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Modern spark-ignited (SI) engines offer excellent emission reduction when operated with a stoichiometric mixture and a three-way catalytic converter. A challenge with stoichiometric compared to diluted operation is the knock propensity due to the high reactivity of the mixture. This limits the compression ratio, thus reducing engine efficiency and increasing exhaust temperature. The current work evaluated a model of conditions at inlet valve closing (IVC) and top dead center (TDC) for steady state operation. The IVC temperature model is achieved by a cycle-to-cycle resolved residual gas fraction estimator. Due to the potential charge cooling effect from methanol, a method was proposed to determine the fraction of fuel sourced from a wall film. Determining the level of charge cooling is important as it heavily impacts the IVC and TDC temperatures.

Global warming and climate change have led to a greater interest in the implementation of biofuels in internal combustion engines. In spark ignited engines, biofuels have been shown to improve efficiency and knock resistance while decreasing emissions of unburned hydrocarbons, carbon monoxide and particles. This study investigates the effect of biofuels on SI engine combustion through a graphical compilation of previously reported results. Experimental data from 88 articles were used to evaluate the trends of the addition of different biofuels in gasoline. Graphs illustrating engine performance, combustion phasing and emissions are presented in conjunction with data on the physiochemical properties of each biofuel component to understand the observed trends. Internal combustion engines have the ability to handle a wide variety of fuels resulting in a broad range of biofuel candidates.

Clean combustion is one of the inherent benefits of using a high methane content fuel, natural gas or biogas. A single carbon atom in the fuel molecule results, to a large extent, in particle-free combustion. This is due to the high energy required for binding multiple carbon atoms together during the combustion process, required to form soot particles. When scaling up this process and applying it in the internal combustion engine, the resulting emissions from the engine have not been observed to be as particle free as the theory on methane combustion indicates. These particles stem from the combustion of engine oil and its ash content. One common practice has been to lower the ash content to regulate the particulate emissions, as was done for diesel engines. For a gas engine, this approach has been difficult to apply, as the piston and valvetrain lubrication becomes insufficient.