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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of charge motion and laminar flame speeds on combustion and exhaust temperature have been studied by using an air jet in the intake flow to produce an adjustable swirl or tumble motion, and by replacing the nitrogen in the intake air by argon or CO₂, thereby increasing or decreasing the laminar flame speed. The objective is to examine the "Late Robust Combustion" concept: whether there are opportunities for producing a high exhaust temperature using retarded combustion to facilitate catalyst warm-up, while at the same time, keeping an acceptable cycle-to-cycle torque variation as measured by the coefficient of variation (COV) of the net indicated mean effective pressure (NIMEP). The operating condition of interest is at the fast idle period of a cold start with engine speed at 1400 RPM and NIMEP at 2.6 bar. A fast burn could be produced by appropriate charge motion. The combustion phasing is primarily a function of the spark timing.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

In recent years, catalyst systems such as a lean NOx trap (LNT) catalyst system and a urea selective catalytic reduction (SCR) system have been developed to obtain cleaner diesel emissions. At Nissan, we developed an emission control system for meeting Tier 2 Bin 5 requirements in 2003. On the basis of that technology, a new HC-NOx trap catalyst system has now been developed that complies with the SULEV standards without increasing the catalyst volume and precious metal loading. Compliance with the SULEV standards requires a further reduction of HC (NMHC) emissions by 84% and NOx by 60% compared with the emission performance Tier 2 Bin 5 compliant catalyst system. Consequently high conversion performance for both HCs and NOx is needed. An investigation of HC emission behavior under the FTP75 mode showed that a reduction of cold-phase HCs was critical for meeting the standard. Large quantities of HCs above C4 are emitted in the cold state.

In 2006, Nissan began limited leasing of the X-TRAIL FCV equipped with their in-house developed Fuel Cell (FC) stack. Since then, the FC stack has been improved in cost, size, durability and cold start-up capability with the aim of promoting full-scale commercialization of FCVs. However, reduction of cost and size has remained a significant challenge because limited mass transport through the membrane electrode assembly (MEA) has made it difficult to increase the rated current density of the FC. Furthermore, it has been difficult to reduce the variety of FC stack components due to the complex stack configuration. In this study, improvements have been achieved mainly by adopting an advanced MEA to overcome these difficulties. First, the adoption of a new MEA and separators has improved mass transport through the MEA for increased rated current density. Second, an integrated molded frame (IMF) has been adopted as the MEA support.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

To improve the fuel economy via high EGR, combustion stability is enhanced through the addition of hydrogen, with its high flame-speed in air-fuel mixture. So, in order to realize on-board hydrogen production we developed a fuel reformer which produces hydrogen rich gas. One of the main issues of the reformer engine is the effects of reformate gas components on combustion performance. To clarify the effect of reformate gas contents on combustion stability, chemical kinetic simulations and single-cylinder engine test, in which hydrogen, CO, methane and simulated gas were added to intake air, were executed. And it is confirmed that hydrogen additive rate is dominant on high EGR combustion. The other issue to realize the fuel reformer was the catalyst deterioration. Catalyst reforming and exposure test were carried out to understand the influence of actual exhaust gas on the catalyst performance.

This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.

Ceramic honeycombs have been used as automotive catalyst supports in US, Japan, Europe and other highly urbanized countries. Now, engine output is a great concern for automanufacturers, and reduction of the wall thickness of honeycomb substrates became indespensable for maintenance of gas flow restriction to a certain low level. To reduce wall thickness, material should be strong to maintain canning strength of substrates. Mechanical strength was improved with high density cordierite. However, isostatic strength of whole substrates was still insufficient with reduced thin walls for canning in spite of the material's high mecanical strength. Discussion is carried out on further possibility of improving canning performance of thin wall substrates as well as flow restriction, and warm up characteristics.

A novel engine management strategy for achieving fast catalyst light-off without the use of an exhaust air pump in a port-fuel-injected, spark ignition engine was developed. A conventional 4-cylinder engine was operated with three cylinders running rich and the fourth one as an air pump to supply air to the exhaust manifold. Under steady-state cold coolant conditions, this strategy achieved near total oxidation of CO and HC with sufficiently retarded spark timing, resulting in a 400% increase in feedgas enthalpy flow and a 90% reduction in feedgas HC emissions compared to conventional operation. The strategy was also evaluated for crank starts. Using the existing engine hardware, implementing the strategy resulted in a reduction in catalyst light-off time from 28.0 seconds under conventional operation to 9.1 seconds.

A new multidimensional calculation method has been developed to simulate the warm-up characteristics of close-coupled catalytic converter systems. First, a one-dimensional gas exchange simulation and a three-dimensional exhaust gas flow calculation are combined to simulate the pulsation gas flow caused by the gas exchange process. The gas flow calculation and a heat transfer calculation are then combined to simulate heat transfer in the exhaust manifold and the catalyst honeycomb under pulsation flow. The predicted warm-up characteristics of the systems examined agreed well with the experimental data. In this simulation, CPU time was reduced greatly through the use of new calculation methods. Finally, the warm-up process of close-coupled catalysts is analyzed in detail with this simulation method. The design requirements for improving warm-up characteristics have been made clear.

The thinnest wall thickness of automotive catalyst substrates has previously been 30 μm for metal substrates and 50 μm for ceramic substrates. This paper describes a newly developed catalyst substrate that is the world's first to achieve 20-μm-thick cell walls. This catalyst substrate features low thermal capacity and low pressure loss. Generally, a thinner cell wall decreases substrate strength and heat shock resistance. However, the development of a “diffused junction method”, replacing the previous “wax bonding method”, and a small waved foil has overcome these problems. This diffused junction method made it possible to strengthen the contact points between the inner waved foil and the rolled foil compared with previous substrates. It was also found that heat shock resistance at high temperature can be much improved by applying a slight wave to the foil instead of using a plane foil.

This paper describes a newly developed HC-adsorption three-way catalyst and adsorption system that reduce cold-start HC emissions with high efficiency. This system is the first of its kind anywhere in the world to be implemented on production vehicles. An overview is given of the various improvements made to achieve higher cold-start HC conversion efficiency. Improvement of conversion performance was accomplished by (1) increasing the thermal stability of the HC adsorbent, (2) improving desorbed HC conversion efficiency and durability and (3) optimizing the geometric surface area (GSA) of the substrate. Concretely, the thermal stability of the adsorbent was improved by enhancing the high-temperature durability of zeolite. Improvement of desorbed HC conversion efficiency was accomplished by improving the OSC material so as to match the temperature rise characteristic and usage temperature of the catalyst.

HC emission standards will be tightened during the 1990's in the US. A key issue in reducing HC emission is improving the warm-up characteristics of catalysts during the cold start of engines. For this purpose, studies are under way on reduction of heat mass of ceramic substrates. Reduction of cell walls in substrates to thickness smaller than the current thickness of 12mil or 6mil has resulted in reduced heat mass, and also reduced flow restriction of substrates. The warm-up characteristics of low bulk density catalysts are better than those of high bulk density, i.e., the warm-up characteristics of thinner wall or lower cell density catalysts are better than those of thicker wall or higher cell density catalysts. A relationship between geometric surface area and warm-up characteristics is observed.

In the Japan Clean Air Program II (JCAP II) Diesel WG, effects of fuel properties on the performance of two types of diesel NOx emission aftertreatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined. For a Urea-SCR system, the NOx emission reduction performance with and without an oxidation catalyst installed in front of the SCR catalyst at low exhaust gas temperature operation was compared. For an NSR catalyst system, the effect of fuel sulfur on both emissions and fuel economy during 50,000 km driving was examined. Furthermore, effects of other fuel properties such as distillation on exhaust emissions were investigated. The results show that sulfur is the influential factor for both devices. Namely, high NOx emission reduction performance of the Urea-SCR system with the oxidation catalyst at low exhaust gas temperature operation is influenced by sulfur.

Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.

The California Low-Emission Vehicle (LEV) standards mandate a reduction in non-methane organic gases (NMOG). With the aim of analyzing NMOG emissions, a comparison was made of the hydrocarbon species found in the exhaust gas when different types of catalyst systems and fuel specifications were used. NMOG emissions are usually measured by removing methane from the total hydrocarbon (THC) emissions and adding aldehyde and ketone emissions. The NMOG level found in this way is thus influenced by the rate of methane in THC emissions. Another important factor in the LEV standards is specific reactivity (SR), indicating the formation potential of ozone, which is one cause of photochemical smog. Specific reactivity is expressed by the amount of ozone generated per unit weight of NMOG emissions, and is affected by the respective proportion of hydrocarbon species in the total NMOG emissions.

The thermal environment in the automotive engine compartment is expected to become increasingly severe in the years ahead owing to the installation of a large-size manifold catalyst to reduce exhaust emissions, among other factors. This will make it even more important to analyze the engine compartment layout in terms of heat flow considerations at the design conceptualization stage of a new vehicle. In this research, a flow analysis program called DRAG4D was applied to find the flow velocity distribution and ambient air temperature distribution in the engine compartment during driving, idling and after the engine was turned off. This original program developed at Nissan takes into account the effects of the energy balance and buoyancy, and provides a practical level of prediction accuracy. The time required to create an analytical model and perform the computations has been shortened by using an automatic grid generation function, based on a solid model, and experimental equations.

Hydrocarbons and other organic materials emitted from S.I. engines cause ozone to form in the air. Since each species of organic materials has a different reactivity, exhaust components affect ozone formation in different ways. The effects of exhaust emission control devices and fuel properties on speciated emissions and ozone formation were examined by measuring speciated emissions with a gas chromatograph and a high-performance liquid chromatograph. In the case of gasoline fuels, catalyst systems with higher conversion rates such as close-coupled catalyst systems are effective in reducing alkenes and aromatics which show high reactivities to ozone formation. With deterioration of the catalyst, non-methane organic gas (NMOG) emission increases, but the specific reactivity of ozone formation tends to decrease because of the increase in alkane contents having low MIR values.