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In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.

A steady-state system mass balance calculation was performed to investigate design issues regarding the storage and/or processing of solid waste. In the initial stages of BIO-Plex, only a certain percentage of the food requirement will be satisfied through crop growth. Since some food will be supplied to the system, an equivalent amount of waste will accumulate somewhere in the system. It is a system design choice as to where the mass should accumulate in the system. Here we consider two approaches. One is to let solid waste accumulate in order to reduce the amount of material processing that is needed. The second is to process all of the solid waste to reduce solid waste storage and then either resupply oxygen or add physical/chemical (P/C) processors to recover oxygen from the excess carbon dioxide and water that is produced by the solid waste processor.

The Plant Generic BioProcessing Apparatus (PGBA), a plant growth facility developed for commercial space biotechnology research, has flown successfully on 3 spaceflight missions for 4, 10 and 16 days. The environmental control systems of this plant growth chamber (28 liter/0.075 m2) provide atmospheric, thermal, and humidity control, as well as lighting and nutrient supply. Typical performance profiles of water transpiration and dehumidification, carbon dioxide absorption (photosynthesis) and respiration rates in the PGBA unit (on orbit and ground) are presented. Data were collected on single and mixed crops. Design options and considerations for the different sub-systems are compared with those of similar hardware.

The “low power-CO2 removal (LPCOR) system” is an advanced air revitalization system that is under development at NASA Ames Research Center. The LPCOR utilizes the fundamental design features of the ‘four bed molecular sieve’ (4BMS) CO2 removal technology of the International Space Station (ISS). LPCOR improves power efficiency by replacing the desiccant beds of the 4BMS with a membrane dryer and a state-of-the-art, structured adsorbent device that collectively require 25% of the thermal energy required by the 4BMS desiccant beds for regeneration. Compared to the 4BMS technology, it has the added functionality to deliver pure, compressed CO2 for oxygen recovery. The CO2 removal and recovery functions are performed in a two-stage adsorption compressor. CO2 is removed from the cabin air and partially compressed in the first stage. The second stage performs further compression and delivers the compressed CO2 to a reduction unit such as a Sabatier reactor for oxygen recovery.

Designers of future space vehicles envision simplifying the Atmosphere Revitalization (AR) system by combining the functions of trace contaminant (TC) control and carbon dioxide removal into one swing-bed system. Flow rates and bed sizes of the TC and CO2 systems have historically been very different. There is uncertainty about the ability of trace contaminant sorbents to adsorb adequately in a high-flow or short bed length configurations, and to desorb adequately during short vacuum exposures. This paper describes preliminary results of a comparative experimental investigation into adsorbents for trace contaminant control. Ammonia sorbents and low temperature catalysts for CO oxidation are the foci. The data will be useful to designers of AR systems for Constellation. Plans for extended and repeated vacuum exposure of ammonia sorbents are also presented.

Dynamic simulation of the lunar outpost habitat life support was undertaken to investigate the impact of life support failures and to investigate possible responses. Some preparatory static analysis for the Lunar Outpost life support model, an earlier version of the model, and an investigation into the impact of Extravehicular Activity (EVA) were reported previously. (Jones, 2008-01-2184, 2008-01-2017) The earlier model was modified to include possible resupply delays, power failures, recycling system failures, and atmosphere and other material storage failures. Most failures impact the lunar outpost water balance and can be mitigated by reducing water usage. Food solids and nitrogen can be obtained only by resupply from Earth. The most time urgent failure is a loss of carbon dioxide removal capability. Life support failures might be survivable if effective operational solutions are provided in the system design.

In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work was to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. TDA and NASA Ames Research Center have developed a pilot scale low temperature ozone oxidation system to convert organic waste to CO2 and H2O.

The current CO2 removal technology of NASA is very energy intensive and contains many non-optimized subsystems. This paper discusses the concept of a next-generation, membrane-integrated, adsorption processor for CO2 removal and compression in closed-loop air revitalization systems. The membrane module removes water from the feed, passing it directly into the processor's exhaust stream; it replaces the desiccant beds in the current four-bed molecular sieve system, which must be thermally regenerated. Moreover, in the new processor, CO2 is removed and compressed in a single two-stage unit. This processor will use much less power than NASA's current CO2 removal technology and will be capable of maintaining a lower CO2 concentration in the cabin than that can be achieved by the existing CO2 removal systems.

We modeled BIO-Plex designs with separate or combined atmospheres and then simulated controlling the atmosphere composition. The BIO-Plex is the Bioregenerative Planetary Life Support Systems Test Complex, a large regenerative life support test facility under development at NASA Johnson Space Center. Although plants grow better at above-normal carbon dioxide levels, humans can tolerate even higher carbon dioxide levels. Incinerator exhaust has very high levels of carbon dioxide. An elaborate BIO-Plex design would maintain different atmospheres in the crew and plant chambers and isolate the incinerator exhaust in the airlock. This design option easily controls the crew and plant carbon dioxide levels but it uses many gas processors, buffers, and controllers. If all the crew’s food is grown inside BIO-Plex, all the carbon dioxide required by the plants can be supplied by crew respiration and the incineration of plant and food waste.

New variable environment Modified Energy Cascade (MEC) crop models were developed for all the Advanced Life Support (ALS) candidate crops and implemented in SIMULINK. The MEC models are based on the Volk, Bugbee, and Wheeler Energy Cascade (EC) model and are derived from more recent Top-Level Energy Cascade (TLEC) models. The MEC models were developed to simulate crop plant responses to day-to-day changes in photosynthetic photon flux, photoperiod, carbon dioxide level, temperature, and relative humidity. The original EC model allowed only changes in light energy and used a less accurate linear approximation. For constant nominal environmental conditions, the simulation outputs of the new MEC models are very similar to those of earlier EC models that use parameters produced by the TLEC models. There are a few differences. The new MEC models allow setting the time for seed emergence, have more realistic exponential canopy growth, and have corrected harvest dates for potato and tomato.

CO2 removal, recovery and reduction are essential processes for a closed loop air revitalization system in a crewed spacecraft. Typically, a compressor is required to recover the low pressure CO2 that is being removed from the spacecraft in a swing bed adsorption system. This paper describes integrated tests of a Temperature-Swing Adsorption Compressor (TSAC) with high-fidelity systems for carbon dioxide removal and reduction assemblies (CDRA and Sabatier reactor). It also provides details of the TSAC operation at various CO2 loadings. The TSAC is a solid-state compressor that has the capability to remove CO2 from a low-pressure source, and subsequently store, compress, and deliver it at a higher pressure. TSAC utilizes the principle of temperature-swing adsorption compression and has no rapidly moving parts.

One of the major problems associated with solid waste processing technologies is effluent contaminants that are released in gaseous forms from the processes. This is a concern in both biological as well as physicochemical solid waste processing. Carbon dioxide (CO2), the major gas released, does not present a serious problem and there are currently in place a number of flight-qualified technologies for CO2 removal. However, a number of other gases, in particular NOx, SO2, NH3, and various hydrocarbons (e.g. CH4) do present health hazards to the crew members in space habitats. In the present configuration of solid waste processing in the International Space Station (ISS), some of these gases are removed by the Trace Contaminant Control System (TCCS), demands a major resupply. Reduction of the resupply can be effective by using catalyst impregnated carbon nanotubes. For example, NO decomposition to N2 and O2 is thermodynamically favored.

To ensure that adequate water resources are available during a mission, any net water loss from the habitat must be balanced with an equivalent amount of makeup water. For a Mars transit mission, the primary sources of makeup water will likely involve water contained in shipped tanks and in prepackaged food. As mission length increases, it becomes more cost effective to increase system water closure (recovery and generation) than to launch adequate amounts of contained water. This trend may encourage designers to specify increased water recovery in lieu of higher food moisture content. However, food palatability requirements will likely declare that prepackaged foods have a minimum hydration (averaged over all food types). The food hydration requirement may even increase with mission duration. However, availability requirements for specific emergency scenarios may declare that determined quantities of water be provided in tanks, rather than as moisture in food.

We have developed top-level crop models for analysis of Advanced Life Support (ALS) systems that use plants to grow food. The crops modeled are candidates for ALS use: bean (dry), lettuce, peanut, potato (white), rice, soybean, sweet potato, tomato, and wheat. The crop models are modified versions of the energy cascade crop growth model originally developed for wheat by Volk, Bugbee, and Wheeler. The models now simulate the effects of temperature, carbon dioxide level, planting density, and relative humidity on canopy gas exchange, in addition to the effects of light level and photoperiod included in the original model. The energy cascade model has also been extended to predict the times of canopy closure, grain setting (senescence), and maturity (harvest) as functions of the environmental conditions.

Spaceflight plant growth chambers require an atmosphere control system to maintain adequate levels of carbon dioxide and oxygen, as well as to limit trace gas components, for optimum or reproducible scientific performance. Recent atmosphere control anomalies of a spaceflight plant chamber, resulting in unstable CO2 control, have been analyzed. An activated carbon filter, designed to absorb trace gas contaminants, has proven detrimental to the atmosphere control system due to its large buffer capacity for CO2. The latest plant chamber redesign addresses the control anomalies and introduces a new approach to atmosphere control (low leakage rate chamber, regenerative control of CO2, O2, and ethylene).

Since the mid 1980s, NASA has developed advanced waste management technologies that collect and process waste. These technologies include incineration, hydrothermal oxidation, pyrolysis, electrochemical oxidation, activated carbon production, brine dewatering, slurry bioreactor oxidation, composting, NOx control, compaction, and waste collection. Some of these technologies recover resources such as water, oxygen, nitrogen, carbon dioxide, carbon, fuels, and nutrients. Other technologies such as the Waste Collection System (WCS - the commode) collect waste for storage or processing. The need for waste processing varies greatly depending upon the mission scenario. This paper reviews the waste management technology development activities conducted by NASA since the mid 1980s and explores the drivers that determine the application of these technologies to future missions.

In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. Previously, TDA Research, Inc. demonstrated the potential of a low temperature dry oxidation process using ozone in a small laboratory reactor.