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Technical Paper

Effect of Catalyst Systems on Characteristics of Exhaust Hydrocarbon Species

1993-10-01
932718
The California Low-Emission Vehicle (LEV) standards mandate a reduction in non-methane organic gases (NMOG). With the aim of analyzing NMOG emissions, a comparison was made of the hydrocarbon species found in the exhaust gas when different types of catalyst systems and fuel specifications were used. NMOG emissions are usually measured by removing methane from the total hydrocarbon (THC) emissions and adding aldehyde and ketone emissions. The NMOG level found in this way is thus influenced by the rate of methane in THC emissions. Another important factor in the LEV standards is specific reactivity (SR), indicating the formation potential of ozone, which is one cause of photochemical smog. Specific reactivity is expressed by the amount of ozone generated per unit weight of NMOG emissions, and is affected by the respective proportion of hydrocarbon species in the total NMOG emissions.
Technical Paper

A Study of a Gasoline-Fueled Near-Zero-Emission Vehicle Using an Improved Emission Measurement System

1998-10-19
982555
This paper concerns research on an emission control system aimed at reducing emission levels to well below the ULEV standards. As emission levels are further reduced in the coming years, it is projected that measurement error will increase substantially. Therefore, an analysis was made of the conventional measurement system, which revealed the following major problems. 1. The conventional analyzer, having a minimum full-scale THC range of 10 ppmC, cannot measure lower concentration emissions with high accuracy. 2. Hydrocarbons are produced in various components of the measurement system, increasing measurement error. 3. Even if an analyzer with a minimum full-scale THC range of 1 ppmC is used in an effort to measure low concentrations, the 1 ppmC measurement range cannot be applied when the dilution air contains a high THC concentration. This makes it impossible to obtain highly accurate measurements. 4.
Technical Paper

Development of New Technologies Targeting Zero Emissions for Gasoline Engines

2000-03-06
2000-01-0890
This paper describes new technologies for achieving exhaust emission levels much below the SULEV standards in California, which are the most stringent among the currently proposed regulations in the world. Catalyst light-off time, for example, has been significantly reduced through the adoption of a catalyst substrate with an ultra-thin wall thickness of 2 mil and a catalyst coating specifically designed for quicker light-off. A highly-efficient HC trap system has been realized by combining a two-stage HC trap design with an improved HC trap catalyst. The cold-start HC emission level has been greatly reduced by an electronically actuated swirl control valve with a high-speed starter. Further, an improved Air Fuel Ratio (AFR) control method has achieved much higher catalyst HC and NOx conversion efficiency.
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