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To improve the fuel economy via high EGR, combustion stability is enhanced through the addition of hydrogen, with its high flame-speed in air-fuel mixture. So, in order to realize on-board hydrogen production we developed a fuel reformer which produces hydrogen rich gas. One of the main issues of the reformer engine is the effects of reformate gas components on combustion performance. To clarify the effect of reformate gas contents on combustion stability, chemical kinetic simulations and single-cylinder engine test, in which hydrogen, CO, methane and simulated gas were added to intake air, were executed. And it is confirmed that hydrogen additive rate is dominant on high EGR combustion. The other issue to realize the fuel reformer was the catalyst deterioration. Catalyst reforming and exposure test were carried out to understand the influence of actual exhaust gas on the catalyst performance.