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The results of this study make clear the characteristics of electrode performance deterioration in terms of cell voltage reduction in polymer electrolyte fuel cells (PEFCs) caused by the presence of certain quantities of carbon monoxide and/or hydrogen sulfide in the anode feed. AC impedance measurements of the anode and cathode potentials revealed that both electrode potentials showed deterioration in the presence of each type of poisoning gas. This suggests that the poisoning gases permeated the electrolyte membrane and transferred to the cathode, causing performance deterioration by poisoning the catalyst. In addition, AC impedance measurements indicated that the presence of hydrogen sulfide in the anode feed increased the membrane impedance, thus implying some poisoning effect even on the electrolyte membrane.

Hydrogen is expected to be a clean and energy-efficient fuel for the next generation of power sources because it is CO2-free and has excellent combustion characteristics. In this study, an attempt was made to apply Homogeneous Charge Compression Ignition (HCCI) combustion to hydrogen with the aim of achieving low oxides of nitrogen (NOx) emissions and high fuel economy with the assistance of the di-methyl-ether (DME) fuel supplement. As a result, HCCI combustion of hydrogen mixed with 25 vol% DME achieved approximately a 30% improvement in fuel economy compared with HCCI of pure DME and spark-ignited lean-burn combustion of pure hydrogen under almost zero NOx emissions and low hydrocarbon (HC) emissions. This is attributed to control of the combustion process to attain the optimum onset of combustion and to a reduction of cooling losses.

Hybrid electric vehicle with internal combustion engine fueled with hydrogen can be a competitor to the fuel cell electric vehicle that is thought to be the ultimately clean and efficient vehicle. The objective in this research is to pursue higher thermal efficiency and lower exhaust emissions in a hydrogen-fueled engine for the series type hybrid vehicle system. Influences of compression ratio, surface / volume ratio of combustion chamber, and boost pressure on thermal efficiency and exhaust emissions were analyzed. Results showed that reduction of the surface / volume ratio by increased cylinder bore was effective to improve indicated thermal efficiency, and it was possible to achieve 44% of indicated thermal efficiency. However, brake thermal efficiency resulted in 35.5%. It is considered that an improved mechanical efficiency by an optimized engine design could increase the brake thermal efficiency largely.

A development project for a hydrogen internal combustion engine (ICE) system for trucks supporting Japanese freightage has been promoted as a candidate for use in future vehicles that meet ultra-low emission and anti-global warming targets. This project aims to develop a hydrogen ICE truck that can handle the same freight as existing trucks. The core development technologies for this project are a direct-injection (DI) hydrogen ICE system and a liquid hydrogen tank system which has a liquid hydrogen pump built-in. In the first phase of the project, efforts were made to develop the DI hydrogen ICE system. Over the past three years, the following results have been obtained: A high-pressure hydrogen gas direct injector developed for this project was applied to a single-cylinder hydrogen ICE and the indicated mean effective pressure (IMEP) corresponding to a power output of 147 kW in a 6-cylinder hydrogen ICE was confirmed.