigation of high speed direct injection (DI) compression ignition (CI) engine combustion fueled with gasoline injected using a triple-pulse strategy in the low temperature combustion (LTC) regime is presented. This work aims to extend the operation ranges for a light-duty diesel engine, operating on gasoline, that have been identified in previous work via extended controllability of the injection process. The single-cylinder engine (SCE) was operated at full load (16 bar IMEP, 2500 rev/min) and computational simulations of the in-cylinder processes were performed using a multi-dimensional CFD code, KIVA-ERC-Chemkin, that features improved sub-models and the Chemkin library. The oxidation chemistry of the fuel was calculated using a reduced mechanism for primary reference fuel combustion chosen to match ignition characteristics of the gasoline fuel used for the SCE experiments.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.

The internal flow in an injector is greatly affected by cavitation formation, and this in turn impacts the spray characteristics of diesel injectors. In the current work, the performance of the Homogeneous Relaxation Model (HRM) in simulating cavitation inside a diesel injector is evaluated. This model is based on the assumption of homogeneous flow, and was originally developed for flash boiling simulations. However, the model can potentially simulate the spectrum of vaporization mechanisms ranging from cavitation to flash boiling through the use of an empirical time scale which depends on the thermodynamic conditions of the injector fuel. A lower value of this time scale represents a lower deviation from thermal equilibrium conditions, which is an acceptable assumption for small-scale cavitating flows. Another important advantage is the ability of this model to be easily coupled with real fuel models.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries. The impact of these inhibitors on spark ignited fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the additive concentrations to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel; and, to show how the variation in the concentrations of the CIs impact the operation and performance of vehicles, specifically, the effects on intake valve deposit formation. Commercially available corrosion inhibitor packages for both gasoline and ethanol blended fuels, specifically E85 fuels, were studied for their chemical compositions, and their impact on valves for a port fuel injection (PFI) engine.

Engine knock has been studied extensively over the years. Its undesired effects on drivability, its potential to damage an engine, and its impact on limiting the compression ratio are the main reasons why it remains a current topic of research. This paper focuses on exploiting the connection between auto-ignition and knock. A new method based on the frequency analysis of the heat release traces is proposed to detect and estimate auto-ignition/knock robustly. Filtering the heat release signal with the appropriate bandwidth is crucial to avoid misdetection. The filter settings used in this paper are found using spectral analysis of the heat release signal. By using the proposed method, it is possible to detect auto-ignition/knock even under the presence of undesired sensor resonance effects and noise from mechanical and electrical sources.

It is advantageous to increase the specific power output of diesel engines and to operate them at higher load for a greater portion of a driving cycle to achieve better thermal efficiency and thus reduce vehicle fuel consumption. Such operation is limited by excessive smoke formation at retarded injection timing and high rates of cylinder pressure rise at more advanced timing. Given this window of operation, it is desired to understand the influence of fuel properties such that optimum combustion performance and emissions can be retained over the range of fuels commonly available in the marketplace. Data are examined from a direct-injection single-cylinder research engine for eight common diesel fuels including soy-based biodiesel blends at two high load operating points with no exhaust gas recirculation (EGR) and at a moderate load with four levels of EGR.

Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.

Vehicle manufacturers have developed new vehicle and diesel engine technologies compatible with B6-B20 biodiesel blends meeting ASTM D7467, “Standard Specification for Diesel Fuel Oil, Biodiesel Blend (B6 to B20).” However, recent U.S. market place fuel surveys have shown that many retail biodiesel samples are out of specification. A vehicle designed to use biodiesel blends is likely to encounter occasional use of poor quality biodiesel fuel; and therefore understanding the effects of bad marketplace biodiesel fuels on engine and fuel system performance is critical to develop durable automotive technologies. The results presented herein are from vehicle evaluation studies with both on-specification and off-specification bio-based fuels. These studies focused on the performance of fuel injection equipment, engine, engine oil, emissions and emissions system durability.

The effects of using blended renewable diesel fuel (30% vol.), obtained from Rapeseed Methyl Ester (RME) and Hydrotreated Vegetable Oil (HVO), in a Euro 5 small displacement passenger car diesel engine have been evaluated in this paper. The hydraulic behavior of the common rail injection system was verified in terms of injected volume and injection rate with both RME and HVO blends fuelling in comparison with commercial diesel. Further, the spray obtained with RME B30 was analyzed and compared with diesel in terms of global shape and penetration, to investigate the potential differences in the air-fuel mixing process. Then, the impact of a biofuel blend usage on engine performance at full load was first analyzed, adopting the same reference calibration for all the tested fuels.

The light-medium load operating range (4-7 bar net IMEP) presents many challenges for advanced low temperature combustion strategies utilizing low cetane fuels (specifically, 87-octane gasoline) in light-duty, high-speed engines. The overly lean overall air-fuel ratio (Φ≺0.4) sometimes requires unrealistically high inlet temperatures and/or high inlet boost conditions to initiate autoignition at engine speeds in excess of 1500 RPM. The objective of this work is to identify and quantify the effects of variation in input parameters on overall engine operation. Input parameters including inlet temperature, inlet pressure, injection timing/duration, injection pressure, and engine speed were varied in a ~0.5L single-cylinder engine based on a production General Motors 1.9L 4-cylinder high-speed diesel engine.

The U.S. Renewable Fuel Standard 2 (RFS2) mandates the use of advanced renewable fuels such as cellulosic ethanol to be blended into gasoline in the near future. As such, determining the impact of these new fuel blends on vehicle performance is important. Therefore, General Motors conducted engine dynamometer evaluations on the impact of cellulosic ethanol blends on port fuel injected (PFI) intake valve deposits and gasoline direct injected (GDI) fuel injector plugging. Chemical analysis of the test fuels was also conducted and presented to support the interpretation of the engine results. The chemical analyses included an evaluation of the specified fuel parameters listed in ASTM International's D4806 denatured fuel ethanol specification as well as GC/MS hydrocarbon speciations to help identify any trace level contaminant species from the new ethanol production processes.

Biodiesel, a fuel comprised of mono-alkyl esters of long-chain fatty acids also known as Fatty Acid Methyl Esters(FAME), derived from vegetable oils or animal fats, has become an important commercial marketplace automotive fuel in the United States (US) and around the world over last few years. FAME biodiesels have many chemical and physical property differences compared to conventional petroleum based diesel fuels. Also, the properties of biodiesel vary based on the feedstock chosen for biodiesel production. One of the key differences between petroleum diesel fuels and biodiesel is the energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects the vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb calorimeter, this analytical laboratory testing is time consuming and expensive.

Biodiesel use is increasing around the world. Vehicle failures due to filter clogging issues have been reported in the field with use of biodiesel blended fuels in winter months. In certain instances, filter clogging was caused by precipitate formation above the cloud point of the fuel. Minor contaminants in biodiesel such as sterol glucosides and saturated monoglycerides are suspected to cause precipitation above the cloud point. ASTM has added a requirement to test biodiesel fuel for cold soak filtration test to prevent occurrences of this phenomenon of precipitation above the cloud point. This study focuses on understanding the correlation between cold soak filtration test results and presence of contaminants such as sterol glucosides and saturated monoglycerides in biodiesel fuels. Test samples were also subjected to thermal cycling at temperatures below the cloud point of fuel to co-correlate the cold soak filtration test results to visual observation of precipitate formation.