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Journal Article

Ash Effects on Diesel Particulate Filter Pressure Drop Sensitivity to Soot and Implications for Regeneration Frequency and DPF Control

2010-04-12
2010-01-0811
Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.
Journal Article

Reduction of Cold-Start Emissions through Valve Timing in a GDI Engine

2016-04-05
2016-01-0827
This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

Assessment of Gasoline Direct Injection Engine Cold Start Particulate Emission Sources

2017-03-28
2017-01-0795
The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Journal Article

Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

2011-04-12
2011-01-1305
The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.
Journal Article

CoQ Tradeoffs in Manufacturing Process Improvement and Inspection Strategy Selection: A Case Study of Welded Automotive Assemblies

2012-04-16
2012-01-0514
In today's highly competitive automotive markets manufacturers must provide high quality products to survive. Manufacturers can achieve higher levels of quality by changing or improving their manufacturing process and/or by product inspection where many strategies with different cost implications are often available. Cost of Quality (CoQ) reconciles the competing objectives of quality maximization and cost minimization and serves as a useful framework for comparing available manufacturing process and inspection alternatives. In this paper, an analytic CoQ framework is discussed and some key findings are demonstrated using a set of basic inspection strategy scenarios. A case of a welded automotive assembly is chosen to explore the CoQ tradeoffs in inspection strategy selection and the value of welding process improvement. In the assembly process, many individual components are welded in series and each weld is inspected for quality.
Journal Article

Soot and Ash Deposition Characteristics at the Catalyst-Substrate Interface and Intra-Layer Interactions in Aged Diesel Particulate Filters Illustrated using Focused Ion Beam (FIB) Milling

2012-04-16
2012-01-0836
The accumulation of soot and lubrication-derived ash particles in a diesel particulate filter (DPF) increases exhaust flow restriction and negatively impacts engine efficiency. Previous studies have described the macroscopic phenomenon and general effects of soot and ash accumulation on filter pressure drop. In order to enhance the fundamental understanding, this study utilized a novel apparatus that of a dual beam scanning electron microscope (SEM) and focused ion beam (FIB), to investigate microscopic details of soot and ash accumulation in the DPF. Specifically, FIB provides a minimally invasive technique to analyze the interactions between the soot, ash, catalyst/washcoat, and DPF substrate with a high degree of measurement resolution. The FIB utilizes a gallium liquid metal ion source which produces Ga+ ions of sufficient momentum to directionally mill away material from the soot, ash, and substrate layers on a nm-μm scale.
Journal Article

Sensitivity Analysis of Ash Packing and Distribution in Diesel Particulate Filters to Transient Changes in Exhaust Conditions

2012-04-16
2012-01-1093
Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.
Journal Article

In-Situ Optical Analysis of Ash Formation and Transport in Diesel Particulate Filters During Active and Passive DPF Regeneration Processes

2013-04-08
2013-01-0519
The formation and transport processes governing the build-up of incombustible ash deposits in diesel particulate filters (DPF) are influenced to a large extent by the filter's operating history. More specifically, the regeneration process, whether active, passive, or some variation of the two, has long been assumed to exert significant influence on the resulting ash characteristics. Until recently, only limited circumstantial evidence was available to describe differences in ash properties and distribution impacting DPF performance for filters subjected to different regeneration strategies. This work presents, for the first time, results from a comprehensive series of evaluations with optically-accessible DPF core samples showing the processes controlling the formation, transport, and interaction of the soot and ash deposits over a range of DPF regeneration conditions.
Journal Article

Ash Accumulation and Impact on Sintered Metal Fiber Diesel Particulate Filters

2015-04-14
2015-01-1012
While metal fiber filters have successfully shown a high degree of particle retention functionality for various sizes of diesel engines with a low pressure drop and a relatively high filtration efficiency, little is known about the effects of lubricant-derived ash on the fiber filter systems. Sintered metal fiber filters (SMF-DPF), when used downstream from a diesel engine, effectively trap and oxidize diesel particulate matter via an electrically heated regeneration process where a specific voltage and current are applied to the sintered alloy fibers. In this manner the filter media essentially acts as a resistive heater to generate temperatures high enough to oxidize the carbonaceous particulate matter, which is typically in excess of 600°C.
Journal Article

Direct Measurements of Soot/Ash Affinity in the Diesel Particulate Filter by Atomic Force Microscopy and Implications for Ash Accumulation and DPF Degradation

2014-04-01
2014-01-1486
Inorganic engine lubricant additives, which have various specific, necessary functions such as anti-wear, leave the combustion chamber bound to soot particles (approximately ≤1% by mass) as ash [13], and accumulate in aftertreatment components. The diesel particulate filter (DPF) is especially susceptible to ash-related issues due to its wall-flow architecture which physically traps most of the soot and ash emissions. Accumulated lubricant-derived ash results in numerous problems including increased filter pressure drop and decreased catalytic functionality. While much progress has been made to understand the macroscopic details and effects of ash accumulation on DPF performance, this study explores the nano- and micron-scale forces which impact particle adhesion and mobility within the particulate filter.
Journal Article

On the Nature of Particulate Emissions from DISI Engines at Cold-Fast-Idle

2014-04-01
2014-01-1368
Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.
Journal Article

Effect of Operation Strategy on First Cycle CO, HC, and PM/PN Emissions in a GDI Engine

2015-04-14
2015-01-0887
The impact of the operating strategy on emissions from the first combustion cycle during cranking was studied quantitatively in a production gasoline direct injection engine. A single injection early in the compression cycle after IVC gives the best tradeoff between HC, particulate mass (PM) and number (PN) emissions and net indicated effective pressure (NIMEP). Retarding the spark timing, it does not materially affect the HC emissions, but lowers the PM/PN emissions substantially. Increasing the injection pressure (at constant fuel mass) increases the NIMEP but also the PM/PN emissions.
Technical Paper

Engine-Out “Dry” Particular Matter Emissions from SI Engines

1997-10-01
972890
The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.
Technical Paper

Engine Wear Modeling with Sensitivity to Lubricant Chemistry: A Theoretical Framework

2007-04-16
2007-01-1566
The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.
Technical Paper

Modeling Costs and Fuel Economy Benefits of Lightweighting Vehicle Closure Panels

2008-04-14
2008-01-0370
This paper illustrates a methodology in which complete material-manufacturing process cases for closure panels, reinforcements, and assembly are modeled and compared in order to identify the preferred option for a lightweight closure design. First, process-based cost models are used to predict the cost of lightweighting the closure set of a sample midsized sports utility vehicle (SUV) via material and process substitution. Weight savings are then analyzed using a powertrain simulation to understand the impact of lightweighting on fuel economy. The results are evaluated in the context of production volume and total mass change.
Technical Paper

Investigation of the Dilution Process for Measurement of Particulate Matter from Spark-Ignition Engines

1998-10-19
982601
Measurements of particulate matter (PM) from spark ignition (SI) engine exhaust using dilution tunnels will become more prevalent as emission standards are tightened. Hence, a study of the dilution process was undertaken in order to understand how various dilution related parameters affect the accuracy with which PM sizes and concentrations can be determined. A SI and a compression ignition (CI) engine were separately used to examine parameters of the dilution process; the present work discusses the results in the context of SI exhaust dilution. A Scanning Mobility Particle Sizer (SMPS) was used to measure the size distribution, number density, and volume fraction of PM. Temperature measurements in the exhaust pipe and dilution tunnel reveal the degree of mixing between exhaust and dilution air, the effect of flowrate on heat transfer from undiluted and diluted exhaust to the environment, and the minimum permissible dilution ratio for a maximum sample temperature of 52°C.
Technical Paper

Crash Safety of Lithium-Ion Batteries Towards Development of a Computational Model

2010-04-12
2010-01-1078
Battery packs for Hybrids, Plug-in Hybrids, and Electric Vehicles are assembled from a system of modules (sheets) with a tight sheet metal casing around them. Each module consists of an array of individual cells which vary in the composition of electrodes and separator from one manufacturer to another. In this paper a general procedure is outlined on the development of a constitutive and computational model of a cylindrical cell. Particular emphasis is placed on correct prediction of initiation and propagation of a tearing fracture of the steel can. The computational model correctly predicts rupture of the steel can which could release aggressive chemicals, fumes, or spread the ignited fire to the neighboring cells. The initiation site of skin fracture depends on many factors such as the ductility of the casing material, constitutive behavior of the system of electrodes, and type of loading.
Technical Paper

Inverse Method for Measuring Weld Temperatures during Resistance Spot Welding

2001-03-05
2001-01-0437
A new monitoring system predicts the progression of welding temperature fields during resistance spot welding. The system captures welding voltages and currents to predict contact diameters and simulate temperature fields. The system accurately predicts fusion lines and heat-affected zones. Accuracy holds even for electrode tips used for a few thousand welds of zinc coated steels.
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