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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

Low combustion efficiency and high hydrocarbon emissions at low loads are key issues of natural gas and diesel (NG-diesel) dual fuel engines. For better engine performance, two diesel-spray-orientated (DSO) bowls were developed based on the existing diesel injector of a heavy-duty diesel engine with the purpose of placing more combustible natural gas/air mixture around the diesel spray jets. A protrusion-ring was designed at the rim of the piston bowl to enhance the in-cylinder flame propagation. Numerical simulations were conducted for a whole engine cycle at engine speed of 1200 r/min and indicated mean effective pressure (IMEP) of 0.6 MPa. Extended coherent flame model 3 zones (ECFM-3Z) combustion model with built-in soot emissions model was employed. Simulation results of the original piston bowl agreed well with the experimental data, including in-cylinder pressure and heat released rate (HRR), as well as soot and methane emissions.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

CAI combustion has the potential to be the most clean combustion technology in internal combustion engines and is being intensively researched. Following the previous research on CAI combustion of gasoline fuel, systematic investigation is being carried out on the application of bio-fuels in CAI combustion. As part of an on-going research project, CAI combustion of methanol and ethanol was studied on a single-cylinder direct gasoline engine with an air-assisted injector. The CAI combustion was achieved by trapping part of burnt gas within the cylinder through using short-duration camshafts and early closure of the exhaust valves. During the experiment the engine speed was varied from 1200rpm to 2100rpm and the air/fuel ratio was altered from the stoichiometry to the misfire limit. Their combustion characteristics were obtained by analysing cylinder pressure trace.

The effects of load, speed, exhaust gas recirculation (EGR) level and hydrogen addition level on the emissions from a diesel engine have been investigated. The experiments were performed on a 2.0 litre, 4 cylinder, direct injection engine with a high pressure common-rail injection system. Injection timing was varied between 14° BTDC and TDC and injection pressures were varied from 800 bar to 1400 bar to find a suitable base point. EGR levels were then varied from 0% to 40%. Hydrogen induction was varied between 0 and 6% vol. of the inlet charge. In the case of using hydrogen and EGR, the hydrogen replaced air. The load was varied from 0 to 5.4 bar BMEP at two engine speeds, 1500 rpm and 2500 rpm. For this investigation the carbon monoxide (CO), total unburnt hydrocarbons (THC), nitrogen oxides (NOx) and the filter smoke number (FSN) were all measured.

Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

The transportation sector in the United States is a major contributor to global energy consumption and carbon dioxide emission. To assess the future potentials of different technologies in addressing these two issues, we used a family of simulation programs to predict fuel consumption for passenger cars in 2020. The selected technology combinations that have good market potential and could be in mass production include: advanced gasoline and diesel internal combustion engine vehicles with automatically-shifting clutched transmissions, gasoline, diesel, and compressed natural gas hybrid electric vehicles with continuously variable transmissions, direct hydrogen, gasoline and methanol reformer fuel cell hybrid electric vehicles with direct ratio drive, and battery electric vehicle with direct ratio drive.

The use of diesel particulate filter [DPF] has become a standard in modern diesel engine after treatment technology. However pressure drop develops across the filter as PM accumulates and this requires quick periodic burn-out without incurring thermal runaway temperatures that could compromise DPF integrity during operation. Adequate understanding of soot oxidation is needed for design and manufacture of efficient filter traps for the engine system. In this study, we have examined the impact of blending biodiesel on oxidation of PM generated from a high speed direct injection [HSDI] diesel engine, which was operated with 20% [B20] and 40% [B40] blends of two biodiesel fuels. The PM samples were collected from the engine exhaust using a Pall Tissuquartz filter, the oxidation characteristics of the samples were carried out using thermogravimetric analyzer [TGA]. The biodiesel oxidation data obtained from pure petrodiesel was compared against the fuel blends.

Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.

Controlled Auto Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), is one of the most promising combustion technologies to reduce the fuel consumption and NOx emissions. Currently, CAI combustion is constrained at part load operation conditions because of misfire at low load and knocking combustion at high load, and the lack of effective means to control the combustion process. Extending its operating range including high load boundary towards full load and low load boundary towards idle in order to allow the CAI engine to meet the demand of whole vehicle driving cycles, has become one of the key issues facing the industrialisation of CAI/HCCI technology. Furthermore, this combustion mode should be compatible with different fuels, and can switch back to conventional spark ignition operation when necessary. In this paper, the CAI operation is demonstrated on a 2-stroke gasoline direct injection (GDI) engine equipped with a poppet valve train.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

In this paper, an experimental study was performed to investigate characteristics of flame propagation and knocking combustion of hydrous (10% water content) and anhydrous ethanol at different air/fuel ratios in comparison to RON95 gasoline. Experiments were conducted in a full bore overhead optical access single cylinder port-fuel injection spark-ignition engine. High speed images of total chemiluminescence and OH* emission was recorded together with the in-cylinder pressure, from which the heat release data were derived. The results show that under the stoichiometric condition anhydrous ethanol and wet ethanol with 10% water (E90W10) generated higher IMEP with at an ignition timing slightly retarded from MBT than the gasoline fuel for a fixed throttle position. Under rich and stoichiometric conditions, the knock limited spark timing occurred at 35 CA BTDC whereas both ethanol and E90W10 were free from knocking combustion at the same operating condition.

The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).

The combustion behavior in a modem 4-valve engine using a broad range of methanol/gasoline fuel mixtures was studied. The initial flame development was examined by using a spark plug fiber optics probe. Approximately, the kernel expansion speed, Sg, is relatively unchanged from M0 to M40; jumps by ∼30% from M40 to M60; and then remains roughly constant from M60 to M100. Statistics of the IMEP indicate that at a lean idle condition the combustion rate and robustness correlate with Sg: a higher value of Sg gives better combustion. Thus M60-M100 fuels give better idle combustion behavior than the M0-M40 fuels.