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Generally, cobalt-contained sintered materials have mainly been applied for exhaust valve seat inserts (VSI). However, there is a trend to restrict the use of cobalt as well as lead environmental law, and cobalt is expensive. To solve these problems, a new exhaust VSI on the assumption of being cobalt and lead free, applicable for conventional engines, having good machinability, and with a reduced cost was developed. The new exhaust VSI is a material dispersed with two types of hard particles, Fe-Cr-C and Fe-Mo-Si, in the matrix of an Fe-3.5mass%Mo at the ratio of 15 mass % and 10 mass % respectively.

The key-points in the diffusion bonding technique of green compacts during sintering, are the material compositions, which should be chosen according to their dimensional change during sintering, and the fitting clearance, which should be maintained in the range of press fit. Applying this technique, we have developed sinter-diffusion bonded idler sprockets for automotive engines by comfirming the bonding strength and torsional fatigue strength. And we also have developed a nondestructive analysis method for assuring the joint strength of idler sprockets in the mass production.

Internal combustion engines experience severe valve train wear and the reduction of valve seat and seat insert wear has been a long-standing issue. In this work, worn valve seats and inserts were examined to obtain a fundamental understanding of the wear mechanisms and the results were applied in developing new valve seat insert materials. The new exhaust valve insert material for gasoline engines is a sintered alloy steel containing Co-base hard particles, with lead infiltrated only for inserts used in unleaded gasoline engines. The new intake valve insert material for gasoline engines is a high-Mo sintered steel, obtained through transient liquid phase sintering and with copper precipitated uniformly. This material can be used for both leaded and unleaded gasoline engines. Valve and valve seat insert wear has long been an issue of concern to engine designers and manufacturers.