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In 2006, Nissan began limited leasing of the X-TRAIL FCV equipped with their in-house developed Fuel Cell (FC) stack. Since then, the FC stack has been improved in cost, size, durability and cold start-up capability with the aim of promoting full-scale commercialization of FCVs. However, reduction of cost and size has remained a significant challenge because limited mass transport through the membrane electrode assembly (MEA) has made it difficult to increase the rated current density of the FC. Furthermore, it has been difficult to reduce the variety of FC stack components due to the complex stack configuration. In this study, improvements have been achieved mainly by adopting an advanced MEA to overcome these difficulties. First, the adoption of a new MEA and separators has improved mass transport through the MEA for increased rated current density. Second, an integrated molded frame (IMF) has been adopted as the MEA support.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

To improve the fuel economy via high EGR, combustion stability is enhanced through the addition of hydrogen, with its high flame-speed in air-fuel mixture. So, in order to realize on-board hydrogen production we developed a fuel reformer which produces hydrogen rich gas. One of the main issues of the reformer engine is the effects of reformate gas components on combustion performance. To clarify the effect of reformate gas contents on combustion stability, chemical kinetic simulations and single-cylinder engine test, in which hydrogen, CO, methane and simulated gas were added to intake air, were executed. And it is confirmed that hydrogen additive rate is dominant on high EGR combustion. The other issue to realize the fuel reformer was the catalyst deterioration. Catalyst reforming and exposure test were carried out to understand the influence of actual exhaust gas on the catalyst performance.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

This paper describes a newly developed steel composition and surface modification methods for improving the rolling contact fatigue strength of parts used in transmission systems, especially continuously variable transmissions (CVTs) to increase their torque capacity. The mechanisms of two types of typical rolling contact fatigue phenomenon in case hardening steel were examined with the aim of improving rolling contact fatigue strength. One concerned white etching constituents (WEC) and the other one concerned peculiar microstructural changes caused by hydrogen originating from decomposition of the lubrication oil as a result of repeated rolling contact stress cycles. The rolling contact fatigue strength limit due to WEC has been improved markedly by dispersing fine M23C6 alloy carbides in the martensite matrix at the subsurface layer of parts.

The FFVs under study operates on either M85 or M0 or any mixture of the two. Nissan has been actively conducting reseach and development on flexible fuel vehicles (FFVs) to explore the possibilities for long-range energy conservation and air quality improvement. The engine converted for use in these FFVs is a 1.6 liter, four-cylinder in-line powerplant, with dual overhead camshafts and four valves per cylinder. It employs the Nissan Variable valve timing Control System (NVCS). The fuel sensor for measuring the methanol concentration in the fuel has been improved both in terms of accuracy and durability. This paper describes the engine performance and exhaust emission levels (formaldehydes unburned methanol and HC emissions) obtained with both M85 and M0.

With the aim of improving the air quality in large cities, the California Air Resources Board (CARB) has stipulated that non-methane organic gas (NMOG) composed of carbon numbers from C1 to C12 must be reduced for vehicle categories designated as Transitional Low Emission Vehicles (TLEVs), Low Emission Vehicles (LEVs), Ultra low Emission Vehicles (ULEVs), and Zero Emission Vehicles (ZEVs). Although considerable research work has been done on this issue to date, the entire picture is still not clear. Studies done by the authors have been aimed at providing a better understanding of the potential for reducing automotive tailpipe emissions by using several clean fuel candidates. The major questions of concern are the extent to which emissions of certain species can actually be reduced and what fuel can provide the best performance under a reduced NMOG condition.

The California Low-Emission Vehicle (LEV) standards mandate a reduction in non-methane organic gases (NMOG). With the aim of analyzing NMOG emissions, a comparison was made of the hydrocarbon species found in the exhaust gas when different types of catalyst systems and fuel specifications were used. NMOG emissions are usually measured by removing methane from the total hydrocarbon (THC) emissions and adding aldehyde and ketone emissions. The NMOG level found in this way is thus influenced by the rate of methane in THC emissions. Another important factor in the LEV standards is specific reactivity (SR), indicating the formation potential of ozone, which is one cause of photochemical smog. Specific reactivity is expressed by the amount of ozone generated per unit weight of NMOG emissions, and is affected by the respective proportion of hydrocarbon species in the total NMOG emissions.

This paper presents the results of several studies conducted on a natural gas vehicle. In one study of engine-out emissions performance, the exhaust emissions of the CNG engine were lower than those of the base gasoline engine. In another study of the conversion characteristics of three-way catalysts, it was found that the conversion efficiency of total hydrocarbons (THCs) was much lower in the lean-mixture region for the NGV. The reduced efficiency was traced to lower conversion and poor reactivity of low-end hydrocarbons and to a higher concentration of H2O.

In 1994, the California Air Resources Board implemented low-emission vehicle (LEV) standards with the aim of improving urban air quality. One feature of the LEV standards is the increasingly tighter regulation of non-methane organic gases (NMOG), taking into account ozone formation, in addition to the existing control of non-methane hydrocarbons (NMHC). Hydrocarbons and other organic gases emitted by S.I. engines have been identified as a cause of atmospheric ozone formation. Since the reactivity of each chemical species in exhaust emissions differs, the effect on ozone formation varies depending on the composition of the exhaust gas components. This study examined the effect of different engine types, fuel atomization conditions, turbulence and emission control systems on emission species and specific reactivity. This was done using gas chromatographs and a high-performance liquid chromatograph to analyze exhaust emission species that affect ozone formation.

To reduce engine exhaust emissions, we have had to deal with this global environmental problem from the fuel side by introducing oxygenated fuels, reducing the RVP and using low aromatics. But when we change the fuel components and distillation, we must take note about how these affect the engine driveability. We have used T50, T90, RVP and so on as the fuel index up to the present. It is possible to characterize the fuel from one aspect, but these indexes don't always represent the real feature of the fuel. In this paper we propose a New Driveability Index (here in after referred to as NDI) that is more realistic and accurate than the other fuel indexes. We used a 1600cc DOHC L4 MPI type engine. We used Model Gasolines and Market Gasolines, see Appendix(1), (2) and (3), and tested them according to the Excess Air Ratio Response Test Method (here in after referred to as λ-R Test) that was suggested in SAE paper #930375, and we calculated the NDI statistically.

The effect of the introduction of low-emission vehicles on potential air quality improvement in the Los Angeles area was predicted using a three-dimensional airshed simulation model. The simulations were based on ozone concentration estimates made on the basis of data released by the California Air Resources Board concerning projected quantities of emissions from various sources in 2010. Analyses were made of three scenarios. One assumed that LEV, ULEV and ZEV regulations were enforced as planned, a second assumed that these planned regulations were modified; and a third assumed that emission levels from various sources were reduced in line with the goals of the Air Quality Management Plan formulated by the South Coast Air Quality Management District.

Nissan has recently developed and begun driving tests of a fuel cell vehicle equipped with a methanol reformer that produces hydrogen through the use of a catalyst to induce chemical reactions between methanol and water. With this onboard fuel cell system, only methanol in the form of a liquid fuel needs to be supplied, making the system highly practical as an automotive powertrain for near-future application. The Nissan Fuel Cell Vehicle (FCV) adopts a high-efficiency neodymium magnet synchronous traction motor combined with lithium-ion batteries that enable the vehicle to achieve optimum electric power by switching between a fuel cell-powered driving mode and a battery-powered driving mode. This presentation will cover the current status of the FCV development program and driving test results.

A new variable compression turbo (VC-Turbo) engine, which has a multi-link system for controlling the compression ratio from 8:1 to 14:1, requires high axial force for fastening the multi-links because of high input loads and the downsizing requirement. Therefore, it was necessary to develop a 1.6-GPa tensile strength bolt with plastic region tightening. One of the biggest technical concerns is delayed fracture. In this study, quenched and tempered alloy steels were chosen for the 1.6-GPa tensile strength bolt.

On-board hydrogen generation technology using a fuel reforming catalyst is an effective way to improve the fuel efficiency of automotive internal combustion engines. The main issue to be addressed in developing such a catalyst is to suppress catalyst deterioration caused by carbon deposition on the catalyst surface due to sulfur adsorption. Enhancing the hydrocarbon and water activation capabilities of the catalyst is important in improving catalyst durability. It was found that the use of a rare earth element is effective in improving the water activation capability of the catalyst. Controlling the hydrocarbon activation capability of the catalyst for a good balance with water activation was also found to be effective in improving catalyst durability.

In 2006, Nissan began limited leasing of the X-TRAIL FCV equipped with their in-house developed Fuel Cell (FC) stack. Since then, the FC stack has been improved in durability, cold start-up capability, cost and size with the aim of promoting full-scale commercialization of FCVs. However, reduction of cost and size has remained a significant challenge because limited mass transport through the membrane electrode assembly (MEA) has made it difficult to increase the rated current density of the FC. Furthermore, it has been difficult to reduce the variety of FC stack components due to the complex stack configuration. In this study, improvements have been achieved mainly by adopting an advanced MEA to overcome these difficulties. First, the adoption of a new MEA and separators has improved mass transport through the MEA for increased rated current density. Second, an integrated molded frame (IMF) has been adopted as the MEA support.