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Technical Paper

CFD Modeling of Processes Upstream of the Catalyst for Urea SCR NOx Reduction Systems in Heavy-Duty Diesel Applications

2011-04-12
2011-01-1322
This project is one component of a broader effort whose ultimate goal is to provide CFD-based tools that can be used to optimize the design of urea SCR NOx aftertreatment systems for heavy-duty diesel engines. Here the focus is on predicting the distributions of key chemical species (ammonia, in particular) at the inlet to the catalysts. Two aspects of the physical models have been emphasized: the multi-phase models, and the gas-phase chemistry models. A hierarchy of four simplified geometric configurations has been used for model development and parametric studies, and to establish the appropriate level of physical modeling and numerical fidelity required. The resulting physical and numerical parameters then have been used to model a production SCR system. Initial quantitative comparisons with experimental measurements are encouraging.
Technical Paper

Styrofoam Precursors as Drop-in Diesel Fuel

2013-09-08
2013-24-0108
Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.
Technical Paper

Injection of Fuel at High Pressure Conditions: LES Study

2011-09-11
2011-24-0041
This paper presents a large eddy simulation study of the liquid spray mixing with hot ambient gas in a constant volume vessel under engine-like conditions with the injection pressure of 1500 bar, ambient density 22.8 kg/m₃, ambient temperature of 900 K and an injector nozzle of 0.09 mm. The simulation results are compared with the experiments carried out by Pickett et al., under similar conditions. Under modern direct injection diesel engine conditions, it has been argued that the liquid core region is small and the droplets after atomization are fine so that the process of spray evaporation and mixing with the air is controlled by the heat and mass transfer between the ambient hot gas and central fuel flow. To examine this hypothesis a simple spray breakup model is tested in the present LES simulation. The simulations are performed using an open source compressible flow solver, in OpenFOAM.
Technical Paper

Influence of the Wall Temperature and Combustion Chamber Geometry on the Performance and Emissions of a Mini HCCI Engine Fueled with Diethyl Ether

2008-04-14
2008-01-0008
Nowadays for small-scale power generation there are electrochemical batteries and mini engines. Many efforts have been done for improving the power density of the batteries but unfortunately the value of 1 MJ/kg seems to be asymptotic. If the energy source is an organic fuel which has an energy density of around 29 MJ/kg with a minimum overall efficiency of only 3.5%, this device would surpass the batteries. This paper is the fifth of a series of publications aimed to study the HCCI combustion process in the milli domain at high engine speed in order to design and develop VIMPA, Vibrating Microengine for Low Power Generation and Microsystems Actuation. Previous studies ranged from general characterization of the HCCI combustion process by using metal and optical engines, to more specific topics for instance the influence of the boundary layer and quenching distance on the quality of the combustion.
Technical Paper

Influence of the Compression Ratio on the Performance and Emissions of a Mini HCCI Engine Fueled Ether with Diethyl

2007-10-29
2007-01-4075
Power supply systems play a very important role in applications of everyday life. Mainly, for low power generation, there are two ways of producing energy: electrochemical batteries and small engines. In the last few years many improvements have been carried out in order to obtain lighter batteries with longer duration but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. If the energy source is an organic fuel with an energy density of around 29 MJ/kg and a minimum overall efficiency of only 3.5%, this device can surpass the batteries. Nowadays the most efficient combustion process is HCCI combustion which is able to combine high energy conversion efficiency and low emission levels with a very low fuel consumption. In this paper, an investigation has been carried out concerning the effects of the compression ratio on the performance and emissions of a mini, Vd = 4.11 [cm3], HCCI engine fueled with diethyl ether.
Technical Paper

Improving Ion Current Feedback for HCCI Engine Control

2007-10-29
2007-01-4053
In HCCI you do not have the same control of the combustion like in SI and Diesel engines. Controlling the start of a combustion event is a difficult task and requires feedback from previous cycles. This feedback can be retrieved from ion current measurements. By applying a voltage over the spark gap, ions will lead a current and a signal that represents the combustion in the cylinder will be retrieved. Voltages of 450 V were used. The paper describes a new method to enhance the combustion phasing from the Ion current trace in HCCI engines. The method is using the knowledge of how the signal should look. This is known due to the fact that the shape of the ion current signal is similar from cycle to cycle. This new observation is shown in the paper. Also the correlation between the ion current and CA50 was studied. Later the signals have been used for combustion feedback.
Technical Paper

Mini High Speed HCCI Engine Fueled with Ether: Load Range, Emission Characteristics and Optical Analysis

2007-08-05
2007-01-3606
Power supply systems play a very important role in everyday life applications. There are mainly two ways of producing energy for low power generation: electrochemical batteries and small engines. In the last few years, many improvements have been carried out in order to obtain lighter batteries with longer durations but unfortunately the energy density of 1 MJ/kg seems to be an asymptotic value. An energy source constituted of an organic fuel with an energy density around 29 MJ/kg and a minimum overall efficiency of only 3.5% could surpass batteries. Nowadays, the most efficient combustion process is HCCI combustion which has the ability to combine a high energy conversion efficiency with low emission levels and a very low fuel consumption. The present paper describes an investigation carried out on a modified model airplane engine, on how a pure HCCI combustion behaves in a small volume, Vd = 4.11 cm3, at very high engine speeds (up to 17,500 [rpm]).
Technical Paper

Low Soot, Low NOx in a Heavy Duty Diesel Engine Using High Levels of EGR

2005-10-24
2005-01-3836
The objective of the study presented here was to examine the possibility of simultaneously reducing soot and nitrogen oxide (NOx) emissions from a heavy duty diesel engine, using very high levels of EGR (exhaust gas recirculation). The investigation was carried out using a 2 litre DI single cylinder diesel engine. Two different EGR strategies were examined. One entailed maintaining a constant charge air pressure with a varied exhaust back pressure in order to change the amount of EGR. In the other strategy a constant pressure difference was maintained over the engine, resulting in different equivalence ratios at similar EGR levels. EGR levels of 60 % or more significantly reduced both soot and NOx emissions at 25 % engine load with constant charge air pressure and increasing exhaust back pressure. However, combustion under these conditions was incomplete, resulting in high emissions of carbon monoxide (CO), unburned hydrocarbons (HC) and high fuel consumption.
Technical Paper

Transient Emission Predictions With Quasi Stationary Models

2005-10-24
2005-01-3852
Heavy trucks contribute significantly to the overall air pollution, especially NOx and PM emissions. Models to predict the emissions from heavy trucks in real world on road conditions are therefore of great interest. Most such models are based on data achieved from stationary measurements, i.e. engine maps. This type of “quasi stationary” models could also be of interest in other applications where emission models of low complexity are desired, such as engine control and simulation and control of exhaust aftertreatment systems. In this paper, results from quasi stationary calculations of fuel consumption, CO, HC, NOx and PM emissions are compared with time resolved measurements of the corresponding quantities. Measurement data from three Euro 3-class engines is used. The differences are discussed in terms of the conditions during transients and correction models for quasi stationary calculations are presented. Simply using engine maps without transient correction is not sufficient.
Technical Paper

Multi-Output Control of a Heavy Duty HCCI Engine Using Variable Valve Actuation and Model Predictive Control

2006-04-03
2006-01-0873
Autoignition of a homogeneous mixture is very sensitive to operating conditions, therefore fast control is necessary for reliable operation. There exists several means to control the combustion phasing of an Homogeneous Charge Compression Ignition (HCCI) engine, but most of the presented controlled HCCI result has been performed with single-input single-output controllers. In order to fully operate an HCCI engine several output variables need to be controlled simultaneously, for example, load, combustion phasing, cylinder pressure and emissions. As these output variables have an effect on each other, the controller should be of a structure which includes the cross-couplings between the output variables. A Model Predictive Control (MPC) controller is proposed as a solution to the problem of load-torque control with simultaneous minimization of the fuel consumption and emissions, while satisfying the constraints on cylinder pressure.
Technical Paper

Low Temperature Combustion in a Heavy Duty Diesel Engine Using High Levels of EGR

2006-04-03
2006-01-0075
The possibilities for extending the range of engine loads in which soot and NOx emissions can be minimised by using low temperature combustion in conjunction with high levels of EGR was investigated in a series of experiments with a single cylinder research engine. The results show that very low levels of both soot and NOx emissions can be achieved at engine loads up to 50 % by reducing the compression ratio to 14 and applying high levels of EGR (up to approximately 60 %). Unfortunately, the low temperature combustion is accompanied by increases in fuel consumption and emissions of both HC and CO. However, these drawbacks can be reduced by advancing the injection timing. The research engine was a 2 litre direct injected (DI), supercharged, heavy duty, single cylinder diesel engine with a geometry based on Volvo's 12 litre engine, and the amount of EGR was increased by adjusting the exhaust back pressure while keeping the charge air pressure constant.
Technical Paper

Modelling Diesel Engine Combustion and NOx Formation for Model Based Control and Simulation of Engine and Exhaust Aftertreatment Systems

2006-04-03
2006-01-0687
Emissions standards are becoming increasingly harder to reach without the use of exhaust aftertreatment systems such as Selective Catalytic Reduction and particulate filters. In order to make efficient use of these systems it is important to have accurate models of engine-out emissions. Such models are also useful for optimizing and controlling next-generation engines without aftertreatment using for example exhaust gas recirculation (EGR). Engines are getting more advanced using systems such as common rail fuel injection, variable geometry turbochargers (VGT) and EGR. With these new technologies and active control of the injection timing, more sophisticated models than simple stationary emission maps must be used to get adequate results. This paper is focused on the calculation of engine-out NOx and engine parameters such as cylinder pressure, temperature and gas flows.
Technical Paper

A Combined 3D/Lumped Modeling Approach to Ammonia SCR After-treatment Systems: Application to Mixer Designs

2006-04-03
2006-01-0469
In practical applications of ammonia SCR aftertreatment systems using urea as the reductant storage compound, one major difficulty is the often constrained packaging envelope. As a consequence, complete mixing of the urea solution into the exhaust gas stream as well as uniform flow and reductant distribution profiles across the catalyst inlet face are difficult to achieve. This paper discusses a modeling approach, where a combination of 3D CFD and a lumped parameter SCR model enables the prediction of system performance, even with non-uniform exhaust flow and ammonia distribution profiles. From the urea injection nozzle to SCR catalyst exit, each step in the modeling process is described and validated individually. Finally the modeling approach was applied to a design study where the performance of a range of urea-exhaust gas mixing sections was evaluated.
Technical Paper

Investigation of Boundary Layer Behaviour in HCCI Combustion using Chemiluminescence Imaging

2005-10-24
2005-01-3729
A five-cylinder diesel engine, converted to a single cylinder operated optical engine is run in Homogeneous Charge Compression Ignition (HCCI) mode. A blend of iso-octane and n-heptane is used as fuel. An experimental study of the horizontal boundary layer between the main combustion and the non-reacting surface of the combustion chamber is conducted as a function of speed, load, swirl and injection strategy. The combustion behaviour is monitored by chemiluminescence measurements. For all cases an interval from -10 to 16 crank angles after top dead center (CAD ATDC) in steps of one CAD are studied. One image-intensified camera observes the boundary layer up close from the side through a quartz cylinder liner while a second camera has a more global view from below to see more large scale structure of the combustion. The averaged chemiluminescence intensity from the HCCI combustion is seen to scale well with the rate of heat release.
Technical Paper

Combustion Chamber Wall Temperature Measurement and Modeling During Transient HCCI Operation

2005-10-24
2005-01-3731
In this paper the combustion chamber wall temperature was measured by the use of thermographic phosphor. The temperature was monitored over a large time window covering a load transient. Wall temperature measurement provide helpful information in all engines. This temperature is for example needed when calculating heat losses to the walls. Most important is however the effect of the wall temperature on combustion. The walls can not heat up instantaneously and the slowly increasing wall temperature following a load transient will affect the combustion events sucseeding the transient. The HCCI combustion process is, due to its dependence on chemical kinetics more sensitive to wall temperature than Otto or Diesel engines. In depth knowledge about transient wall temperature could increase the understanding of transient HCCI control. A “black box” state space model was derived which is useful when predicting transient wall temperature.
Journal Article

UHC and CO Emissions Sources from a Light-Duty Diesel Engine Undergoing Dilution-Controlled Low-Temperature Combustion

2009-09-13
2009-24-0043
Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.
Technical Paper

Influence of Inlet Temperature and Hot Residual Gases on the Performances of a Mini High Speed Glow Plug Engine

2006-11-13
2006-32-0057
Nowadays the power supplying systems have a fundamental importance for all small and portable devices. For low power applications, there are two main ways for producing power: electrochemical batteries and mini engines. Even though in recent years many developments have been carried out in improving the design of batteries, the energy density of 1MJ/kg seems to be an asymptotic value. If the energy source is a hydrocarbon fuel, whose energy density is 46 MJ/kg, with an overall efficiency of only 2.5 % it is possible to surpass the electrochemical batteries. On the other hand, having a mini engine, as energy source, implies three main problems: vibrations, noise and emissions. A light (230 g) model airplane engine with a displacement volume of 4.11 cm3 and a geometrical compression ratio of 13.91 has been studied. The work carried out in this paper can be divided basically in three parts.
Technical Paper

Fuel Injection and Mean Swirl Effects on Combustion and Soot Formation in Heavy Duty Diesel Engines

2007-04-16
2007-01-0912
High-speed video imaging in a swirl-supported (Rs = 1.7), direct-injection heavy-duty diesel engine operated with moderate-to-high EGR rates reveals a distinct correlation between the spatial distribution of luminous soot and mean flow vorticity in the horizontal plane. The temporal behavior of the experimental images, as well as the results of multi-dimensional numerical simulations, show that this soot-vorticity correlation is caused by the presence of a greater amount of soot on the windward side of the jet. The simulations indicate that while flow swirl can influence pre-ignition mixing processes as well as post-combustion soot oxidation processes, interactions between the swirl and the heat release can also influence mixing processes. Without swirl, combustion-generated gas flows influence mixing on both sides of the jet equally. In the presence of swirl, the heat release occurs on the leeward side of the fuel sprays.
Technical Paper

Effects on Combustion by Using Kerosene or MK1 Diesel

2007-01-23
2007-01-0002
Because of coming emission legislation emissions of nitrogen oxides and particular matter (PM) have to be substantially decreased. Several new concepts for low-emission engines have been proposed such as different variants on the HCCI engine but also engines with exhaust aftertreatment to reduce exhaust emissions. It is not only the engine design that influences emissions but also the fuel that is used. This study compares kerosene fuel with commercial diesel fuel. Kerosene fuel has considerable market availability since it is used in the aviation transport sector. Therefore it is possible to supply the land-based transportation sector with this fuel in relatively large quantities. Kerosene is a fuel with lower cetane number than diesel fuel, thus giving a longer ignition delay, making it viable for lower emissions since the longer ignition delay gives a longer time for the fuel to mix with the in-cylinder gas prior to combustion onset.
Technical Paper

Detailed Heat Release Analyses with Regard to Combustion of RME and Oxygenated Fuels in an HSDI Diesel Engine

2007-04-16
2007-01-0627
Experiments on a modern DI Diesel engine were carried out: The engine was fuelled with standard Diesel fuel, RME and a mixture of 85% standard Diesel fuel, 5% RME and 10% higher alcohols under low load conditions (4 bar IMEP). During these experiments, different external EGR levels were applied while the injection timing was chosen in a way to keep the location of 50% heat release constant. Emission analysis results were in accordance with widely known correlations: Increasing EGR rates lowered NOx emissions. This is explained by a decrease of global air-fuel ratio entailing longer ignition delay. Local gas-fuel ratio increases during ignition delay and local combustion temperature is lowered. Exhaust gas analysis indicated further a strong increase of CO, PM and unburned HC emissions at high EGR levels. This resulted in lower combustion efficiency. PM emissions however, decreased above 50% EGR which was also in accordance with previously reported results.
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