Effects of Engine Oil Composition on the Activity of Exhaust Emissions Oxidation Catalysts
Platinum, palladium, and copper-chromium oxidation catalysts for exhaust emission control were exposed to exhaust gases from a steady-state engine dynamometer test in which the amount of oil consumed per unit volume of catalyst was high. When unleaded gasoline (0.004 Pb g/gal, 0.004 P g/gal) was used, conventional SE oil caused somewhat greater loss of catalyst activity than an ashless and phosphorus-free (“clean”) oil. Chemical analysis of the catalyst indicated that phosphorus from the conventional oil was probably responsible for the difference. However, a test run with low-lead (0.5 Pb g/gal, 0.004 P g/gal) gasoline and “clean” oil caused much greater catalyst activity deterioration than either of the tests with unleaded gasoline.