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Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

Power supply systems play a very important role in applications of everyday life. Mainly, for low power generation, there are two ways of producing energy: electrochemical batteries and small engines. In the last few years many improvements have been carried out in order to obtain lighter batteries with longer duration but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. If the energy source is an organic fuel with an energy density of around 29 MJ/kg and a minimum overall efficiency of only 3.5%, this device can surpass the batteries. Nowadays the most efficient combustion process is HCCI combustion which is able to combine high energy conversion efficiency and low emission levels with a very low fuel consumption. In this paper, an investigation has been carried out concerning the effects of the compression ratio on the performance and emissions of a mini, Vd = 4.11 [cm3], HCCI engine fueled with diethyl ether.

An experimental study of a glow plug engine combustion process has been performed by applying chemiluminescence imaging. The major intent was to understand what kind of combustion is present in a glow plug engine and how the combustion process behaves in a small volume and at high engine speed. To achieve this, images of natural emitted light were taken and filters were applied for isolating the formaldehyde and hydroxyl species. Images were taken in a model airplane engine, 4.11 cm3, modified for optical access. The pictures were acquired using a high speed camera capable of taking one photo every second or fourth crank angle degree, and consequently visualizing the progress of the combustion process. The images were taken with the same operating condition at two different engine speeds: 9600 and 13400 rpm. A mixture of 65% methanol, 20% nitromethane and 15% lubricant was used as fuel.

Experiments on a modern DI Diesel engine were carried out: The engine was fuelled with standard Diesel fuel, RME and a mixture of 85% standard Diesel fuel, 5% RME and 10% higher alcohols under low load conditions (4 bar IMEP). During these experiments, different external EGR levels were applied while the injection timing was chosen in a way to keep the location of 50% heat release constant. Emission analysis results were in accordance with widely known correlations: Increasing EGR rates lowered NOx emissions. This is explained by a decrease of global air-fuel ratio entailing longer ignition delay. Local gas-fuel ratio increases during ignition delay and local combustion temperature is lowered. Exhaust gas analysis indicated further a strong increase of CO, PM and unburned HC emissions at high EGR levels. This resulted in lower combustion efficiency. PM emissions however, decreased above 50% EGR which was also in accordance with previously reported results.

High-speed video imaging in a swirl-supported (Rs = 1.7), direct-injection heavy-duty diesel engine operated with moderate-to-high EGR rates reveals a distinct correlation between the spatial distribution of luminous soot and mean flow vorticity in the horizontal plane. The temporal behavior of the experimental images, as well as the results of multi-dimensional numerical simulations, show that this soot-vorticity correlation is caused by the presence of a greater amount of soot on the windward side of the jet. The simulations indicate that while flow swirl can influence pre-ignition mixing processes as well as post-combustion soot oxidation processes, interactions between the swirl and the heat release can also influence mixing processes. Without swirl, combustion-generated gas flows influence mixing on both sides of the jet equally. In the presence of swirl, the heat release occurs on the leeward side of the fuel sprays.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

Homogeneous Charge Compression Ignition (HCCI) holds great promises for good fuel economy and low emissions of NOX and soot. The concept of HCCI is premixed combustion of a highly diluted mixture. The dilution limits the combustion temperature and thus prevents extensive NOX production. Load is controlled by altering the quality of the charge, rather than the quantity. No throttling together with a high compression ratio to facilitate auto ignition and lean mixtures results in good brake thermal efficiency. However, HCCI also presents challenges like how to control the combustion and how to achieve an acceptable load range. This work is focused on solutions to the latter problem. The high dilution required to avoid NOX production limits the mass of fuel relative to the mass of air or EGR. For a given size of the engine the only way to recover the loss of power due to dilution is to force more mass through the engine.

Although there seems to be a consensus regarding the low emission potential of DME, there are still different opinions about why the low NOx emissions can be obtained without negative effects on thermal efficiency. Possible explanations are: The physical properties of DME affecting the spray and the mixture formation Different shape and duration of the heat release in combination with reduced heat losses In this paper an attempt is made to increase the knowledge of DME in relation to diesel fuel with respect to heat release and NOx formation. The emphasis has been to create injection conditions as similar as possible for both fuels. For that purpose the same injection system (CR), injection pressure (270 bar), injection timing and duration have been used for the two fuels. The only differences were the diameters of the nozzle holes, which were chosen to give the same fuel energy supply, and the physical properties of the fuels.

Laser-Rayleigh imaging has been employed to measure the relative fuel concentration in the gaseous jet region of DME sprays. The measurements were performed in an optically accessible diesel truck engine equipped with a common rail injection system. A one-hole nozzle was used to guarantee that the recorded pressure history was associated with the heat release in the imaged spray. To compensate for the low compression ratio in the modified engine the inlet air was preheated. Spray development was studied for two levels of preheating, from the start of injection to the point where all fuel was consumed. The results indicate that there is a strong correlation between the amount of unburned fuel present in the cylinder and the rate of heat release at a given time. The combustion can not be described as purely premixed or purely mixing-controlled at any time, but always has an element of both. After all fuel appears to have vanished there is still an extended period of heat release.

During development of an air assisted, direct injection combustion system, it was found that an air pulse during the late part of compression stroke significantly shortened the combustion duration and extended the lean limits of the engine. The effect of an injection of pure air through an air assist direct injector was studied with Particle Image Velocimetry, PIV. Results showed that an air pulse during the compression stroke significantly speeded up in-cylinder velocities, which also was showed in the heat release analysis. A system to use low density seeding particles was developed and is presented in the paper.

Laser-induced incandescence (LII) is a sensitive diagnostic technique capable of making exhaust particulate-matter measurements during transient operating conditions. This paper presents measurements of LII signals obtained from the exhaust gas of a 1.9-L TDI diesel engine. A scanning mobility particle sizer (SMPS) is used in fixed-size mode to obtain simultaneous number concentration measurements in real-time. The transient studies presented include a cranking-start/idle/shutdown sequence, on/off cycling of EGR, and rapid load changes. The results show superior temporal response of LII compared to the SMPS. Additional advantages of LII are that exhaust dilution and cooling are not required, and that the signal amplitude is directly proportional to the carbon volume fraction and its temporal decay is related to the primary particle size.

A specially designed cylinder head, enabling unthrottled operation with a standard cam-phasing mechanism, was tested in an optical single-cylinder engine. The in-cylinder flow was measured with particle image velocimetry (PIV) and the results were compared with heat release and emission measurements. The article also discusses effects of residual gas and effective compression ratio on heat-release and emissions. The special design of the cylinder head, with one inlet and one exhaust valve per camshaft, made it possible to operate the engine unthrottled at part load. Cam phasing led to late inlet valve closing, but also to increased valve overlap. The exhaust valve closing was late in the intake stroke, resulting in high amounts of residual gases. Two different camshafts were used with late inlet valve closing. One of the camshafts had shorter valve open duration on the phased exhaust cam lobe.

A comparison of scanning mobility particle sizer (SMPS) and laser-induced incandescence (LII) measurements of diesel particulate matter (PM) was performed. The results reveal the significance of the aggregate nature of diesel PM on interpretation of size and volume fraction measurements obtained with an SMPS, and the accuracy of primary particle size measurements by LII. Volume fraction calculations based on the mobility diameter measured by the SMPS substantially over-predict the space-filling volume fraction of the PM. Correction algorithms for the SMPS measurements, to account for the fractal nature of the aggregate morphology, result in a substantial reduction in the reported volume. The behavior of the particulate volume fraction, mean and standard deviation of the mobility diameter, and primary particle size are studied as a function of the EGR for a range of steady-state engine speeds and loads for a turbocharged direct-injection diesel engine.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

In this paper a fast NOx model is presented which can be used for engine optimization, aftertreatment control or virtual mapping. A cylinder pressure trace is required as input data. High calculation speed is obtained by using table interpolation to calculate equilibrium temperatures and species concentrations. Test data from a single-cylinder engine and from a complete six-cylinder engine have been used for calibration and validation of the model. The model produces results of good agreement with emission measurements using approximately 50 combustion product zones and a calculation time of one second per engine cycle. Different compression ratios, EGR rates, injection timing, inlet pressures etc. were used in the validation tests.

Homogeneous Charge Compression Ignition (HCCI) has a great potential for low NOx emissions but problems with emissions of unburned hydrocarbons (HC). One way of reducing the HC is to use direct injection. The purpose of this paper is to present experimental data on the trade off between NOx and HC. Injection timing, injection pressure and nozzle configuration all effect homogeneity of the mixture and thus the NOx and HC emissions. The engine studied is a single cylinder version of a Scania D12 that represents a modern heavy-duty truck size engine. A common rail (CR) system has been used to control injection pressure and timing. The combustion using injectors with different nozzle hole diameters and spray angle, both colliding and non-colliding, has been studied. The NOx emission level changes with start of injection (SOI) and the levels are low for early injection timing, increasing with retarded SOI. Different injectors produce different NOx levels.

A naturally aspirated in-line six-cylinder 2.9-litre Volvo engine is operated in Homogeneous Charge Compression Ignition (HCCI) mode, using camshafts with low lift and short duration generating negative valve overlap. Standard port fuel injection is used and pistons and cylinder head are unchanged from the automotive application. HCCI through negative valve overlap is recognized as one of the possible implementation strategies of HCCI closest to production. It is important to gain knowledge of the constraints and limits on the possible operating region. In this work, the emphasis is on investigating how cycle-to-cycle and cylinder-to-cylinder deviations limit the operating region, how these effects change in different parts of the operating region and how they can be controlled. At low load the cycle-to-cycle phenomena cause periodic behavior in combustion timing; together with cylinder deviations this is found responsible for decreasing the operating regime.

Exhaust Emissions from lean burn natural gas engines may not always be as low as the potential permits, especially engines with open loop lambda control. These engines can produce much higher emissions than a comparable diesel engine without exhaust gas after treatment. Even if the engine has closed loop lambda control, emissions are often unacceptably high for future emission regulations. A three way catalyst is, today, the best way to reduce hazardous emissions. The drawback is that the engine has to operate with a stoichiometric mixture and this leads to; higher heat losses, higher pumping work at low to medium loads, higher thermal stress on the engine and higher knock tendency (requiring lower compression ratio, and thus lower brake efficiency). One way to reduce these drawbacks is to dilute the stoichiometric mixture with EGR. This paper compares lean burn operation with operation at stoichiometric conditions diluted with EGR, and using a three way catalyst.

An ionization sensor has been used to study the combustion process in a six-cylinder lean burn, truck-sized engine fueled with natural gas and optimized for low emissions of nitric oxides. The final goal of the investigations is to study the prospects of using the ionization sensor for finding the optimal operating position with respect to low NOx emission and stable engine operation. The results indicate that unstable combustion can be detected by analyzing the coefficient of variation (CoV) of the detector current amplitude. Close relationships between this measure and the CoV of the indicated mean effective pressure have been found during an air-fuel ratio scan with fixed ignition advance.

Exhaust Gas Recirculation, EGR, is one of the most effective means of reducing NOx emissions from diesel engines and is likely to be used in order to meet future emissions standards. Exhaust gases can either be used to replace some of the air that enters the engine or can be added to the intake flow. The former case has been studied in this paper. One advantage of air replacement is that the exhaust mass flow is reduced in addition to the decreased NOx formation. The objective of this study has been to take a closer look at the factors affecting NOx emissions at different EGR rates. This is done by combining heat release analysis, based on measured pressure traces and NO formation in a multi zone combustion model. The model used is an improved version of an earlier presented model [1]. One feature in the new model is the possibility to separate the NO formation during the premixed combustion from NO formed during the diffusive combustion.