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Technical Paper

Investigation of the Dilution Process for Measurement of Particulate Matter from Spark-Ignition Engines

Measurements of particulate matter (PM) from spark ignition (SI) engine exhaust using dilution tunnels will become more prevalent as emission standards are tightened. Hence, a study of the dilution process was undertaken in order to understand how various dilution related parameters affect the accuracy with which PM sizes and concentrations can be determined. A SI and a compression ignition (CI) engine were separately used to examine parameters of the dilution process; the present work discusses the results in the context of SI exhaust dilution. A Scanning Mobility Particle Sizer (SMPS) was used to measure the size distribution, number density, and volume fraction of PM. Temperature measurements in the exhaust pipe and dilution tunnel reveal the degree of mixing between exhaust and dilution air, the effect of flowrate on heat transfer from undiluted and diluted exhaust to the environment, and the minimum permissible dilution ratio for a maximum sample temperature of 52°C.
Technical Paper

Effects of Lubrication System Parameters on Diesel Particulate Emission Characteristics

The effects of lubrication system parameters on particulate emission rate and composition were studied. Engine load, viscosity and piston-ring gap were varied. Particulate rate and composition were measured for multiple combinations of lubricant and ring-gap configurations at three different engine operating conditions. Particulate rates were higher with the lower viscosity oil and larger with the wider top-ring gap. At high load, the difference in particulate rate was due to changes in the non-soluble portion, while at medium and low loads, the change in particulate rate was due to differences in the lubricant-derived portion of the soluble organic fraction (SOF). Additionally, changes in the fuel-derived portion of the SOF were discovered and attributed to changes in fuel-absorption in the oil film.
Technical Paper

Three-Dimensional Computation of the Effects of the Swirl Ratio in Direct-Injection Diesel Engines on NOx and Soot Emissions

Three-dimensional computation has been applied to analyze combustion and emission characteristics in direct-injection diesel engines. A computational code called TurboKIVA was used to investigate the effects of the swirl ratio, one of the fundamental factors related to combustion control, on combustion characteristics and NOx and soot emissions. The code was first modified to calculate soot formation and oxidation and the precise behavior of fuel drops on the combustion chamber wall. As a result of improving calculation accuracy, good agreement was obtained between the measured and predicted pressure, heat release rate and NOx and soot emissions. Using this modified version of TurboKIVA, the effects of the swirl ratio on NOx and soot emissions were investigated. The computational results showed that soot emissions were reduced with a higher swirl ratio. However, a further increase in the swirl ratio produced greater soot emissions.
Technical Paper

Engine-Out “Dry” Particular Matter Emissions from SI Engines

The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.
Technical Paper

Effect of Composition, Particle Size, and Heat Treatment on the Mechanical Properties of Al-4.5 wt.% Cu Based Alumina Particulate Reinforced Composites

The quest for higher efficiency and performance of automotive vehicles requires application of materials with high strength, stiffness and lower weight in their construction. Particulate-reinforced aluminum-matrix composites are cost-competitive materials, which can meet these requirements. MMCC, Inc. has been optimizing particulate-reinforced alloy systems and developing the Advanced Pressure Infiltration Casting (APIC™) process for the manufacture of components from these materials. This paper discusses the results of a recent study in which composites reinforced with 55 vol.% alumina were cast using two sizes of alumina particulate and eight different matrix alloys based on Al-4.5 wt.% Cu with varying amounts of silicon and magnesium. Optimum heat treatments for each alloy were determined utilizing microhardness studies. The tensile strength and fracture toughness were evaluated as a function of alloy chemistry, particulate size, and heat treatment.
Technical Paper

Decoupled Design of Cylinder Liner for IC Engines

Concept of a new decoupled cylinder liner design for internal combustion (IC) engines is presented from the framework of axiomatic design to improve friction and wear characteristics. In the current design, the piston rings fail to satisfy their functional requirements at the two dead centers of the piston stroke where lubrication is poor. It is proposed that by using undulated cylindrical surfaces selectively along the cylinder liner, much of the existing friction and wear problems of IC engines may be solved. The main idea behind undulated surface is to trap wear particles at the piston-cylinder interface in order to minimize plowing, and thus maintain low friction even in areas where lubrication fails to be hydrodynamic. In dry sliding tests using a modified engine motored at low speeds, undulated cylinders operated for significantly longer time than smooth cylinders without catastrophic increase in friction.
Technical Paper

New PM Valve Seat Insert Materials for High Performance Engines

Internal combustion engines experience severe valve train wear and the reduction of valve seat and seat insert wear has been a long-standing issue. In this work, worn valve seats and inserts were examined to obtain a fundamental understanding of the wear mechanisms and the results were applied in developing new valve seat insert materials. The new exhaust valve insert material for gasoline engines is a sintered alloy steel containing Co-base hard particles, with lead infiltrated only for inserts used in unleaded gasoline engines. The new intake valve insert material for gasoline engines is a high-Mo sintered steel, obtained through transient liquid phase sintering and with copper precipitated uniformly. This material can be used for both leaded and unleaded gasoline engines. Valve and valve seat insert wear has long been an issue of concern to engine designers and manufacturers.
Technical Paper

Development of High Strength Transmission Gears

High strength transmission gears have been developed for use in the final gear set of front-wheel-drive vehicles. The steel used as the gear material has a higher molybdenum content, allowing more austenite to be retained following carburizing than is possible with chromium steel. As a result, the steel can be subjected to higher intensity shot peening by using harder peening particles which are projected by an air-nozzle peening system. With this procedure, the fatigue strength of the gears can be increased 1.6 times over that of conventional gears.
Technical Paper

Analysis of Interior Airflow in a Full-Scale Passenger-Compartment Model Using a Laser-Light-Sheet Method

Flow velocity distributions in the passenger compartment were measured from visualized images of particle flow paths obtained with a full-scale model. The flow paths were visualized using an approach that combined a particle tracing method with a pulse-laser light technique. Air was used as the fluid medium with the full-scale passenger compartment model and water was used as the fluid medium with a one-fourth scale model. A comparison of the results obtained with the two models confirmed that there was good agreement between the flow velocity distributions. Using the full-scale model, measurements were also made of the flow velocity distributions when two dummies were placed in the front-seats.
Technical Paper

Effects of Fuel Properties Associated with In-Cylinder Behavior on Particulate Number from a Direct Injection Gasoline Engine

The purpose of this work was to gain a fundamental understanding of which fuel property parameters are responsible for particulate emission characteristics, associated with key intermediate behavior in the engine cylinder such as the fuel film and insufficient mixing. Accordingly, engine tests were carried out using various fuels having different volatility and chemical compositions under different coolant temperature conditions. In addition, a fundamental spray and film visualization analysis was also conducted using a constant volume vessel, assuming the engine test conditions. As for the physical effects, the test results showed that a low volatility fuel displayed high particulate number (PN) emissions when the injection timing was advanced. The fundamental test clearly showed that the amount of fuel film on the impingement plate increased under such operating conditions with a low volatility fuel.
Technical Paper

Effect of Operating Conditions on the Particulates from a Single Cylinder Diesel Engine

Particulates were collected from the exhaust of a single cylinder diesel engine at different speeds and fuel-air equivalence ratios. The filters were rated to capture 99.99% of all particulates >0.3 microns in diameter. Samples were taken at 1500 RPM and equivalence ratios varying from about 0.2 to 0.7, and at an equivalence ratio of about 0.3 and engine speeds varying from 1000 to 2500 RPM. A base point with an equivalence ratio of 0.3 with an engine speed of 1500 RPM was repeated several times to establish the expected test variation of the particulate data. The particulate properties investigated were the total mass of particulate produced per mass of fuel burned, the mass fraction of extractable organic material in the sample, and the mutagenic potency of the extract as measured by a bacterial bioassay. Variation in fuel-air ratio (engine load) affected the particulate and extractable organic production much more than variations in engine speed.
Technical Paper

Potentiality of Small DI Diesel Engines Under Consideration of Emissions and Noise Control

The potentiality of direct injection (DI) diesel engines for passenger cars has been examined by comparing the characteristics of fuel consumption, exhaust emissions and noize levels between a turbocharged DI diesel engine and a turbocharged IDI diesel engine with the same displacement, 4 cylinders and 2 liters. It was observed that improved fuel consumption was obtained as the engine load increased, namely, 10 - 15% in the higher load range and 5 - 10% in the partial load range. In comparison to the IDI engine, the exhaust emissions of the DI engine tended to contain two or three times higher NOx and HC, and also about 30% higher particulates. Further, the noise levels of the DI engine were approximately 2 - 4 dB (A) higher than those of the IDI engine.
Technical Paper

A Comparative Study on Different Dual-Fuel Combustion Modes Fuelled with Gasoline and Diesel

Comparisons have been made between dual-fuel (80% port-injection gasoline and 20% direct-injection diesel by mass) Highly Premixed Charge Combustion (HPCC) and blended-fuel (80% gasoline and 20% diesel) Low Temperature Combustion (LTC) modes on a 1-L single-cylinder test engine. In the HPCC mode, both early-injection (E-HPCC) and late-injection (L-HPCC) of diesel have been used. The comparisons have been conducted with a fixed fuel injection rate of 50 mg/cycle at 1500 rpm, and with the combustion phasing fixed (by adjusting the injection timing) so that the 50% heat release point (CA50) is at 8° ATDC. The rapid heat release process of LTC leads to the highest maximum pressure rise rate (MPRR). A two-peak heat release process is observed in L-HPCC, resulting in a lower MPRR. The heat release rate and MPRR values for the E-HPCC are comparable to the L-HPCC values. The EHPCC mode provides the lowest NOX emission. The soot emissions for all three modes are low.
Technical Paper

Microfluidic Simulation of Diesel Exhaust Gas and Soot Oxidation in Diesel Particulate Filter

Particulate matter (PM) including soot in diesel exhaust gas is a serious atmospheric pollutant, and stricter exhaust emission standards are being set in many countries. As one of the key technologies, a diesel particulate filter (DPF) for PM trap in the after-treatment of the exhaust gas has been developed. Typically, the inlet size of filter monolith is about 2 mm, and the thickness of the filter wall is only 0.2 mm, where soot particles are removed. It is impossible to observe the small-scale phenomena inside the filter, experimentally. Then, in the present study, we conducted microfluidic simulation with soot oxidation. Here, a real cordierite filter was used in the simulation. The inner structure of the filter was scanned by a 3D X-ray CT Computed Tomography) technique. The advantage is that it is non-intrusive system, and it has a high spatial resolution in the micrometer.
Technical Paper

Effect of In-Cylinder Liquid Fuel Films on Engine-Out Unburned Hydrocarbon Emissions for an SI Engine

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.
Technical Paper

Influence of Material Properties and Pore Design Parameters on Non-Catalyzed Diesel Particulate Filter Performance with Ash Accumulation

Diesel particulate filters (DPF) are a common component in emission-control systems of modern clean diesel vehicles. Several DPF materials have been used in various applications. Silicone Carbide (SiC) is common for passenger vehicles because of its thermal robustness derived from its high specific gravity and heat conductivity. However, a segmented structure is required to relieve thermal stress due to SiC's higher coefficient of thermal expansion (CTE). Cordierite (Cd) is a popular material for heavy-duty vehicles. Cordierite which has less mass per given volume, exhibits superior light-off performance, and is also adequate for use in larger monolith structures, due to its lower CTE. SiC and cordierite are recognized as the most prevalent DPF materials since the 2000's. The DPF traps not only combustible particles (soot) but also incombustible ash. Ash accumulates in the DPF and remains in the filter until being physically removed.
Technical Paper

TEM Analysis of Soot Particles Sampled from Gasoline Direction Injection Engine Exhaust at Different Fuel Injection Timings

For better understanding of in-cylinder soot formation processes and governing factors of the number of emitted soot particles of Gasoline Direct Injection (GDI) engines, Transmission Electron Microscope (TEM) analysis of morphology and nanostructure of the soot particles sampled in the exhaust should provide useful information. However, the number concentration of the soot particles emitted from GDI engines is relatively low, which was impeding reliable morphological analysis of the soot particles based on a sufficient number of sampled particles. Therefore, in the present study, a water-cooled thermophoretic sampler for simple and direct sampling of exhaust soot particles was developed and employed, which enabled to obtain a sufficient number of particle samples from the exhaust with Particulate Number (PN) 105 #/cc level for quantitative morphology analysis.
Technical Paper

Impact of Oil-derived Sulfur and Phosphorus on Diesel NOx Storage Reduction Catalyst - JCAP II Oil WG Report

Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.
Technical Paper

Particulate Matter Emission During Start-up and Transient Operation of a Spark-Ignition Engine

In order to understand why emissions of Particulate Matter (PM) from Spark-Ignition (SI) automobiles peak during periods of transient operation such as rapid accelerations, a study of controlled, repeatable transients was performed. Time-resolved engine-out PM emissions from a modern four-cylinder engine during transient load and air/fuel ratio operation were examined, and the results could be fit in most cases to a first order time response. The time constants for the transient response are similar to those measured for changes in intake valve temperature, reflecting the strong dependence of PM emissions on the amount of liquid fuel in the combustion chamber. In only one unrepeatable case did the time response differ from a first order function: showing an overshoot in PM emissions during transition from the initial to the final steady state PM emission level.
Technical Paper

Particulate Matter Emission During Start-up and Transient Operation of a Spark-Ignition Engine (2): Effect of Speed, Load, and Real-World Driving Cycles

Previous research into Particulate Matter (PM) emissions from a spark-ignition engine has shown that the main factor determining the how PM emissions respond to transient engine operating conditions is the effect of those conditions on intake port processes such as fuel evaporation. The current research extends the PM emissions data base by examining the effect of transient load and speed operating conditions, as well as engine start-up and shut-down. In addition, PM emissions are examined during “real-world” driving conditions - specifically, the Federal Test Procedure. Unlike the previous work, which was performed on an engine test stand with no exhaust gas recirculation and with a non-production engine controller, the current tests are performed on a fully-functional, production vehicle operated on a chassis dynamometer to better examine real world emissions.