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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Fracture split forged steel connecting rods are utilized in many new high performance automotive engines to increase durability. Higher strength levels are needed as the power density increases. Fracture splitting without plastic deformation is necessary for manufacturability. Metallurgical design is a key for achieving the required performance levels. Several medium carbon steels containing 0.07 wt pct P, 0.06 wt pct S and various amounts of Mn, Si, V, and N were produced by vacuum induction melting laboratory heats and hot working the cast ingots into plates. The plates were cooled at varying rates to simulate typical cooling methods after forging. Microstructures were generally ferrite and pearlite as evaluated by light optical and scanning electron microscopy. Mechanical properties were determined by standard tensile tests, high strain rate notched tensile tests, and Charpy V-notch impact tests to assess “splittability”.

Quenching and partitioning (Q&P) is a novel heat treatment to produce third generation advanced high-strength steels (AHSS). The influence of carbon on mechanical properties of Q&P treated CMnSi-steels was studied using 0.3C-1.5Mn-1.5Si and 0.4C-1.5Mn-1.5Si alloys. Full austenitization followed by two-step Q&P treatments were conducted using varying partitioning times and a fixed partitioning temperature of 400 °C. The results were compared to literature data for 0.2C-1.6Mn-1.6Si, 0.2-3Mn-1.6Si and 0.3-3Mn-1.6Si Q&P treated steels. The comparison showed that increasing the carbon content from 0.2 to 0.4 wt pct increased the ultimate tensile strength by 140 MPa per 0.1 wt pct C up to 1611 MPa without significantly decreasing ductility for the partitioning conditions used. Increased alloy carbon content did not substantially increase the retained austenite fractions. The best combinations of ultimate tensile strength and total elongation were obtained using short partitioning times.

This article is concerned with identification of true stress-strain curve under biaxial tension of thermoplastic polymers. A new type of biaxial tension attachment was embedded first in a universal material test machine, which is able to transform unidirectional loading of the test machine to biaxial loading on the specimen with constant velocity. Cruciform specimen geometry was optimized via FE modeling. Three methods of calculating true stress in biaxial tension tests were compared, based on incompressibility assumption, linear elastic theory and inverse engineering method, respectively. The inverse engineering method is more appropriate for thermoplastic polymers since it considers the practical volume change of the material during biaxial tension deformation. The strategy of data processing was established to obtain biaxial tension true stress-strain curves of different thermoplastic polymers.

In today's highly competitive automotive markets manufacturers must provide high quality products to survive. Manufacturers can achieve higher levels of quality by changing or improving their manufacturing process and/or by product inspection where many strategies with different cost implications are often available. Cost of Quality (CoQ) reconciles the competing objectives of quality maximization and cost minimization and serves as a useful framework for comparing available manufacturing process and inspection alternatives. In this paper, an analytic CoQ framework is discussed and some key findings are demonstrated using a set of basic inspection strategy scenarios. A case of a welded automotive assembly is chosen to explore the CoQ tradeoffs in inspection strategy selection and the value of welding process improvement. In the assembly process, many individual components are welded in series and each weld is inspected for quality.

The fuel energy consumption of subsonic air transportation is examined. The focus is on identification and quantification of fundamental engineering design tradeoffs which drive the design of subsonic tube and wing transport aircraft. The sensitivities of energy efficiency to recent and forecast technology developments are also examined.

The windage tray effect on aeration in the engine sump was assessed by replacing much of the windage tray materials with wire meshes of various blockages. The mesh was to prevent direct impact of the oil drops spinning off the crank shaft onto the sump oil, and simultaneously, to provide sufficient drainage so that there was no significant build up of windage tray oil film that would interact with these droplets. Aeration at the oil pump inlet was measured by X-ray absorption in a production V-6 SI engine motoring at 2000 to 6000 rpm. Within experimental uncertainty, these windage tray changes had no effect on aeration. Thus activities in the sump such as the interaction of the oil drops spun from the crank shaft with the sump oil or with the windage tray, and the agitation of the sump oil by the crank case gas, were not major contributors to aeration at the pump inlet.

We present results which verify the design parameters and suggest performance capabilities/limitations of the Mars Gravity Biosatellite's proposed atmospherics control subassembly. Using a combination of benchtop prototype testing and analytic techniques, we derive control requirements for ammonia. Further, we demonstrate the dehumidification performance of our proposed partial gravity condensing heat exchanger. Ammonia production is of particular concern in rodent habitats. The contaminant is released following chemical degradation of liquid waste products. The rate of production is linked to humidity levels and to the design of habitat modules in terms of bedding substrate, air flow rates, choice of structural materials, and other complex factors. Ammonia buildup can rapidly lead to rodent health concerns and can negatively impact scientific return.

A series of bending fatigue tests were conducted and S-N data were obtained for two groups of 4320 steel samples: (1) carburized, quenched and tempered, (2) carburized, quenched, tempered and shot peened. Shot peening improved the fatigue life and endurance limit. The S-N data exhibited large scatter, especially for carburized samples and at the high cycle life regime. Sample characterization work was performed and scatter bands were established for residual stress distributions, in addition to fracture and fatigue properties for 4320 steel. Moreover, a fatigue life analysis was performed using fracture mechanics and strain life fatigue theories. Scatter in S-N curves was established computationally by using the lower bound and upper bound in materials properties, residual stress and IGO depth in the input data. The results for fatigue life analysis, using either computational fracture mechanics or strain life theory, agreed reasonably well with the test data.

The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.

Fine water mist has become a commercial technology for fire suppression in multiple applications. With funding from NASA, ADA Technologies, Inc. (ADA) is developing a handheld fine water mist fire extinguisher for use on manned spacecraft and in future planetary habitats. This design employs only water and nitrogen as suppression agents to allow local refill and reuse. The prototype design incorporates features to generate a uniform fine water mist regardless of the direction of the gravitational vector or lack of gravity altogether. The system has been proven to extinguish open fires and hidden fire scenarios in tests conducted at the Colorado School of Mines (CSM). This design can be deployed as a portable extinguisher or as an automated system for local fire protection in instrument racks or storage spaces. Continued development will result in prototype hardware suitable for use on future manned spacecraft.

This paper illustrates a methodology in which complete material-manufacturing process cases for closure panels, reinforcements, and assembly are modeled and compared in order to identify the preferred option for a lightweight closure design. First, process-based cost models are used to predict the cost of lightweighting the closure set of a sample midsized sports utility vehicle (SUV) via material and process substitution. Weight savings are then analyzed using a powertrain simulation to understand the impact of lightweighting on fuel economy. The results are evaluated in the context of production volume and total mass change.

Knowledge of the net thinning strain that occurs in a sheet as it is bent over a single radius is an important component in understanding sheet metal formability. The present study extends the initial work of Swift on thinning during plane-strain bending to sheet steels with power law stress-strain behavior and with the inclusion of friction. The experimental data come from studies on the enhanced forming limit curve on DQSK steel and analysis of the curl behavior of 590R and DP600 steels. Results for single radius bending from these studies are used in the present investigation. It has been found that the amount of net thinning strain depends on back tension, initial plane-strain yield strength, and the maximum true bending strain calculated for the neutral plane at the mid-thickness of the sheet.

Drawbeads in production stamping dies often have insufficient penetration of the male bead into the female cavity. With insufficient penetration, the actual bending radii of the sheet metal are larger than the geometrical radii of the drawbead. The actual bending radii in the sheet directly affect the force that restrains sheet movement. To predict the restraining stress due to a drawbead, it is necessary to know the actual bending radii in the sheet as it passes though the drawbead. Data from a previous study are used to develop empirical regression equations for predicting measured radii of the sheet that is bent around the radii in a drawbead. A physical model for the evolution of the sheet radii as the drawbead closes is proposed. This model is consistent with the empirical equations and the mechanics of the sheet bending process.

ADA Technologies, Inc. has designed and built a microgravity-tolerant portable fire extinguisher prototype for use in manned spacecraft and planetary habitats. This device employs Fine Water Mist (FWM) as the fire extinguishing agent, and is refillable from standard stores on long-duration missions. The design uses a single storage tank for minimal mass and volume. The prototype employs a dual-fluid atomizer concept where the pressurant gas (nitrogen) also enhances the water atomization process to generate a droplet size distribution in the optimum diameter range of 10 to 50 micrometers. The expanding discharge gas plume carries the mist to the immediate vicinity of the fire where its extensive surface area promotes high heat transfer rates. A series of 80 fire suppression tests was recently completed to evaluate design options for the hardware and validate performance on three representative fire scenarios.

Battery packs for Hybrids, Plug-in Hybrids, and Electric Vehicles are assembled from a system of modules (sheets) with a tight sheet metal casing around them. Each module consists of an array of individual cells which vary in the composition of electrodes and separator from one manufacturer to another. In this paper a general procedure is outlined on the development of a constitutive and computational model of a cylindrical cell. Particular emphasis is placed on correct prediction of initiation and propagation of a tearing fracture of the steel can. The computational model correctly predicts rupture of the steel can which could release aggressive chemicals, fumes, or spread the ignited fire to the neighboring cells. The initiation site of skin fracture depends on many factors such as the ductility of the casing material, constitutive behavior of the system of electrodes, and type of loading.

A new monitoring system predicts the progression of welding temperature fields during resistance spot welding. The system captures welding voltages and currents to predict contact diameters and simulate temperature fields. The system accurately predicts fusion lines and heat-affected zones. Accuracy holds even for electrode tips used for a few thousand welds of zinc coated steels.

With the increased use of tubular steel products, especially for automotive hydroforming applications, there is increased interest in understanding the mechanical properties measured by tensile tests from specimens of different orientations in the tube. In this study, two orientations of tensile specimens were evaluated -- axial specimens with and without flattening and flattened circumferential specimens. Three steels were evaluated -- two thicknesses of aluminum killed drawing quality (AKDQ) steel and one thickness of high strength low alloy (HSLA) steel. Mechanical property data were obtained from the flat stock, conventional production tubes and quasi tubes. Quasi tubes were produced from the flat stock on a 3-roll bender, but the quasi tube was not welded or sized.

The existing vehicle designs exhibit a high level of coupling. For instance the coupling in the suspension and steering systems manifests itself through the change in wheel alignment parameters (WAP) due to suspension travel. This change in the WAP causes directional instability and tire-wear. The approach of the industry to solve this problem has been twofold. The first approach has been optimization of suspension link lengths to reduce the change in WAP to zero. Since this is not possible with the existing architecture, the solution used is the optimization of the spring stiffness K to get a compromise solution for comfort (which requires significant suspension travel and hence a soft spring) and directional stability (which demands least possible change in wheel alignment parameters and hence a stiff spring).

A revolutionary interplanetary rapid transit concept for transporting scientists and explorers between Earth and Mars is presented by Global Aerospace Corporation under funding from the NASA Institute for Advanced Concepts (NIAC) with support from the Colorado School of Mines, and Science Applications International Corporation. We describe an architecture that uses highly autonomous spaceships, dubbed Astrotels; small Taxis for trips between Astrotels and planetary Spaceports; Shuttles that transport crews to and from orbital space stations and planetary surfaces; and low-thrust cargo freighters. In addition we discuss the production of rocket fuels using extraterrestrial materials; aerocapture to slow Taxis at the planets; and finally describe a number of trade studies and their life-cycle cost results.