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Journal Article

Ash Effects on Diesel Particulate Filter Pressure Drop Sensitivity to Soot and Implications for Regeneration Frequency and DPF Control

2010-04-12
2010-01-0811
Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.
Journal Article

Characteristics and Effects of Lubricant Additive Chemistry on Ash Properties Impacting Diesel Particulate Filter Service Life

2010-04-12
2010-01-1213
Ash accumulation in diesel particulate filters, mostly from essential lubricant additives, decreases the filter's soot storage capacity, adversely affects fuel economy, and negatively impacts the filter's service life. While the adverse effects of ash accumulation on DPF performance are well known, the underlying mechanisms controlling these effects are not. To address these issues, results of detailed measurements with specially formulated lubricants, correlating ash properties to individual lubricant additives and their effects on DPF pressure drop, are presented. Investigations using the specially-formulated lubricants showed ash consisting primarily of calcium sulfates to exhibit significantly increased flow resistance as opposed to ash primarily composed of zinc phosphates. Furthermore, ash accumulated along the filer walls was found to be packed approximately 25% denser than ash accumulated in the channel end-plugs.
Technical Paper

A Numerical Model for Piston Pin Lubrication in Internal Combustion Engines

2020-09-15
2020-01-2228
As the piston pin works under significant mechanical load, it is susceptible to wear, seizure, and structural failure, especially in heavy duty internal combustion engines. It has been found that the friction loss associated with the pin is comparable to that of the piston, and can be reduced when the interface geometry is properly modified. However, the mechanism that leads to such friction reduction, as well as the approaches towards further improvement, remain unknown. This work develops a piston pin lubrication model capable of simulating the interaction between the pin, the piston, and the connecting rod. The model integrates dynamics, solid contact, oil transport, and lubrication theory, and applies an efficient numerical scheme with second order accuracy to solve the highly stiff equations. As a first approach, the current model assumes every component to be rigid.
Technical Paper

Development of JASO GLV-1 0W-8 Low Viscosity Engine Oil for Improving Fuel Efficiency considering Oil Consumption and Engine Wear Performance

2020-04-14
2020-01-1423
Engine oil with viscosity lower than 0W-16 has been needed for improving fuel efficiency in the Japanese market. However, lower viscosity oil generally has negative aspects with regard to oil consumption and anti-wear performance. The technical challenges are to reduce viscosity while keeping anti-wear performance and volatility level the same as 0W-20 oil. They have been solved in developing a new engine oil by focusing on the molybdenum dithiocarbamate friction modifier and base oil properties. This paper describes the new oil that supports good fuel efficiency while reliably maintaining other necessary performance attributes.
Technical Paper

The Development of JASO GLV-1 Next Generation Low Viscosity Automotive Gasoline Engine Oils Specification

2020-04-14
2020-01-1426
It is well understood that using lower viscosity engine oils can greatly improve fuel economy [1, 2, 3, 4]. However, it has been impossible to evaluate ultra-low viscosity engine oils (SAE 0W-12 and below) utilizing existing fuel economy test methods. As such, there is no specification for ultra-low viscosity gasoline engine oils [5]. We therefore developed firing and motored fuel economy test methods for ultra-low viscosity oils using engines from Japanese automakers [6, 7, 8]. This was done under the auspices of the JASO Next Generation Engine Oil Task Force (“TF” below), which consists mainly of Japanese automakers and entities working in the petroleum industry. Moreover, the TF used these test methods to develop the JASO GLV-1 specification for next-generation ultra-low viscosity automotive gasoline engine oils such as SAE 0W-8 and 0W-12. In developing the JASO GLV-1 specification, Japanese fuel economy tests and the ILSAC engine tests for evaluating engine reliability were used.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

Sensitivity Analysis of Ash Packing and Distribution in Diesel Particulate Filters to Transient Changes in Exhaust Conditions

2012-04-16
2012-01-1093
Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.
Journal Article

Direct Measurements of Soot/Ash Affinity in the Diesel Particulate Filter by Atomic Force Microscopy and Implications for Ash Accumulation and DPF Degradation

2014-04-01
2014-01-1486
Inorganic engine lubricant additives, which have various specific, necessary functions such as anti-wear, leave the combustion chamber bound to soot particles (approximately ≤1% by mass) as ash [13], and accumulate in aftertreatment components. The diesel particulate filter (DPF) is especially susceptible to ash-related issues due to its wall-flow architecture which physically traps most of the soot and ash emissions. Accumulated lubricant-derived ash results in numerous problems including increased filter pressure drop and decreased catalytic functionality. While much progress has been made to understand the macroscopic details and effects of ash accumulation on DPF performance, this study explores the nano- and micron-scale forces which impact particle adhesion and mobility within the particulate filter.
Technical Paper

Engine-Out “Dry” Particular Matter Emissions from SI Engines

1997-10-01
972890
The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.
Technical Paper

The Effects of Sulfated Ash, Phosphorus and Sulfur on Diesel Aftertreatment Systems - A Review

2007-07-23
2007-01-1922
This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.
Technical Paper

Modeling and Measurement of Tribological Parameters between Piston Rings and Liner in Turbocharged Diesel Engine

2007-04-16
2007-01-1440
This paper presents tribological modeling, experimental work, and validation of tribology parameters of a single cylinder turbocharged diesel engine run at various loads, speeds, intake boost pressures, and cylinder liner temperatures. Analysis were made on piston rings and liner materials, rings mechanical and thermal loads, contact pressure between rings and liner, and lubricant conditions. The engine tribology parameters were measured, and used to validate the engine tribology models. These tribology parameters are: oil film thickness, coefficient of friction between rings and liner, friction force, friction power, friction torque, shear rate, shear stress and wear of the sliding surfaces. In order to measure the oil film thickness between rings and liner, a single cylinder AVL turbocharged diesel engine was instrumented to accept the difference in voltage drop method between rings, oil film, and liner.
Technical Paper

Engine Wear Modeling with Sensitivity to Lubricant Chemistry: A Theoretical Framework

2007-04-16
2007-01-1566
The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.
Technical Paper

Thermal Imaging Technology using a Thermoelectric Infrared Sensor

2008-04-14
2008-01-0912
This paper describes a low-cost 48 × 48 element thermal imaging camera intended for use in measuring the temperature in a car interior for advanced air conditioning systems. The compact camera measures 46 × 46 × 60 mm. It operates under a program stored in the central processing unit and can measure the interior temperature distribution with an accuracy of ±0.7°C in range from 0 to 40°C. The camera includes a thermoelectric focal plane array (FPA) housed in a low-cost vacuum-sealed package. The FPA is fabricated with the conventional IC manufacturing process and micromachining technology. The chip is 6.5 × 6.5 mm in size and achieves high sensitivity of 4,300 V/W, which is higher than the performance reported for any other thermopile. This high performance has been achieved by optimizing the sensor's thermal isolation structure and a precisely patterned Au-black absorber that attains high infrared absorptivity of more than 90%.
Technical Paper

Oil Conditioning as a Means to Minimize Lubricant Ash Requirements and Extend Oil Drain Interval

2009-06-15
2009-01-1782
A novel approach to condition the lubricant at a fixed station in the oil circuit is explored as a potential means to reduce additive requirements or increase oil drain interval. This study examines the performance of an innovative oil filter which releases no additives into the lubricant, yet enhances the acid control function typically performed by detergent and dispersant additives. The filter chemically conditions the crankcase oil during engine operation by sequestering acidic compounds derived from engine combustion and lubricant degradation. Long duration tests with a heavy-duty diesel engine show that the oil conditioning with the strong base filter reduces lubricant acidity (TAN), improves Total Base Number (TBN) retention, and slows the rate of viscosity increase and oxidation. The results also indicate that there may be a reduction in wear and corrosion.
Technical Paper

Research on High Strength Material and Its Surface Modification for Parts Used Under Rolling Contact Cycles

2004-03-08
2004-01-0633
This paper describes a newly developed steel composition and surface modification methods for improving the rolling contact fatigue strength of parts used in transmission systems, especially continuously variable transmissions (CVTs) to increase their torque capacity. The mechanisms of two types of typical rolling contact fatigue phenomenon in case hardening steel were examined with the aim of improving rolling contact fatigue strength. One concerned white etching constituents (WEC) and the other one concerned peculiar microstructural changes caused by hydrogen originating from decomposition of the lubrication oil as a result of repeated rolling contact stress cycles. The rolling contact fatigue strength limit due to WEC has been improved markedly by dispersing fine M23C6 alloy carbides in the martensite matrix at the subsurface layer of parts.
Technical Paper

Development of an Automotive Air Conditioning System Using the HFC-134a Refrigerant

1992-02-01
920216
Regulations on the use of chlorofluorocarbons (CFCs) are being adopted around the world to protect the ozone layer from these chemicals. It is Nissan's position that environmental protection is one of the most important issues facing automotive engineers today. Accordingly, with the aim of ensuring a healthier environment, we have been working for approximately three years on the development of an automotive air conditioning system using the HFC-134a refrigerant in place of CFC-12. Starting with the introduction of this air conditioning system in a new production model scheduled for release in March 1992, the system is expected to be used in all new models for North America by the end of 1993. This paper describes the HFC-134a automotive air conditioning system from the standpoint of the design changes required in comparison with a conventional CFC-12 system and technical measures needed for vehicle application.
Technical Paper

Research on the Effect of Lubricant Oil and Fuel Properties on LSPI Occurrence in Boosted S. I. Engines

2016-10-17
2016-01-2292
The effects of lubricant oil and fuel properties on low speed pre-ignition (LSPI) occurrence in boosted S.I. engines were experimentally evaluated with multi-cylinder engine and de-correlated oil and fuel matrices. Further, the auto-ignitability of fuel spray droplets and evaporated homogeneous fuel/oil mixtures were evaluated in a combustion bomb and pressure differential scanning calorimetry (PDSC) tests to analyze the fundamental ignition process. The work investigated the effect of engine conditions, fuel volatility and various lubricant additives on LSPI occurrence. The results support the validity of aspects of the LSPI mechanism hypothesis based on the phenomenon of droplets of lubricant oil/fuel mixture (caused by adhesion of fuel spray on the liner wall) flying into the chamber and autoigniting before spark ignition.
Technical Paper

A One-Line Correlation for Predicting Oil Vaporization from Liner for IC Engines

2018-04-03
2018-01-0162
The increasingly stringent regulations for fuel economy and emissions require better optimization and control of oil consumption. One of the primary mechanisms of oil consumption is vaporization from the liner; we consider this as the “minimum oil consumption (MOC).” This paper presents a physical-mathematical cycle model for predicting the MOC. The numerical simulations suggest that the MOC is markedly sensitive to oil volatility, liner temperature, engine load and speed but less sensitive to oil film thickness. A one-line correlation is proposed for quick MOC estimations. It is shown to have <15% error compared to the cycle MOC computation. In the “dry region” (between top ring and OCR at the TDC), oil is depleted due to high heat and continual exposure to the combustion chamber.
Technical Paper

Modeling the Evolution of Fuel and Lubricant Interactions on the Liner in Internal Combustion Engines

2018-04-03
2018-01-0279
In internal combustion engines, a portion of liquid fuel spray may directly land on the liner and mix with oil (lubricant), forming a fuel-oil film (~10μm) that is much thicker than the original oil film (~0.1μm). When the piston retracts in the compression stroke, the fuel-oil mixture may have not been fully vaporized and can be scraped by the top ring into the 1st land crevice and eventually enter the combustion chamber in the format of droplets. Studies have shown that this mechanism is possibly a leading cause for low-speed pre-ignition (LSPI) as the droplets contain oil that has a much lower self-ignition temperature than pure fuel. In this interest, this work aims to study the oil-fuel interactions on the liner during an engine cycle, addressing molecular diffusion (in the liquid film) and vaporization (at the liquid-gas interface) to quantify the amount of fuel and oil that are subject to scraping by the top ring, thereby exploring their implications on LSPI and friction.
Technical Paper

Development of a Lubricant for Retrofitting Automotive Air Conditioners for Use with HFC-134a

1994-03-01
940594
This paper presents a new refrigeration lubricant for use with the HFC-134a retrofit refrigerant in automotive air-conditioning systems originally designed to use the CFC-12 refrigerant, one of the regulated CFCs scheduled to be phased out. This new retrofit lubricant provides high lubricity and excellent performance characteristics as a result of adopting a newly developed PAG base oil with a block polymer structure and a new antiwear additive formulation. In retrofit systems, it assures sufficient durability for wobble-plate-type variable displacement compressors, which experience severe lubrication conditions.
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