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Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.

A novel approach to condition the lubricant at a fixed station in the oil circuit is explored as a potential means to reduce additive requirements or increase oil drain interval. This study examines the performance of an innovative oil filter which releases no additives into the lubricant, yet enhances the acid control function typically performed by detergent and dispersant additives. The filter chemically conditions the crankcase oil during engine operation by sequestering acidic compounds derived from engine combustion and lubricant degradation. Long duration tests with a heavy-duty diesel engine show that the oil conditioning with the strong base filter reduces lubricant acidity (TAN), improves Total Base Number (TBN) retention, and slows the rate of viscosity increase and oxidation. The results also indicate that there may be a reduction in wear and corrosion.

This paper presents a numerical model of the rotational and lateral dynamics of the piston (secondary motion) and piston slap in mixed lubrication. Piston dynamic behavior, frictional and impact forces are predicted as functions of crank angle. The model considers piston skirt surface waviness, roughness, skirt profile, thermal and mechanical deformations. The model considers partially-flooded skirt and calculates the pressure distributions and friction in the piston skirt region for both hydrodynamic and boundary lubrication. Model predictions are compared with measurements of piston position using gap sensors in a single-cylinder engine and the comparison between theory and measurement shows remarkable agreement.

A complete one-dimensional mixed lubrication model has been developed to predict oil film thickness and friction of the piston ring-pack. An average flow model and a roughness contact model are used to consider the effects of surface roughness on both hydrodynamic and boundary lubrication. Effects of shear-thinning and liner temperature on lubricant viscosity are included. An inlet condition is applied by considering the unsteady wetting location at the leading edge of the ring. A ‘film non-separation’ exit condition is proposed to replace Reynolds exit condition when the oil squeezing becomes dominant. Three lubrication modes are considered in the model, namely, pure hydrodynamic, mixed, and pure boundary lubrication. All of these considerations are crucial for studying the oil transport, asperity contact, and friction especially in the top dead center (TDC) region where the oil control ring cannot reach.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

Lowering lubricant viscosity to reduce friction generally carries a side-effect of increased metal-metal contact in mixed or boundary lubrication, for example near top ring reversal along the engine cylinder liner. A strategy to reduce viscosity without increased metal-metal contact involves controlling the local viscosity away from top-ring-reversal locations. This paper discusses the implementation of insulation or thermal barrier coating (TBC) as a means of reducing local oil viscosity and power cylinder friction in internal combustion engines with minimal side-effects of increased wear. TBC is selectively applied to the outside diameter of the cylinder liner to increase the local oil temperature along the liner. Due to the temperature dependence of oil viscosity, the increase in temperature from insulation results in a decrease in the local oil viscosity.