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Gas chromatographic methods for analyzing hydrocarbon species in vehicle exhaust emissions were compared in terms of their collection efficiency, detection limit, repeatability and number of species detected using cylinder gas and tailpipe emission samples. The main methods compared were a Tenax cold trap injection (TCT) method (C5-C12 HCs) and a cold trap injection (CTI) method (C2-C4 HCs; C5-C12 HCs). Our own direct (DIR) method was used to confirm the collection efficiencies. Both methods yielded good results, but the CTI method showed low collection efficiency for some C2-C4 HCs. Measurement of individual species is needed with this method for accurate analysis of tailpipe emissions. Both the CTI method and the TCT method combined with the DIR method for determining C2-C4 HCs yielded nearly the same ozone specific reactivity values for the NMHC species analyzed.

In 1994, the California Air Resources Board implemented low-emission vehicle (LEV) standards with the aim of improving urban air quality. One feature of the LEV standards is the increasingly tighter regulation of non-methane organic gases (NMOG), taking into account ozone formation, in addition to the existing control of non-methane hydrocarbons (NMHC). Hydrocarbons and other organic gases emitted by S.I. engines have been identified as a cause of atmospheric ozone formation. Since the reactivity of each chemical species in exhaust emissions differs, the effect on ozone formation varies depending on the composition of the exhaust gas components. This study examined the effect of different engine types, fuel atomization conditions, turbulence and emission control systems on emission species and specific reactivity. This was done using gas chromatographs and a high-performance liquid chromatograph to analyze exhaust emission species that affect ozone formation.