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A new multidimensional calculation method has been developed to simulate the warm-up characteristics of close-coupled catalytic converter systems. First, a one-dimensional gas exchange simulation and a three-dimensional exhaust gas flow calculation are combined to simulate the pulsation gas flow caused by the gas exchange process. The gas flow calculation and a heat transfer calculation are then combined to simulate heat transfer in the exhaust manifold and the catalyst honeycomb under pulsation flow. The predicted warm-up characteristics of the systems examined agreed well with the experimental data. In this simulation, CPU time was reduced greatly through the use of new calculation methods. Finally, the warm-up process of close-coupled catalysts is analyzed in detail with this simulation method. The design requirements for improving warm-up characteristics have been made clear.

The authors used a mass spectrometer to determine an SOF reduction mechanism of a diesel oxidation catalyst. The results indicate that SOF reduction lies in the catalytic conversion of high molecular organic matter to low molecular organic matter. And unregulated emissions are also reduced through this conversion. It is also found that the SOF reduction performance is highly dependent up on the condition of the wash coat. There is some limitation to improving diesel oxidation catalyst performance because of the sulfur content found in diesel fuel. Finally, the authors have determined what we think are the specifications of the presently best catalytic converter.

A new type of catalytic converter has been developed for the coming TLEV (Transitional Low Emission Vehicle) standards. It is a “Front Curve Catalytic Converter (FCCC)” using a curved cordierite ceramic honeycomb substrate. During this development, an optimum location and volume of the front curve catalytic converter were determined from the view points of thermal deterioration of the catalyst and hydrocarbon conversion performance. Based on CAE (Computer Aided Engineering) analysis, the best curvature radius of the substrate was selected to minimize a pressure drop of the front curve catalytic converter. The emission conversion and light-off performances of the front curve catalytic converter were compared with a conventional straight design. A series of durability tests; hot vibration, engine dynamometer and vehicle fleet tests were also conducted to confirm the reliability of the new front curve catalytic converter.

Various heat resistant alloys are being introduced for use in automobile emission equipment, such as thermal reactors and catalytic converters. For the past several years Japan has been developing alloys which emphasize oxidation resistance. Therefore, oxidation phenomena have been thoroughly researched and clarified. On the other hand, embrittlement, which is a marked deterioration similar to oxide deterioration, has not been studied sufficiently. The major subjects of investigation were the two forms of embrittlement in austenitic heat resistant alloys, caused by the precipitation of σ phase and the absorption of Nitrogen. Useful information was obtained from these results.

Three Japanese automobile manufacturers-Mitsubishi Motors Corp., Nissan Motor Co., Ltd., and Toyo Kogyo Co., Ltd.-have been making efforts over the past three years to design and develop effective thermal reactor-exhaust gas recirculation and catalytic converter systems suitable for small engines. The work is being done by members participating in the IIEC (Inter-Industry Emission Control) Program, and the exhaust emission levels of the concept vehicles developed by these companies have met the goal established by the IIEC Program at low mileage. Each system, however, has a characteristic relationship between exhaust emission level and loss of fuel economy. Much investigation is required, particularly with respect to durability, before any system that will fully satisfy all service requirements can be completed. This paper reports the progress of research and development of the individual concept vehicles.

The front exhaust pipe and the heat-shield plate of the catalytic converter are excited by the engine vibration. Noise radiation occurs on their surface. Concerning vehicle exterior noise, noise radiated from the exhaust system is often one of major sources as well as engine and exhaust noise. This paper describes the longitudinal vibration model-as a beam-is applied to the high frequency vibration that causes the noise radiated from the exhaust system. It describes also some methods of reducing such noise radiation by isolating the vibration from the front exhaust pipe. These methods are: adding mass to the front pipe, changing the material of the front pipe to a smaller Young's modulus one, installing flexible pipe composed by two sections, and so on.