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To characterize the effects of renewable fuels on particulate emissions from GDI engines, engine experiments were conducted using EN228-compliant gasoline fuel blends containing no oxygenates, 10% ethanol (EtOH), or 22% ethyl tert-butyl ether (ETBE). The experiments were conducted in a single cylinder GDI engine using a 6-hole fuel injector operated at 200 bar injection pressure. Both PN in raw exhaust and solid PN (SPN) were measured at two load points and various start of injection (SOI) timings. Raw PN and SPN results were classified into various size ranges, corresponding to current and future legislations. At early SOI timings, where particulate formation is dominated by diffusion flames on the piston due to liquid film, the oxygenated blends yielded dramatically higher PN and SPN emissions than reference gasoline because of fuel effects.

Combustion characteristics of dimethyl ether, DME, have been investigated experimentally, in a heavy duty single cylinder engine equipped with an adapted common rail fuel injection system, and the effects of varying injection timing, rail pressure and exhaust gas recirculation on the combustion and emission parameters. The results show that DME combustion does not produce soot and with the use of exhaust gas recirculation NOX emissions can also be reduced to very low levels. However, high injection pressure and/or a DME adopted combustion system is required to improve the mixing process and thus reduce the combustion duration and carbon monoxide emissions.

This investigation includes a comparison of two Fischer Tropsch (FT) fuels derived from natural gas and a Rapeseed Methyl Ester (RME) fuel with Swedish low sulfur Diesel in terms of emissions levels, fuel consumption and combustion parameters. The engine used in the study was an AVL single cylinder heavy-duty engine, equipped with a cylinder head of a Volvo D12 engine. Two loads (25% and 100%) were investigated at a constant engine speed of 1200 rpm. The engine was calibrated to operate in different levels of EGR and with variable injections timings. A design of experiments was constructed to investigate the effects of these variables, and to identify optimal settings. The results showed that the soot emissions yielded by FT and RME fuels are up to 40 and 80 percent lower than those yielded by the Swedish Diesel. In addition the FT fuel gave slightly lower, and the RME significant higher NOx emissions than the Swedish Diesel.

An experimental study of a glow plug engine combustion process has been performed by applying chemiluminescence imaging. The major intent was to understand what kind of combustion is present in a glow plug engine and how the combustion process behaves in a small volume and at high engine speed. To achieve this, images of natural emitted light were taken and filters were applied for isolating the formaldehyde and hydroxyl species. Images were taken in a model airplane engine, 4.11 cm3, modified for optical access. The pictures were acquired using a high speed camera capable of taking one photo every second or fourth crank angle degree, and consequently visualizing the progress of the combustion process. The images were taken with the same operating condition at two different engine speeds: 9600 and 13400 rpm. A mixture of 65% methanol, 20% nitromethane and 15% lubricant was used as fuel.

Experiments were performed using a Light-Duty, single-cylinder, research engine in which the emissions, fuel consumption and combustion characteristics of two Fischer-Tropsch (F-T) Diesel fuels derived from natural gas and two conventional Diesel fuels (Swedish low sulfur Diesel and European EN 590 Diesel) were compared. Due to their low aromatic contents combustion with the F-T Diesel fuels resulted in lower soot emissions than combustion with the conventional Diesel fuels. The hydrocarbon emissions were also significantly lower with F-T fuel combustion. Moreover the F-T fuels tended to yield lower CO emissions than the conventional Diesel fuels. The low emissions from the F-T Diesel fuels, and the potential for producing such fuels from biomass, are powerful reason for future interest and research in this field.

Optical studies of combusting diesel sprays were done on three different alternative liquid fuels and compared to Swedish environmental class 1 diesel fuel (MK1). The alternative fuels were Rapeseed Oil Methyl Ester (RME), Palm Oil Methyl Ester (PME) and Fischer-Tropsch (FT) fuel. The studies were carried out in the Chalmers High Pressure High Temperature spray rig under conditions similar to those prevailing in a direct-injected diesel engine prior to injection. High speed shadowgraphs were acquired to measure the penetration of the continuous liquid phase, droplets and ligaments, and vapor penetration. Flame temperatures and relative soot concentrations were measured by emission based, line-of-sight, optical methods. A comparison between previous engine tests and spray rig experiments was conducted in order to provide a deeper explanation of the combustion phenomena in the engine tests.

In the study reported here the combustion and emission characteristics of a heavy duty six-cylinder diesel engine fuelled with dimethyl ether (DME) of chemical grade and DME with small and varying amounts of methanol and/or water were experimentally investigated. In addition, the size distribution of emitted particles and selected unregulated emissions were sampled. Methanol and water additions had a very limited effect on emissions, but affected the combustion processes in a way that accentuated the premixed combustion and thus caused more energy to be released early in the cycle. At high load, however, the effect was reversed, due to the lack of distinct premixed combustion. The results confirm that DME combustion does not generate any accumulation mode particles. The particles that are detected are smaller than the soot size range and do not occur in greater numbers than those from a diesel engine in the corresponding size range.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

The CFD model, based on the LANL KIVA-3 computer code, modified to account for the multi-step dimethyl ether, DME/air, oxidation chemistry, was developed and used to study the neat DME combustion dynamics in a constant volume at Diesel-like conditions and in the Volvo AH10A245DI Diesel engine. Constant volume simulations confirm high ignition quality of neat DME in air. The results of engine modeling illustrate that the injection schedule used for Diesel fuel is not optimal for DME. Surprisingly, the positive gain and peak pressure levels comparable with those for Diesel fuel were obtained using an early (∼ -20 ATDC) injection through a nozzle of a larger diameter at reduced injection pressures and velocities (∼150m/s) preventing too rapid spray atomization. At these conditions, combustion heat release has a specific two-stage character with a peak value placed behind the TDC.

This paper depicts the main topics of the experimental investigation on alcohol engine development field, aiming at the engineering targets for the emission levels. The first part of this study was focused on engine design optimization for running on ethanol mixed with poly-ethylene glycol (PEG) as ignition improver. It was shown that some design changes in compression ratio, turbine casing, injector nozzle configuration and exhaust pressure governor (EPG) activation, lead to a better engine thermodynamics and its thermochemistry. The second objective of this study was the investigation of engine performance and emission levels, when the ignition improver diethyl ether (DEE) would be generated on board via catalytically dehydration of ethanol, and used directly as soluble mixture or separately fumigated.

DME was tested in a heavy duty diesel engine and in an optically accessible high-temperature and pressure spray chamber in order to investigate and understand the effect of nozzle parameters on emissions, combustion and fuel spray concentration. The engine study clearly showed that smaller nozzle orifices were advantageous from combustion, efficiency and emissions considerations. Heat release analysis and fuel concentration images indicate that smaller orifices result in higher mixing rate between fuel and air due to reductions in the turbulence length scale, which reduce both the magnitude of fuel-rich regions and the steepness of fuel gradients in the spray, which enable more fuel to burn and thereby shorten the combustion duration.

A novel concept of combined hydrogen production and power generation system based on the combustion of aluminum in water is explored. The energy conversion system proposed is potentially able to provide four different energy sources, such us pressurized hydrogen, high temperature steam, heat, and work at the crankshaft on demand, as well as to fully comply with the environment sustainability requirements. Once aluminum oxide layer is removed, the pure aluminum can react with water producing alumina and hydrogen while releasing a significant amount of energy. Thus, the hydrogen can be stored for further use and the steam can be employed for energy generation or work production in a supplementary power system. The process is proved to be self-sustained and to provide a remarkable amount of energy available as work or hydrogen.

It has been previously shown that engine-out soot emissions can be reduced by using Fischer-Tropsch (FT) fuels, due to their lack of aromatics, compared to conventional Diesel fuels. In this investigation the engine-out emissions and fuel consumption parameters of an FT fuel derived from natural gas were compared to those of Swedish low sulfur diesel (MK1) when used in Low Temperature Combustion mode in a single cylinder heavy-duty diesel engine. The effects of varying Needle Opening Pressure (NOP), Charge Air Pressure (CAP) and Exhaust Gas Recirculation (EGR) according to an experimental design on the measured variables were also assessed. CAP and EGR were found to be the most significant factors for the combustion and emission parameters of both fuels. Increases in CAP resulted in lower soot emissions due to enhanced charge mixing, however NOx emissions rose as CAP increased.

Although there seems to be a consensus regarding the low emission potential of DME, there are still different opinions about why the low NOx emissions can be obtained without negative effects on thermal efficiency. Possible explanations are: The physical properties of DME affecting the spray and the mixture formation Different shape and duration of the heat release in combination with reduced heat losses In this paper an attempt is made to increase the knowledge of DME in relation to diesel fuel with respect to heat release and NOx formation. The emphasis has been to create injection conditions as similar as possible for both fuels. For that purpose the same injection system (CR), injection pressure (270 bar), injection timing and duration have been used for the two fuels. The only differences were the diameters of the nozzle holes, which were chosen to give the same fuel energy supply, and the physical properties of the fuels.

Laser-Rayleigh imaging has been employed to measure the relative fuel concentration in the gaseous jet region of DME sprays. The measurements were performed in an optically accessible diesel truck engine equipped with a common rail injection system. A one-hole nozzle was used to guarantee that the recorded pressure history was associated with the heat release in the imaged spray. To compensate for the low compression ratio in the modified engine the inlet air was preheated. Spray development was studied for two levels of preheating, from the start of injection to the point where all fuel was consumed. The results indicate that there is a strong correlation between the amount of unburned fuel present in the cylinder and the rate of heat release at a given time. The combustion can not be described as purely premixed or purely mixing-controlled at any time, but always has an element of both. After all fuel appears to have vanished there is still an extended period of heat release.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

In this paper an online method for automatically reducing complex chemical mechanisms for simulations of combustion phenomena has been developed. The method is based on the Quasi Steady State Assumption (QSSA). In contrast to previous reduction schemes where chemical species are selected only when they are in steady state throughout the whole process, the present method allows for species to be selected at each operating point separately generating an adaptive chemical kinetics. The method is used for calculations of a natural gas fueled engine operating under Homogenous Charge Compression Ignition (HCCI) conditions. We discuss criteria for selecting steady state species and the influence of these criteria on the results such as concentration profiles and temperature.

Having low aromatic compounds, high cetane rating, higher heat of combustion and almost zero sulphur content, a new paraffinic fuel (NPF), developed by Oroboros AB Sweden, was believed to receive attention as a new alternative fuel. Therefore, further investigation and combustion analyses were conducted in a research single-cylinder diesel engine, where detailed thermodynamic analyses were performed by Burst to File high frequency signal sampling code and by the Dragon software, revealing the real thermochemistry history. The aim of this investigation was an effort to reduce the pollution levels in Santiago de Chile by introducing this new paraffinic fuel (NPF). Experimental results have shown that the NPF fuel has a significant impact not only on the emission levels, but also on other energetic parameters of the engine such as ignition delay, cylinder peak pressure, heat release gradient, indicated efficiency etc.

Ion current measurements can give information useful for controlling the combustion stability in a multi-cylinder engine. Operation near the dilution limit (air or EGR) can be achieved and it can be optimized individually for the cylinders, resulting in a system with better engine stability for highly diluted mixtures. This method will also compensate for engine wear, e.g. changes in volumetric efficiency and fuel injector characteristics. Especially in a port injected engine, changes in fuel injector characteristics can lead to increased emissions and deteriorated engine performance when operating with a closed-loop lambda control system. One problem using the ion-current signal to control engine stability near the lean limit is the weak signal resulting in low signal to noise ratio. Measurements presented in this paper were made on a turbocharged 9.6 liter six cylinder natural gas engine with port injection.