Effect of Engine Design/Control Parameters and Emission Control Systems on Specific Reactivity of S.I. Engine Exhaust Gases
In 1994, the California Air Resources Board implemented low-emission vehicle (LEV) standards with the aim of improving urban air quality. One feature of the LEV standards is the increasingly tighter regulation of non-methane organic gases (NMOG), taking into account ozone formation, in addition to the existing control of non-methane hydrocarbons (NMHC). Hydrocarbons and other organic gases emitted by S.I. engines have been identified as a cause of atmospheric ozone formation. Since the reactivity of each chemical species in exhaust emissions differs, the effect on ozone formation varies depending on the composition of the exhaust gas components. This study examined the effect of different engine types, fuel atomization conditions, turbulence and emission control systems on emission species and specific reactivity. This was done using gas chromatographs and a high-performance liquid chromatograph to analyze exhaust emission species that affect ozone formation.