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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

To investigate the effect of aeration on fluid-elastomer compatibility, 4 types of elastomers were aged in three gear lubes. The four types of elastomers include a production fluorinated rubber (FKM) and production hydrogenated nitrile rubber (HNBR) mixed by the part fabricator, a standard low temperature flexible fluorinated rubber (FKM, ES-4) and a standard ethylene-acrylic copolymer (AEM, ES-7) mixed by SAE J2643 approved rubber mixer. The three gear lubes are Fluid a, Fluid b and Fluid c, where Fluid b is a modified Fluid with additional friction modifier, and Fluid c is friction modified chemistry from a different additive supplier. The aeration effect tests were performed at 125°C for 504 hours. The aerated fluid aging test was performed by introducing air into fluid aging tubes as described in General Motors Company Materials Specification GMW16445, Appendix B, side-by-side with a standard ASTM D471 test.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.

The sealing of a lift gate hinge to the body structure is necessary to avoid both the onset of corrosion and to avoid water intrusion into the interior compartment. The hinge-to-body interface typically involves horizontal metal-to-metal surface contact, creating the perfect environment for moisture entrapment and corrosion initiation. The choice of body panel material (uncoated (bare) steel vs. coated (galvanized) steel) drives different sealing approaches especially when considering corrosion avoidance.

Automotive structural components are exposed to high loads, impact situations and corrosion. In addition, there may be temperature excursions that introduce creep as well as reduced modulus (stiffness). These issues have limited the use of light metals in automotive structural applications primarily to aluminum alloys, and primarily to cast wheels and knuckles (only a few of which are forged), cast brake calipers, and cast control arms. This paper reports on research performed at Chongqing University, Chongqing China, under the auspices of General Motors engineering and directed by the first author, to develop a protocol that uses wrought magnesium in control arms. The goal was to produce a chassis part that could provide the same engineering function as current cast aluminum applications; and since magnesium is 33% less dense than aluminum, would be lighter.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries. The impact of these inhibitors on spark ignited fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the additive concentrations to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel; and, to show how the variation in the concentrations of the CIs impact the operation and performance of vehicles, specifically, the effects on intake valve deposit formation. Commercially available corrosion inhibitor packages for both gasoline and ethanol blended fuels, specifically E85 fuels, were studied for their chemical compositions, and their impact on valves for a port fuel injection (PFI) engine.

The electrical architecture design of a rear back glass defrost grid system encompasses many critical criteria that must be integrated into the design. For example, the defrost clip location and interface to the glass must meet all vehicle performance requirements. If the defrost clip to the glass interface is not resistant to vibration and relative movement, detachment and loss of function can occur. This paper describes a back glass defrost clip with a solder joint that is robust to manufacturing variations and customer usage conditions. A designed experiment using Design for Six Sigma methodologies was performed to understand the effects of the attachment interface to the electrical wiring pigtail, and parameters that affect performance. The working constraints, testing set up, validation, and root cause investigation of the clip detachment phenomenon is covered in this paper.

With a tighter regulatory environment, reduction of hydrocarbon emissions has emerged as a major concern for advanced low-temperature combustion engines. Currently precious metal-based diesel oxidation catalysts (DOC) containing platinum (Pt) and palladium (Pd) are most commonly used for diesel exhaust hydrocarbon oxidation. The efficiency of hydrocarbon oxidation is greatly enhanced by employing both Pt and Pd together compared to the case with Pt or Pd alone. However, there have been few systematic studies to investigate the effects of the ratio of platinum to palladium on catalytic oxidation over the DOC. The present study illustrates the relationship between the Pt-Pd ratio and catalyst activity and stability by evaluating a series of catalysts with various Pt to Pd ratios (1:0, 7:1, 2:1, 1:2, 1:5, 0:1). These catalysts were tested for their CO and hydrocarbon light-off temperatures under simulated conditions where both unburned and partially burned hydrocarbons were present.

Ferritic Nitrocarburized (FNC) cast iron brake rotors are proposed as a means to improve corrosion resistance, improve brake lining wear, as well as reduce corrosion-induced pulsation of automotive brake rotors. FNC processing of finish machined brake rotors presents challenges with controlling distortion, i.e., lateral run out (LRO). Prior investigations of FNC brake rotors suggested grinding the rotors to correct distortion. Post grinding the FNC processed rotors may reduce the FNC layer with an accompanying reduction in performance. Stress relieving (SR) the casting prior to FNC was found beneficial in providing a dimensionally acceptable rotor. Dimensional analysis of the stress relieved and FNC processed rotors will be presented. Benefits of FNC processed rotors will be reviewed.